Kinetics of the self-assembly of gemini surfactants

Journal of Surfactants and Detergents

Volumn 7, Issue 3, 2004, Pages 247-255

  Groth, C ^a   Nyden M ^a   Holmberg, K ^a   Kanicky, J R ^b   Shah, D O ^c,d  

^a CHALMERS UNIVERSITY OF TECHNOLOGY   (Sweden)

^b DuPont Titanium Technologies   (United States)

^c University of Florida   (United States)

^d UNIVERSITY OF FLORIDA   (United States)

Author keywords

Dimeric; Gemini surfactants; Kinetics of micellization; Lifetime of micelles; NMR; Self diffusion; Slow relaxation time; Stopped flow

Indexed keywords

CHEMICAL RELAXATION; DIFFUSERS (FLUID); DIMERS; ION EXCHANGE; MICELLES; NUCLEAR MAGNETIC RESONANCE; POSITIVE IONS; REACTION KINETICS; SELF ASSEMBLY;

GEMINI SURFACTANTS; MICELLAR SYSTEMS; SLOW RELAXATION TIME; STOPPED-FLOW TECHNIQUES;

SURFACE ACTIVE AGENTS;

ALKANE DERIVATIVE; ALKENE DERIVATIVE; BROMINE DERIVATIVE; CATIONIC SURFACTANT; DIMER; PHOSMET;

ANALYTIC METHOD; ARTICLE; FLOW KINETICS; LIFESPAN; MICELLE; MOLECULAR SIZE; NUCLEAR MAGNETIC RESONANCE; PULSED FIELD GEL ELECTROPHORESIS;

EID: 14844303767     PISSN: 10973958     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11743-004-0308-8     Document Type: Article

References (59)

