Preparation of novel syndiotactic poly(vinyl alcohol) microspheres through the low-temperature suspension copolymerization or vinyl pivalate and vinyl acetate and heterogeneous saponification

Journal of Applied Polymer Science

Volumn 95, Issue 6, 2005, Pages 1539-1548

  Lee, Se Geun ^a   Kim, Jae Pil ^a   Lyoo, Won Seok ^b   Kwak, Jin Woo ^b   Noh, Seok Kyun ^b   Park, Chan Sik ^c   Kim, Jae Hyun ^c  

^a Seoul National University   (South Korea)

^b Yeungnam University   (South Korea)

^c Dongjin Semichem Co Ltd   (South Korea)

Author keywords

Heterogeneous saponification; Microspheres; P(VPi VAc); Skin core; Syndiotactic PVA

Indexed keywords

BLOOD VESSELS; COPOLYMERIZATION; COPOLYMERS; CRYOGENICS; MOLECULAR WEIGHT; MONOMERS; PARTICLE SIZE ANALYSIS; POLYMERIZATION; SAPONIFICATION; SKIN; SUSPENSIONS (FLUIDS); VINYL RESINS;

HETEROGENEOUS SAPONIFICATION; MICROSPHERES; POLY(VINYL PIVALATE/VINYL ACETATE) (P(VPI/VAC)); SKIN/CORE;

POLYVINYL ALCOHOLS;

COPOLYMERIZATION; POLYMER SCIENCE; POLYVINYL ALCOHOL;

EID: 14644424558     PISSN: 00218995     EISSN: None     Source Type: Journal    
DOI: 10.1002/app.21296     Document Type: Article

References (44)

