Divalent transition metals and magnesium in structures that contain the autunite-type sheet

Canadian Mineralogist

Volumn 42, Issue 6, 2004, Pages 1699-1718

  Locock, Andrew J ^a   Burns, Peter C ^b   Flynn, Theodore M ^c  

^a DEPARTMENT OF NATURAL HISTORY   (Canada)

^b UNIVERSITY OF NOTRE DAME   (United States)

^c UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

Autunite; Bassetite; Crystal structure; Gel synthesis; Hydrothermal synthesis; Kahlerite; Kirchheimerite; Lehnerite; Metakahlerite; Metakirchheimerite; Metalod vite; Metanov ekite; Metasal eite; Nov ekite I; Nov ekite II; Sal eite; Uranyl arsenate; Uranyl phosphate

Indexed keywords

CRYSTAL STRUCTURE; DIFFUSION; HYDRATION; HYDROGEN BONDS; MAGNESIUM COMPOUNDS; POSITIVE IONS; RADIATION; X RAY DIFFRACTION ANALYSIS;

AUTUNITE-TYPE SHEETS; DIVALENT CATIONS; HYDROTHERMAL METHOD;

TRANSITION METALS;

AUTUNITE; CRYSTAL STRUCTURE; MAGNESIUM; TRANSITION ELEMENT; X-RAY DIFFRACTION;

EID: 15044340245     PISSN: 00084476     EISSN: None     Source Type: Journal    
DOI: 10.2113/gscanmin.42.6.1699     Document Type: Article

References (71)