1. James, A.D., B.H. Robinson, and N.C. White, Dynamics of Small Molecule Micelle Interactions - Charge and pH Effects on Kinetics of Interaction of Dyes with Micelles, J. Colloid Interface Sci. 59:328 (1977).
2. Patist, A., S.G. Oh, R. Leung, and D.O. Shah, Kinetics of Micellization: Its Significance to Technological Processes, Colloids Surfaces A 176:3 (2000).
3. Tondre, C., J. Lang, and R. Zana, Use of Dyes for Kinetic Study of Micellar Equilibria, J. Colloid Interface Sci. 52:372 (1975).
4. Hoffmann, H., R. Nagel, G. Platz, and W.J. Ulbricht, Kinetics of Micelle Formation of Alkylpyridinium Halides, Colloid Polym. Sci. 254:812 (1976).
5. Frindi, M., B. Michels, and R. Zana, Ultrasonic Absorption Studies of Surfactant Exchange Between Micelles and Bulk Phase in Aqueous Micellar Solutions of Amphoteric Surfactants, J. Phys. Chem. 98:6607 (1994).
6. Kato, S., S. Harada, and H. Sahara, Ultrasonic Relaxation and Volumetric Studies of the Micelle/Monomer Exchange Process in Aqueous Solutions of the Nonionic Surfactants C7E4, C8E4, and C8E5, J. Phys. Chem. 99:12570 (1995).
7. Lang, J., and R. Zana, Chemical Relaxation Methods, in Surfactants in Solution - New Methods of Investigation, edited by R. Zana, Marcel Dekker, New York, 1987.
8. Wyn-Jones, E., Chemical and Biological Aspects of Relaxation Spectroscopy, D. Reidel, London, 1975.
9. Mijnlieff, P.F., and R. Ditmarsch, Rate of Micelle Formation of Sodium Alkyl Sulphates in Water, Nature 208:889 (1965).
10. Kresheck, G.C., E. Hamori, G. Davenport, and H.A. Scheraga, Determination of Dissociation Rate of Dodecylpyridinium Iodide Micelles by a Temperature-Jump Technique, J. Am. Chem. Soc. 88:246 (1966).
11. Bennion, B.C., L.K.J. Tong, L.P. Holmes, and E.M. Eyring, Kinetics of Sodium Lauryl Sulfate Micelle Dissociation by a Light-Scattering Temperature-Jump Technique, J. Phys. Chem. 73:3288 (1969).
12. Bennion, B.C., and E.M. Eyring, Kinetics of Micelle Dissociation by a Light-Scattering Temperature-Jump Method, J. Colloid Interface Sci. 32:286 (1970).
13. Lang, J., and E.M. Eyring, Kinetics of Dissociation of Nonionic Detergent Micelles by a Temperature-Jump Technique, J. Polym. Sci. A-2 10:89 (1972).
14. Yasunaga, T., H. Oguri, and M. Miura, Acoustic Study on Kinetics for Dissociation-Recombination Reaction Between Micelle and Counterion in Sodium Dodecyl Sulfate Solution, J. Colloid Interface Sci. 23:352 (1967).
15. Yasunaga, T., S. Fujii, and M. Miura, Acoustic Study of Kinetics of Dissociation-Recombination Reaction Between Micelle and Counterion in Solutions of Sodium Salts of Fatty Acids - Sodium Caprylate and Sodium Caprate, J. Colloid Interface Sci. 30:399 (1969).
16. Zana, R., and J.C.R. Lang, Ultrasonic Absorption in Amphiphilic Ionic Aqueous Solutions, Acad. Sci., Ser. C 266:893 (1968).
17. Zana, R., and J.C.R. Lang, An Interpretation of Supersonic Absorption Measurements by Aqueous Solutions of Ionic Amphiphils, Acad. Sci., Ser. C 266:1347 (1968).
18. Lang, J., J.J. Auborn, and E.M. Eyring, Kinetics of Octylphenyl Polyoxyethylene Alcohol Micelle Dissociation by a Stopped-Flow Technique, J. Colloid Interface Sci. 41:484 (1972).
19. Yasunaga, T., K. Takeda, and S. Harada, Kinetic Study of Sodium Dodecyl Sulfate Micelle Dissociation by a Stopped-Flow Method, J. Colloid Interface Sci. 42:457 (1973).
20. Takeda, K., T.N. Tatsumo, and T. Yasunaga, Kinetic Study on Solubilization of Pinacyanol Chloride into Micelle of Sodium Dodecyl-Sulfate by a Stopped-Flow Technique, J. Colloid Interface Sci. 47:128 (1974).
21. Sams, P.J., E. Wyn-Jones, and J. Rassing, A New Model Describing the Kinetics of Micelle Formation from Chemical Relaxation Studies, Chem. Phys. Lett. 13:233 (1972).
22. Graber, E., and R. Zana, Ultrasonor Absorption in Aqueous Solutions of Ionic Amphiphiles. 2. Interpretation of Results Obtained for Weakly Concentrated Micellar Solutions, Kolloid-Z. Z. Polym. 238:479 (1970).
23. Muller, N., Kinetics of Micelle Dissociation by Temperature-Jump Techniques. Reinterpretation, J. Phys. Chem. 76:3017 (1972).
24. Teubner, M., S. Diekmann, and M. Kahlweit, Analysis of the Amplitudes in the Relaxation Processes in Micellar Solutions, Ber. Bunsenges. Phys. Chem. 82:1278 (1978).
25. Lang, J., C. Tondre, R. Zana,, R. Bauer, H. Hoffmann, and W.J. Ulbricht, Chemical Relaxation Studies of Micellar Equilibriums, J. Phys. Chem. 79:276 (1975).
26. Shah, D.O., Micelles, Microemulsions, and Monolayers: Quarter Century Progress at the University of Florida, in Micelles, Microemulsions, and Monolayers, edited by D.O. Shah, Marcel Dekker, New York, 1998, p. 1.
27. Oh, S.G., and D.O. Shah, The Effect of Micellar Lifetime on the Rate of Solubilization and Detergency in Sodium Dodecyl-Sulfate Solutions, J. Am. Oil Chem. Soc. 70:673 (1993).
28. Oh, S.G., and D.O. Shah, Relationship Between Micellar Lifetime and Foamability of Sodium Dodecyl-Sulfate and Sodium Dodecyl-Sulfate 1-Hexanol Mixtures, Langmuir 7:1316 (1991).
29. Oh, S.G., S.P. Klein, and D.O. Shah, Effect of Micellar Lifetime on the Bubble Dynamics in Sodium Dodecyl-Sulfate Solutions, AIChE J. 38:149 (1992).
