Heterogeneous ion-exchange membranes based on sulfonated poly(1,4-phenylene sulfide) and linear polyethylene: Preparation, oxidation stability, methanol permeability and electrochemical properties

Journal of Membrane Science

Volumn 250, Issue 1-2, 2005, Pages 151-157

  Schauer, Jan ^a   Brožová, Libuše ^a  

^a INSTITUTE OF MACROMOLECULAR CHEMISTRY   (Czech Republic)

Author keywords

Fuel cell; Ion exchange membrane; Membrane methanol permeability; Membrane oxidative stability; Sulfonated poly(1,4 phenylene sulfide)

Indexed keywords

BENZENE; CONCENTRATION (PROCESS); ELECTRIC CONDUCTIVITY; FUEL CELLS; IONIC CONDUCTION; MECHANICAL PERMEABILITY; METHANOL; OXIDATION; POLYETHYLENES; STRENGTH OF MATERIALS; SULFONATION; WATER;

CHLOROSULFONIC ACID; IONIC CONDUCTIVITY; SULFONATED PARTICLES;

ION EXCHANGE MEMBRANES;

METHANOL; POLY(1,4 PHENYLENE SULFIDE); POLYETHYLENE DERIVATIVE; SULFIDE; UNCLASSIFIED DRUG;

FUEL CELL; ION EXCHANGE; MEMBRANE TECHNOLOGY; METHANOL; OXIDATION; PERMEABILITY;

ARTICLE; CONDUCTANCE; ELECTROCHEMISTRY; ION EXCHANGE; LABORATORY TEST; MEMBRANE TRANSPORT; OXIDATION; PARTICLE SIZE; PRIORITY JOURNAL; SULFONATION;

EID: 14644423914     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2004.09.047     Document Type: Article

References (44)