1. Agrinier, H., Chantret, F., Geffroy, J., Héry, B., Bachet, B. & Vachey, H. (1972): Une nouvelle espèce minérale: la méta-lodèvite (arséniate hydraté d'uranium et de zinc). Bull. Soc. fr. Minéral. Cristallogr. 95, 360-364.
2. Arend, H. & Connelly, J.J. (1982): Tetramethoxysilane as gel forming agent in crystal growth. J. Crystal Growth 56, 642-644.
3. Beintema, J. (1938): On the composition and crystallography of autunite and the meta-autunites. Recl. Trav. Chim. Pays-Bas 57, 155-175.
4. Berman, R. (1957): Studies of uranium minerals. XXIII. Torbernite, zeunerite and uranospherite. Am. Mineral. 42, 905-910.
5. Braithwaite, R.S.W. & Knight, J.R. (1990): Rare minerals, including several new to Britain, in supergene alteration of U-Cu-As-Bi-Co mineralization near Dalbeattie, south Scotland. Mineral. Mag. 54, 129-131.
6. Brown, I.D. & Altermatt, D. (1985): Bond-valence parameters obtained from a systematic analysis of the inorganic crystal structure database. Acta Crystallogr. B41, 244-247.
7. Bruker (1998): SAINT, V 5.01 program for reduction of data collected on Bruker AXS CCD area detector systems. Bruker Analytical X-ray Systems, Madison, Wisconsin.
8. Burns, P.C. (1999): The crystal chemistry of uranium. In Uranium: Mineralogy, Geochemistry and the Environment (P.C. Burns & R.J. Finch, eds.). Rev. Mineral. 38, 23-90.
9. Burns, P.C., Ewing, R.C. & Hawthorne, F.C. (1997): The crystal chemistry of hexavalent uranium: polyhedron geometries, bond-valence parameters, and polymerization of polyhedra. Can. Mineral. 35, 1551-1570.
10. Burns, R.G. (1993): Mineralogical Applications of Crystal Field Theory (2nd ed.). Cambridge University Press, New York, N.Y.
11. Cassedanne, J.P., Cassedanne, J.O. & De Carvalho, H.F. (1986): Loellingite, uraninite, and their alteration products in the pegmatite from Urucum (Minas Gerais, Brazil). An. Acad. Bras. Cienc. 58 249-266.
12. 2O molecular motions. Solid State Comm. 65, 315-317.
13. Donnay, G. & Donnay, J.D.H. (1955): Contribution to the crystallography of uranium minerals. U.S. Geol. Surv., Trace Elements Investigations Rep. 507 (TEI-507). U.S. Atomic Energy Commission Technical Information Service.
14. Eby, R.K. & Hawthorne, F.C. (1993): Structural relations in copper oxysalt minerals. I. Structural hierarchy. Acta Crystallogr. B49, 28-56.
15. Elton, N.J., Hooper, J.J. & Jeal, A.E. (1994): Nováčekite and metanováčekite from Cornwall. Mineral. Mag. 58, 513-514.
16. Ferraris, G., Gula, A., Ivaldi, G., Nespolo, M., Sokolova, E., Uvarova, Y. & Khomyakov, A.P. (2001): First structure determination of an MDO-2 0 mica polytype associated with a 1M polytype. Eur. J. Mineral. 13, 1013-1023.
17. Finch, R. & Murakami, T. (1999): Systematics and paragenesis of uranium minerals. In Uranium: Mineralogy, Geochemistry and the Environment (P.C. Burns & R.J. Finch, eds.). Rev. Mineral. 38, 91-179.
18. Frondel, C. (1951): Studies of uranium minerals. IX. Saléeite and novacekite. Am. Mineral. 36, 680-686.
19. Frondel , C. (1958): Systematic mineralogy of uranium and thorium. U.S. Geol. Surv., Bull. 1064.
20. Gaines, R. V., Skinner, H.C.W., Foord, E.E., Mason, B., Rosenzweig, A. & King, V.T. (1997): Dana's New Mineralogy (eighth ed.). John Wiley & Sons, New York, N.Y.
21. Guinier, A., chairman (1984): Nomenclature of polytype structures - report of the International Union of Crystallography Ad Hoc Committee on the nomenclature of disordered, modulated and polytype structures. Acta Crystallogr. A40, 399-404.
22. Hallimond, A.F. (1915): On bassetite and uranospathite, new species hitherto classed as autunite. Mineral. Mag. 17, 221-236.
23. Henisch, H.K. (1988): Crystals in Gels and Liesegang Rings. Cambridge University Press, New York, N.Y.
24. Herbst-Irmer R. & Sheldrick, G.M. (1998): Refinement of twinned structures with SHELXL97. Acta Crystallogr. B54, 443-449.
25. Huang, W.T. (1956): Novacekite from the Wichita Mountains, Oklahoma. Am. Mineral. 41, 152-153.
26. Jaffe, H.W. (1988): Crystal Chemistry and Refractivity. Cambridge University Press, New York, N.Y.
27. Jameson, G.B. (1982): On structure refinement using data from a twinned crystal. Acta Crystallogr. A38, 817-820.
28. Jeffrey, G.A. (1997): An Introduction to Hydrogen Bonding. Oxford University Press, New York, N.Y.
29. Krivovichev, S.V., Armbruster, T., Yakovenchuk, V.N., Pakhomovsky, Y.A. & Men'shikov, Y.P. (2003): Crystal structures of lamprophyllite-2M and lamprophyllite-2O from the Lovozero alkaline massif, Kola peninsula, Russia. Eur. J. Mineral. 15, 711-718.
30. Le Page, Y. (1987): Computer derivation of the symmetry elements implied in a structure description. J. Appl. Crystallogr. 20, 264-269.
31. 11. Am. Mineral. 88, 240-244.
32. Locock, A.J. & Burns, P.C. (2003b): Crystal structures and synthesis of the copper-dominant members of the autunite and meta-autunite groups: torbernite, zeunerite, metatorbernite and metazeunerite. Can. Mineral. 41, 489-502.
33. Locock, A.J. & Burns, P.C., Duke, M.J.M. & Flynn, T.M. (2004): Monovalent cations in structures of the meta-autunite group. Can. Mineral. 42, 973-996.
34. Mandarino, J.A. & Back, M.E. (2004): Fleischer's Glossary of Mineral Species 2004. The Mineralogical Record Inc., Tucson, Arizona.
35. 2O; gel growth and characterization. J. Crystal Growth 61, 606-614.
36. Meixner, H. (1953): Kahlerite, a new mineral of the uranium mica group, from the Hüttenberg ore deposits, Carinthia. Der Karinthin 23, 277-280.
37. 2O. Z. Kristallogr. 177, 247-253.
38. Mrose, M.E. (1950): Studies of uranium minerals. III. Saléeite from Schneeberg, Saxony. Am. Mineral. 35, 525-530.
39. 2O, as a new mineral from the pegmatite of Hagendorf/Oberpfalz. Aufschluss 39, 209-217.
40. II = Zn, Ni, and Co). Bull. Soc. fr. Miné ral. Cristallogr. 100, 272-274.
41. Nespolo, M. & Ferraris G. (2001): Effects of the stacking faults on the calculated electron density of mica polytypes - the Ďurovič effect. Eur. J. Mineral. 13, 1035-1045.
42. Ondruš, P., Veselovský, F., Skála, R., Císařová, I., Hloušek, J., Frýda, J., Vavřín, I., Čejka, J. & Gabašová, A. (1997): New naturally occurring phases of secondary origin from Jáchymov (Joachimsthal). J. Czech Geol. Soc. 42 77-108.
43. 2O single crystals from gel. J. Crystal Growth 69, 639-640.
44. Pinto, M.M.S.C., Silva, M.M.V.G. & Neiva, A.M.R. (2001): Uranium mineralization and water contamination in central Portugal. Water-Rock Interaction, Proc. 10th Int. Symp. on Water-Rock Interaction (Villasimius) 2, 1261-1264.
45. Piret, P. & Deliens, M. (1980): New data for holotype saléeite from Shinkolobwe. Bull. Minéral. 103, 630-632.
46. Pozas-Tormo, R., Moreno-Real, L., Martínez-Lara, M. & Bruque-Gamez, S. (1986): Layered metal uranyl phosphates. Retention of divalent ions by amine intercalates of uranyl phosphates. Can. J. Chem. 64 30-34.
47. Robert, M.C. & LeFaucheux, F. (1988): Crystal growth in gels: principle and applications. J. Crystal Growth 90, 358-367.
48. Shannon, R.D. (1976): Revised effective ionic radii and systematic studies of interatomic distances in halide and chalcogenides. Acta Crystallogr. A32, 751-767.
49. Sheldrick, G.M. (1998): SHELXTL NT, V5.1 Program Suite for Solution and Refinement of Crystal Structures. Bruker Analytical X-ray Systems, Madison, Wisconsin.
50. Smith, D.K., Jr. (1984): Uranium mineralogy. In Uranium Geochemistry, Mineralogy, Geology, Exploration and Resources (B. De Vivo, F. Ippolito, G. Capaldi & P.R. Simpson, eds.). Institute of Mining and Metallurgy, London, U.K. (43-88).
51. Spek, A.L. (2003): Single-crystal structure validation with the program PLATON. J. Appl. Crystallogr. 36, 7-13.
52. Stern, T.W. & Annell, C.S. (1954): A second locality of novacekite. Am. Mineral. 39, 675-676.
53. Suzuki, Y., Murakami, T., Kogure, T., Isobe, H. & Sato, T. (1998): Crystal chemistry and microstructures of uranyl phosphates. Mater. Res. Soc., Symp. Proc. 506, 839-846.
54. Thoreau, J. & Vaes, J.F. (1932): La saléeite, nouveau minéral uranifère. Bull. Soc. Belge Géol. 42, 96-100.
55. Vochten, R. (1984): Mineralogical study of meta-zeunerite, meta-kirchheimerite and their Ni-analogue. Proc. Second Int. Congress on Applied Mineralogy in the Minerals Industry (Los Angeles), 1129-1140.
56. Vochten, R. (1986): Synthesis, paragenesis, crystallographic data and electrokinetic properties of bassetite. Papers and Proceedings of the General Meeting of the International Mineralogical Association (Varna 13, 943-955.
57. Vochten, R. (1990): Transformation of chernikovite and sodium autunite into lehnerite. Am. Mineral. 75, 221-225.
58. Vochten, R., De Grave, E. & Pelsmaekers, J. (1984): Mineralogical study of bassetite in relation to its oxidation. Am. Mineral. 69, 967-978.
59. Vochten, R., De Grave, E. & Pelsmaekers, J. (1986): Synthesis, crystallographic and spectroscopic data, solubility and electrokinetic properties of metakahlerite and its Mn analogue. Am. Mineral. 71, 1037-1044.
60. Vochten, R. & Goeminne, A. (1984): Synthesis, crystallographic data, solubility and electrokinetic properties of metazeunerite, meta-kirchheimerite and nickel-uranylarsenate. Phys. Chem. Minerals 11, 95-100.
61. Vochten, R., Piret, P. & Goeminne, A. (1981): Synthesis, crystallographic data, solubility and electrokinetic properties of copper-, nickel- and cobalt-uranylphosphate. Bull. Minéral. 104, 457-467.
62. Vochten, R. & Van Springel, K. (1996): A natural ferrous substituted saléeite from Arcu so Linnarbu, Capoterra, Cagliari, Sardinia. Mineral. Mag. 60, 647-651.
63. Walenta, K. (1958): Die sekundären Uranmineralien des Schwarzwaldes. Jahresh. Geol. Landesamts Baden-Württemb. 3, 17-51.
64. Walenta, K. (1964): Beiträge zur Kenntnis seltener Arsenat-mineralien unter besonderer Berücksichtigung von Vorkommen des Schwarzmaldes. I. Tschermaks Mineral. Petrogr. Mitt. 9, 111-174.
65. Walenta, K. (1965a): Die Uranglimmergruppe. Chem. Erde 24, 254-278.
66. Walenta, K. (1965b): Beiträge zur Kenntnis seltener Arsenat-mineralien unter besonderer Berücksichtigung von Vorkommen des Scharzwaldes. II. Tschermaks Mineral. Petrogr. Mitt. 9, 252-282.
67. Walenta, K. (1977): Neue Funde sekundärer Uranmineralien im mittleren und nördlichen Schwarzwald. Aufschluss 28, 177-188.
68. Walenta, K. & Wimmenauer, W. (1961): Der Mineralbestand des Michaelganges im Weiler bei Lahr (Schwarzwald). Jahresh. Geol. Landesamts Baden-Württemb. 4, 7-37.
69. Wilson, A.J.C., ed. (1992): International Tables for X-ray Crystallography, Volume C. Kluwer Academic Press, Boston, Massachusetts.
70. Zolensky, M.E. (1993): The Structures and Crystal Chemistry of the Autunite and Meta-autunite Mineral Groups. Appendix 1. Gel Growth Experiments. Ph.D. thesis, Pennsylvannia State Univ., University Park, Pennsylvania.
71. 2O, a new uranyl phosphate mineral from Wheal Basset, Redruth, Cornwall, England. Mineral. Mag. 53, 473-478.