30. Patel, S.S., K. Kumar, D.O. Shah, and J.J. Delfino, Effect of Surfactant Concentration and Film Area on the Stability of Films of Surfactant Solutions, J. Colloid Interface Sci. 183:603 (1996).
31. Nikolov, A.D., and D.T. Wasan, Ordered Micelle Structuring in Thin-Films Formed from Anionic Surfactant Solutions. 1. Experimental, J. Colloid Interface Sci. 133:1 (1989).
32. Nikolov, A.D., P.A. Kralchevsky, I.B. Ivanov, and D.T. Wasan, Ordered Micelle Structuring in Thin-Films Formed from Anionic Surfactant Solutions. 2. Model Development, J. Colloid Interface Sci. 133:13 (1989).
33. Oh, S.G., M. Jobalia, and D.O. Shah, The Effect of Micellar Lifetime on the Droplet Size in Emulsions, J. Colloid Interface Sci. 155:511 (1993).
34. Oh, S.G., and D.O. Shah, Effect of Micellar Lifetime on the Wetting Time of Cotton in Sodium Dodecyl Sulfate Solutions, Langmuir 8:1232 (1992).
35. Zana, R., Dimeric and Oligomeric Surfactants, Adv. Colloid Interface Sci. 97:205 (2002).
36. Rosen, M.J., Geminis - A New Generation of Surfactants, Chemtech 23:30 (1993).
37. Zana, R. and E.O. Alami, Gemini Surfactants, in Novel Surfactants: Preparation, Applications, and Biodegradability, 2nd edn., edited by K. Holmberg, Marcel Dekker, New York, 2003, p. 385.
38. Rosen, M.J., and D.J. Tracy, Gemini Surfactants, J. Surfact. Deterg. 1:547 (1998).
39. Menger, F.M., and J.S. Keiper, Gemini Surfactants, Angew. Chem. Int. Ed. 32:1906 (2000).
40. Fisicaro, E., C. Compari, B. Rozycka-Roszak, G. Viscardi, and P.L. Quagliotto, Chemico-physical and Biological Properties of Gemini Surfactants, Curr. Top. Colloid Interface Sci. 2:53 (1997).
41. Zana, R., Dimeric (Gemini) Surfactants: Effect of the Spacer Group on the Association Behavior in Aqueous Solution, J. Colloid Interface Sci. 248:203 (2002).
42. Zana, R., Dimeric and Oligomeric Surfactants. Behavior at Interfaces and in Aqueous Solution: A Review, Adv. Colloid Interface Sci. 97:203 (2002).
43. Bai, G., J. Wang, H. Yan, Z. Li, and R. Thomas, Thermodynamics of Molecular Self-Assembly of Cationic Gemini and Related Double Chain Surfactants in Aqueous Solution, J. Phys. Chem. B 105:3105 (2001).
44. Grosmaire, L., M. Chorro, C. Chorro, S. Partyka, and R. Zana, Thermodynamics of Micellization of Cationic Dimeric (Gemini) Surfactants, Progr. Colloid Polym. Sci. 115:31 (2000).
45. Camesano, T.A., and R. Nagarajan, Micelle Formation and CMC of Gemini Surfactants: A Thermodynamic Model, Colloids Surfaces A 167:165 (2000).
46. Devinsky, F., I. Lacko, F. Bittererova, and L. Tomeckova, Relationship Between Structure, Surface-Activity, and Micelle Formation of Some New Bisquaternary Isosteres of 1,5-Pentanediammonium Dibromides, J. Colloid Interface Sci. 114:314 (1986).
47. Zhu, Y.P., A. Masuyama, Y. Kobata, Y. Nakatsuji, M. Okahara, and M.J. Rosen, Double-Chain Surfactants with Two Carboxylate Groups and Their Relation to Similar Double-Chain Compounds, J. Colloid Interface Sci. 158:40 (1993).
48. Zana, R., Dimeric and Oligomeric Surfactants. Behavior at Interfaces and in Aqueous Solution: A Review, Adv. Colloid Interface Sci. 97:205 (2002).
49. Zana, R., and Y. Talmon, Dependence of Aggregate Morphology on Structure of Dimeric Surfactants, Nature 362:228 (1993).
50. Schmitt, V., F. Schosseler, F. Lequeux, Structure of Salt-Free Wormlike Micelles - Signature by Sans at Rest and Under Shear, Europhys. Lett. 30:31 (1995).
51. Frindi, M., B. Michels, H. Levy, R. Zana, Alkanediyl-α,ω- bis(dimethylalkylammonium bromide) Surfactants. 4. Ultrasonic Absorption Studies of Amphiphile Exchange Between Micelles and Bulk Phase in Aqueous Micellar Solution, Langmuir 10:1140 (1994).
52. Ulbricht, W., and R. Zana, Alkanediyl-α,ω- bis(dimethylalkylammonium bromide) Surfactants. Part 8. Pressure-Jump Study of the Kinetics of Micellar Equilibria in Aqueous Solutions of Alkanediyl-α, ω-bis(dimethyldodecylammonium bromide) Surfactants, Colloids Surfaces A 183-185:487 (2001).
53. Zana, R., M. Benrraou, and R. Rueff, Alkanediyl-α,ω- bis(dimethylalkylammonium bromide) Surfactants. 1. Effect of the Spacer Chain-Length on the Critical Micelle Concentration and Micelle Ionization Degree, Langmuir 7:1072 (1991).
54. Patist, A., Tailoring Micellar Stability to Control Interfacial Properties and Behavior of Dispersed Systems, Ph.D. Thesis, University of Florida, 1999.
55. Shinoda, K., and T. Nakagawa, Colloidal Surfactants: Some Physicochemical Properties, Academic Press, New York, 1963.
56. Hunter, R.J., Foundations of Colloid Science, Oxford University Press, New York, 1987.
57. Pusey, E., Colloidal Suspensions, in Liquids, Freezing, and Glass Transition, edited by J.P. Hansen, D. Levesque, and J. Zinn-Justin, Elsevier, Amsterdam, 1991.
58. Lekkerkerker, H.N.W, and J.K.G. Dhont, On the Calculation of the Self-Diffusion Coefficient of Interacting Brownian Particles, J. Chem. Phys. 80:5790 (1984).
59. Nydén, M., and O. Söderman, Structures and Emulsification Failure in the Microemulsion Phase in the Didodecyldimethylammonium Sulfate/Hydrocarbon/Water System. A Self-Diffusion NMR Study, Langmuir 11:1537 (1995).