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Volumn 44, Issue 6, 2005, Pages 653-660

Kinetics of oligomerization reactions in formaldehyde solutions: NMR experiments up to 373 K and thermodynamically consistent model

Author keywords

Formaldehyde; Quantitative on line 1H NMR spectroscopy; Reaction kinetics; Thermodynamics

Indexed keywords

FORMALDEHYDE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OLIGOMERS; PRESSURE EFFECTS; SYNTHESIS (CHEMICAL);

EID: 14844353999     PISSN: 02552701     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cep.2003.07.004     Document Type: Article
Times cited : (49)

References (17)
  • 3
    • 0029252722 scopus 로고
    • NMR spectroscopic and densimetric study of reaction kinetics of formaldehyde polymer formation in water, deuterium oxide, and methanol
    • I. Hahnenstein, M. Albert, H. Hasse, C.G. Kreiter, and G. Maurer NMR spectroscopic and densimetric study of reaction kinetics of formaldehyde polymer formation in water, deuterium oxide, and methanol Ind. Eng. Chem. Res. 34 1995 440 450
    • (1995) Ind. Eng. Chem. Res. , vol.34 , pp. 440-450
    • Hahnenstein, I.1    Albert, M.2    Hasse, H.3    Kreiter, C.G.4    Maurer, G.5
  • 6
    • 1542541575 scopus 로고    scopus 로고
    • Thermodynamics of reactive separations
    • K. Sundmacher A. Kienle Wiley-VCH Weinheim
    • H. Hasse Thermodynamics of reactive separations K. Sundmacher A. Kienle Reactive Distillation 2003 Wiley-VCH Weinheim 65 96
    • (2003) Reactive Distillation , pp. 65-96
    • Hasse, H.1
  • 7
    • 0034253793 scopus 로고    scopus 로고
    • Vapor-liquid equilibrium of aqueous solutions of formaldehyde and methanol
    • M. Albert, B.C. Garcia, C. Kuhnert, R. Peschla, and G. Maurer Vapor-liquid equilibrium of aqueous solutions of formaldehyde and methanol AIChE J. 46 2000 1676 1687
    • (2000) AIChE J. , vol.46 , pp. 1676-1687
    • Albert, M.1    Garcia, B.C.2    Kuhnert, C.3    Peschla, R.4    Maurer, G.5
  • 9
    • 0032144438 scopus 로고    scopus 로고
    • Vapor-liquid equilibrium of formaldehyde mixtures containing methanol
    • S. Brandani, V. Brandani, and I. Tarquini Vapor-liquid equilibrium of formaldehyde mixtures containing methanol Ind. Eng. Chem. Res. 37 1998 3485 3489
    • (1998) Ind. Eng. Chem. Res. , vol.37 , pp. 3485-3489
    • Brandani, S.1    Brandani, V.2    Tarquini, I.3
  • 10
    • 0348230481 scopus 로고    scopus 로고
    • Quantitative high-resolution on-line NMR spectroscopy in reaction and process monitoring
    • M. Maiwald, H.H. Fischer, Y.K. Kim, K. Albert, and H. Hasse Quantitative high-resolution on-line NMR spectroscopy in reaction and process monitoring J. Magn. Reson. 166 2004 135 146
    • (2004) J. Magn. Reson. , vol.166 , pp. 135-146
    • Maiwald, M.1    Fischer, H.H.2    Kim, Y.K.3    Albert, K.4    Hasse, H.5
  • 11
    • 0039640319 scopus 로고
    • Interpretation of pH-measurements in alcohol-water solvents
    • R.G. Bates, M. Paabo, and R.A. Robinson Interpretation of pH-measurements in alcohol-water solvents J. Phys. Chem. 67 1963 1833 1838
    • (1963) J. Phys. Chem. , vol.67 , pp. 1833-1838
    • Bates, R.G.1    Paabo, M.2    Robinson, R.A.3
  • 12
    • 84982077949 scopus 로고
    • The pH of some standard solutions in methanol and methanol-water mixtures at 25 °c. I. Theoretical part
    • C.L. De Ligny, P.F.M. Luykx, M. Rehbach, and A.A. Wieneke The pH of some standard solutions in methanol and methanol-water mixtures at 25 °C. I. theoretical part Rec. Trav. Chim. 79 1960 699 712
    • (1960) Rec. Trav. Chim. , vol.79 , pp. 699-712
    • De Ligny, C.L.1    Luykx, P.F.M.2    Rehbach, M.3    Wieneke, A.A.4
  • 13
    • 84982349900 scopus 로고
    • The pH of some standard solutions in methanol and methanol-water mixtures at 25 °c. I. Experimental part
    • C.L. De Ligny, P.F.M. Luykx, M. Rehbach, and A.A. Wieneke The pH of some standard solutions in methanol and methanol-water mixtures at 25 °C. I. experimental part Rec. Trav. Chim. 79 1960 713 726
    • (1960) Rec. Trav. Chim. , vol.79 , pp. 713-726
    • De Ligny, C.L.1    Luykx, P.F.M.2    Rehbach, M.3    Wieneke, A.A.4
  • 14
    • 84982383030 scopus 로고
    • The liquid-junction potentials between some buffer solutions in methanol and methanol-water mixtures and a saturated KCl solution in water at 25 °c
    • C.L. De Ligny, and M. Rehbach The liquid-junction potentials between some buffer solutions in methanol and methanol-water mixtures and a saturated KCl solution in water at 25 °C Rec. Trav. Chim. 79 1960 727 730
    • (1960) Rec. Trav. Chim. , vol.79 , pp. 727-730
    • De Ligny, C.L.1    Rehbach, M.2
  • 15
    • 0028406827 scopus 로고
    • 13C NMR spectroscopic study of chemical equilibria in solutions of formaldehyde in water, deuterium oxide, and methanol
    • 13C NMR spectroscopic study of chemical equilibria in solutions of formaldehyde in water, deuterium oxide, and methanol Ind. Eng. Chem. Res. 33 1994 1022 1029
    • (1994) Ind. Eng. Chem. Res. , vol.33 , pp. 1022-1029
    • Hahnenstein, I.1    Hasse, H.2    Kreiter, C.G.3    Maurer, G.4
  • 16
    • 0037208108 scopus 로고    scopus 로고
    • Quantitative NMR spectroscopy of complex liquid mixtures: Methods and results for chemical equilibria in formaldehyde-water-methanol at temperatures up to 383 K
    • M. Maiwald, H.H. Fischer, M. Ott, R. Peschla, C. Kuhnert, C.G. Kreiter, G. Maurer, and H. Hasse Quantitative NMR spectroscopy of complex liquid mixtures: methods and results for chemical equilibria in formaldehyde-water- methanol at temperatures up to 383 K Ind. Eng. Chem. Res. 42 2003 259 266
    • (2003) Ind. Eng. Chem. Res. , vol.42 , pp. 259-266
    • Maiwald, M.1    Fischer, H.H.2    Ott, M.3    Peschla, R.4    Kuhnert, C.5    Kreiter, C.G.6    Maurer, G.7    Hasse, H.8


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.