1. G.G. Scherer Polymer membranes for fuel cells Ber. Bunsenges. Phys. Chem. 94 1990 1008 1014
2. C.H. Wirguin Recent advances in perfluorinated ionomer membranes: structure, properties and applications J. Membr. Sci. 120 1996 1 33
3. A.G. Guzman-Garcia, P.N. Pintauro, M.W. Verbrugge, and E.W. Schneider Analysis of radiation-grafted membranes for fuel cell electrolytes J. Appl. Electrochem. 22 1992 204 214
4. F.N. Büchi, B. Gupta, O. Haas, and G.G. Scherer Performance of differently cross-linked, partially fluorinated proton exchange membranes in polymer electrolyte fuel cells J. Electrochem. Soc. 142 1995 3044 3048
5. H.P. Brack, F.N. Büchi, M. Rota, and G.G. Scherer Development of radiation-grafted membranes for fuel cell applications based on poly(ethylene-alt-tetrafluoroethylene) Polym. Mater. Sci. Eng. 77 1997 368 369
6. T. Lehtinen, G. Sundholm, and F. Sundholm Effect of crosslinking on the physicochemical properties of proton conducting PVDF-g-PSSA membranes J. Appl. Electrochem. 29 1999 677 683
7. A.E. Steck, and C. Stone Development of BAM membrane for fuel cell applications Proceedings of the Second International Symposium on New Mater. Fuel Cell Modern Battery Syst. II Montreal, Canada 1997 792 807
8. C.A. Linkous Development of solid polymer electrolytes for water electrolysis at intermediate temperatures Int. J. Hydrogen Energy 18 1993 641 646
9. R. Nolte, K. Ledjeff, M. Bauer, and R. Mülhaupt Partially sulfonated poly(arylene ether sulfone) - a versatile proton conducting membrane material for modern energy conversion technologies J. Membr. Sci. 83 1993 211 220
10. F. Lufrano, G. Squadrito, A. Patti, and E. Passalacqua Sulfonated polysulfone as promising membranes for polymer electrolyte fuel cells J. Appl. Polym. Sci. 77 2000 1250 1257
11. F. Wang, M. Hickner, Y.S. Kim, T.A. Zawodzinski, and J.E. McGrath Direct polymerization of sulfonated poly(arylene ether sulfone) random (statistical) copolymers: candidates for new proton exchange membranes J. Membr. Sci. 197 2002 231 242
12. J.A. Kerres Development of ionomer membranes for fuel cells J. Membr. Sci. 185 2001 3 27
13. B. Kosmala, and J. Schauer Ion-exchange membranes prepared by blending sulfonated poly(2,6-dimethyl-1,4-phenylene oxide) with polybenzimidazole J. Appl. Polym. Sci. 85 2002 1118 1127
14. H.R. Allcock, M.A. Hofman, C.A. Ambler, S.N. Lvov, X.Y. Zhou, E. Chalkova, and J. Weston Phenyl phosphonic acid functionalized poly[aryloxyphosphazenes] as proton-conducting membranes for direct methanol fuel cells J. Membr. Sci. 201 2002 47 54
15. z+ by electrodialysis comparison with perfluorosulfonic membrane J. Membr. Sci. 160 1999 127 137
16. J.F. Blachot, O. Diat, J.-L. Putaux, A.-L. Rollet, L. Rubatat, C. Vallois, M. Muller, and G. Gebel Anisotropy of structure and transport properties in sulfonated polyimide membranes J. Membr. Sci. 214 2003 31 42
17. K.D. Kreuer On the development of proton conducting polymer membranes for hydrogen and methanol fuel cells J. Membr. Sci. 185 2001 29 39
18. G. Alberti, M. Casciola, L. Massinelli, and B. Bauer Polymeric proton conducting membranes for medium temperature fuel cells (110-160°C) J. Membr. Sci. 185 2001 73 81
19. L. Jörissen, V. Gogel, J. Kerres, and J. Garche New membranes for direct methanol fuel cells J. Power Sources 105 2002 267 273
20. J.S. Wainright, J.-T. Wang, D. Weng, R.F. Savinell, and M.H. Litt Acid-doped polybenzimidazoles: a new polymer electrolyte J. Electrochem. Soc. 142 1995 L121 L123
21. X. Glipa, B. Bonnet, B. Mula, D.J. Jones, and J. Rozière Investigation of the conduction properties of phosphoric and sulfuric acid doped polybenzimidazole J. Mater. Chem. 9 1999 3045 3049
22. R. Bouchet, and E. Siebert Proton conduction in acid doped polybenzimidazole Solid State Ionics 118 1999 287 299
23. M. Kawahara, J. Morita, M. Rikukawa, K. Sanui, and N. Ogata Synthesis and proton conductivity of thermally stable polymer electrolytes: poly(benzimidazole) complexes with strong acid molecules Electrochim. Acta 45 2000 1395 1398
24. 2 fuel cell using acid doped polybenzimidazole as polymer electrolyte Electrochim. Acta 41 1996 193 197
25. J.-T. Wang, J.S. Wainright, R.F. Savinell, and M. Litt A direct methanol fuel cell using acid doped polybenzimidazole as polymer electrolyte J. Appl. Electrochem. 26 1996 751 756
26. H.Z. Friedlander Membranes H.F. Mark N.G. Gaylord Encyclopedia of Polymer Science and Technology vol. 8 1968 Wiley New York 633
27. P.V. Vyas, B.G. Shah, G.S. Trivedi, P. Ray, S.K. Adhikary, and R. Rangarajan Characterization of heterogeneous anion-exchange membranes J. Membr. Sci. 187 2001 39 46
28. V.I. Zabolotsky, V.V. Nikonenko, and N.D. Pismenskaya On the role of the gravitational convection in the transfer enhancement of salt ions in the course of dilute solution electrodialysis J. Membr. Sci. 119 1996 171 181
29. J. Mitáš, M. Červenka, P. Koscielnak, and F. Toman Electrodialytic processes in the region of Dolni Rozinka Proceedings of the CHISA'97 Conference Srní, Czech Republic 1997 36 (in Czech)
30. B. Bonnet, D.J. Jones, J. Roziere, L. Tchicaya, G. Alberti, M. Casciola, L. Massinelli, B. Bauer, A. Peraio, and E. Ramunni Hybrid organic-inorganic membranes for a medium temperature fuel cell J. New Mater. Electrochem. Syst. 3 2000 87 92
31. P. Genova-Dimitrova, B. Baradie, D. Foscallo, C. Poinsignon, and J.Y. Sanchez Ionomeric membranes for proton exchange membrane fuel cell (PEMFC): sulfonated polysulfone associated with phosphatoantimonic acid J. Membr. Sci. 185 2001 59 71
32. S.M.J. Zaidi, S.D. Mikhailenko, G.P. Robertson, M.D. Guiver, and S. Kaliaguine Proton conducting composite membranes from polyether ether ketone and heteropolyacids for fuel cell applications J. Membr. Sci. 173 2000 17 34
33. O. Savadogo Emerging membranes for electrochemical systems: I. Solid polymer electrolyte membranes for fuel cell systems J. New Mater. Electrochem. Syst. 1 1998 47 66
34. M. