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Bis(acetylide)Pt(II) complexes have recently been used as emissive materials in LED devices. See: S.-C. Chan, M. C. W. Chan, Y. Wang, C.-M. Che, K.-K. Cheung and N. Zhu, Chem. Eur. J., 2001, 7, 4180-4190.
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14944373677
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note
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2 in 1:4 molar ratio in 46% and 62% yield, respectively.
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23
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14944382447
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note
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The ratio of diffusion coefficients for 1a and 2a has been determined to be 1.09 by pulsed gradient NMR spectroscopy, consistent with their trimeric and tetrameric structure.
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