Rapid and efficient solid-supported reagent synthesis of fluorine derivatives of phosphorus(V) compounds

Tetrahedron Letters

Volumn 46, Issue 13, 2005, Pages 2215-2217

  Sierakowski, Timothy ^a   Kiddle, James J ^a  

^a WESTERN MICHIGAN UNIVERSITY   (United States)

Author keywords

Chemical warfare agent; DFP; Nerve agent; Phosphonofluoridate; Phosphorus(V) fluoride; Synthesis

Indexed keywords

FLUORINE DERIVATIVE; PHOSPHORUS; REAGENT;

ARTICLE; CHEMICAL REACTION KINETICS; ION EXCHANGE; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; SOLID STATE; SYNTHESIS;

EID: 14744300002     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2005.02.026     Document Type: Article

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22. -] resin in 10 mL of THF was added the appropriate phosphorus(V) chloride (2.8 mmol) at room temperature. After the reaction mixture was stirred for the indicated time the mixture was filtered with suction, and the solvent removed under reduced pressure to furnish the isolated phosphorus(V) fluorides