Highly diastereoselective allylic azide formation and isomerization. Synthesis of 3(2′-amino)-β-lactams

Organic Letters

Volumn 7, Issue 4, 2005, Pages 533-536

  Cardillo, Giuliana ^a   Fabbroni, Serena ^a   Gentilucci, Luca ^a   Perciaccante, Rossana ^a   Piccinelli, Fabio ^a   Tolomelli, Alessandra ^a  

^a UNIVERSITY OF BOLOGNA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

AMINO ACID DERIVATIVE; AZIDE; BETA LACTAM DERIVATIVE;

ALLYLATION; ARTICLE; CHROMATOGRAPHY; COMPLEX FORMATION; CORRELATION ANALYSIS; DENSITY GRADIENT CENTRIFUGATION; DIASTEREOISOMER; ENERGY YIELD; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; HYDROGENATION; ISOMERIZATION; MOLECULAR MECHANICS; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STEREOCHEMISTRY; STRUCTURE ANALYSIS; SUBSTITUTION REACTION; SYNTHESIS; X RAY ANALYSIS;

ALLYL COMPOUNDS; AMINES; BETA-LACTAMS; ISOMERISM; MODELS, MOLECULAR; MOLECULAR CONFORMATION; OXIDES; STEREOISOMERISM; X-RAY DIFFRACTION;

EID: 14844339773     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol047815n     Document Type: Article

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35. 2 = 1.037.
36. 3 (c 1.0); Chiralcel OD (Daicel column), cellulose tris(3,5-dimethyl-phenyl)carbamate phase coated on 10 μm silica gel, n-hexane/2-propanol 90:10 solvent mixture, flow 0.5 mL/min.