1. Sakurada, I. In Polyvinyl Alcohol Fibers; Lewin, M., Ed.; Marcel Dekker: New York, 1985.
2. Martin, F. L. In Encyclopedia of Polymer Science and Technology; Mark, H. F.; Bikales, N. M.; Menges, C. G.; Kroschwitz, J. I., Eds.; Wiley: New York, 1985.
3. Masuda, M. In Polyvinyl Alcohol Development; Finch, C. A., Ed.; Wiley: New York, 1991.
4. Lyoo, W. S.; Kim, J. H.; Choi, J. H.; Kim, B. C.; Blackwell, J. Macromolecules 2001, 34, 3982.
5. Choi, J. H.; Ko, S. W.; Kim, B. C.; Blackwell, J.; Lyoo, W. S. Macromolecules 2001, 34, 2964.
6. Cho, J. D.; Lyoo, W. S.; Chvalun, S. N.; Blackwell, J. Macromolecules 1999, 32, 6236.
7. Lyoo, W. S.; Kim, B. C.; Ha, W. S. Polym Eng Sci 1997, 37, 1259.
8. Lyoo, W. S.; Kim, B. C.; Ha, W. S. Polym J 1997, 30, 424.
9. Lyoo, W. S.; Ha, W. S. Polymer 1996, 37, 3121.
10. Lyoo, W. S.; Han, S. S.; Choi, J. H.; Cho, Y. W.; Ha, W. S. J Korean Fiber Soc 1995, 32, 1023.
11. Lyoo, W. S.; Han, S. S.; Choi, J. H.; Ghim, H. D.; Yoo, S. W.; Lee, J.; Hong, S. I.; Ha, W. S. J Appl Polym Sci 2001, 80, 1003.
12. Lyoo, W. S.; Lee, S. M.; Koo, K.; Lee, J. S.; Ghim, H. D.; Kim, J. P.; Lee, J. J Appl Polym Sci 2001, 82, 1897.
13. Lyoo, W. S.; Ha, W. S. Fibers Polym 2001, 2, 108.
14. Lyoo, W. S.; Ha, W. S. J Korean Fiber Soc 1996, 33, 156.
15. Lyoo, W. S.; Kwark, Y. J.; Ha, W. S. J Korean Fiber Soc 1996, 33, 321.
16. Kim, S. G.; Lee, W. S.; Jo, S. M.; Kim, B. C.; Lyoo, W. S.; Han, J. R. J Korean Fiber Soc 1999, 36, 354.
17. Lyoo, W. S.; Blackwell, J.; Ghim, H. D. Macromolecules 1998, 31, 4253.
18. Lyoo, W. S.; Chvalun, S. N.; Ghim, H. D.; Kim, J. P.; Blackwell, J. Macromolecules 2001, 34, 2615.
19. Lyoo, W. S.; Ha, W. S. Polymer 1999, 40, 497.
20. Lyoo, W. S.; Ha, W. S. J Polym Sci Part A: Polym Chem 1997, 35, 55.
21. Lyoo, W. S.; Kim, J. H.; Ghim, H. D. Polymer 2001, 42, 6317.
22. Lyoo, W. S.; Kim, B. J.; Ha, W. S. J Korean Fiber Soc 1996, 33, 231.
23. Lyoo, W. S.; Yeum, J. H.; Ghim, H. D.; Ji, B. C; Yoon, W. S.; Kim, J. P. J Korean Fiber Soc 2000, 37, 487.
24. Ha, W. S.; Lyoo, W. S.; Choi, Y. G. U.S. Pat. 6, 124, 033 (2000).
25. Yamamoto, T.; Fukae, R.; Saso, T.; Sangen, O.; Kamachi, M.; Sato, T.; Fukunishi, Y. Polym J 1992, 24, 115.
26. Fukae, R.; Yamamoto, T.; Fujita, Y.; Kawatsuki, N.; Sangen, O.; Kamachi, M. Polym J 1997, 29, 293.
27. Sandler, S. R.; Karo, W. Polym Synth 1980, 3, 211.
28. Sakurada, L; Sakaguchi, Y.; Yamaguchi, K. Kobunshi Kagaku 1963, 20, 491.
29. Sandler, S. R.; Karo, W. Polymer Synthesis; Academic: New York, 1980.
30. Balaraman, K. S.; Kulkarni, B. D. J Polym Sci C: Polym Lett 1983, 21, 87.
31. Giannetti, E.; Mazzocchi, R. J Polym Sci Part A: Polym Chem 1986, 24, 2517.
32. Verma, S. K.; Arvindakshan, P.; Bisarya, S. C. J Appl Polym Sci 1992, 46, 702.
33. Dionisio, J. M.; O'Driscoll, K. F. J Polym Sci Part A: Polym Chem 1980, 18, 241.
34. Isabelle, M.; Richard, L. J Neurosurg 1992, 76, 607.
35. Kinoshita, A.; Yamada, K.; Ito, M.; Yamazaki, M.; Taneda, M.; Hayakawa, T. Neuroradiology 1994, 36, 65.
36. Brown, K. T.; Brody, L. A.; Decorate, D. R.; Getrajdman, G. I. J Vasc Interv Radiol 2001, 12, 882.
37. Barnard, C. N.; Schrire, V. Surgery 1968, 63, 727.
38. Castaneda-Zuniga, W. R.; Sanchez, R.; Amplatz, K. Radiology 1978, 126, 783.
39. Herrera, M.; Rysavy, J.; Kotula, F.; Rusnak, B.; Castaneda-Zuniga, W. R.; Amplatz, K. Radiology 1982, 144, 638.
40. Lanman, T. H.; Martin, N. A.; Vinters, H. V. Neuroradiology 1988, 33, 1.
41. Tomashefski, J. F.; Cohen, A. M.; Doershuk, C. F. Hum Pathol 1988, 19, 555.
42. Yamamoto, T.; Seki, S.; Fukae, R.; Sangen, O.; Kamachi, M. Polym J 1990, 22, 567.
43. Capek, I.; Riza, M.; Akashi, M. Makromol Chem 1992, 193, 2843.
44. Saenz, J. M.; Asua, J. M. J Polym Sci Part A: Polym Chem 1995, 33, 1511.