Chlorination of N-phenylbenzenesulfonamides with NCP in aqueous acetic acid. Using the para/meta ratio of substituent effects for mechanism elucidation

Collection of Czechoslovak Chemical Communications

Volumn 69, Issue 12, 2004, Pages 2253-2275

  Reis, João Carlos R ^a   Segurado, Manuel A P ^b   De Oliveira, Jaime D Gomes ^c   Kabilan, Senthamaraikannan ^d   Suganya, Krishnasamy ^d  

^a Centro de Electroquimica e Cinetica da Universidade de Lisboa   (Portugal)

^b RESEARCH INSTITUTE FOR MEDICINES IMED ULISBOA   (Portugal)

^c INSTITUTO SUPERIOR DE ENGENHARIA DE LISBOA   (Portugal)

^d ANNAMALAI UNIVERSITY   (India)

Author keywords

Chlorinations; DFT calculations; Electrostatic interactions; Kinetics; Linear free energy relationships; Reaction mechanisms; Substituent effects; Sulfonamides

Indexed keywords

ACETIC ACID; ANILINE DERIVATIVE; BENZENESULFONAMIDE DERIVATIVE; KETONE DERIVATIVE; PERCHLORIC ACID;

ACIDIFICATION; ARTICLE; CHEMICAL REACTION KINETICS; CHLORINATION; ELECTROCHEMICAL ANALYSIS; MATHEMATICAL MODEL; MOLECULAR MECHANICS; OXIDATION KINETICS; PROTON TRANSPORT; TEMPERATURE DEPENDENCE;

EID: 14844337094     PISSN: 00100765     EISSN: None     Source Type: Journal    
DOI: 10.1135/cccc20042253     Document Type: Article

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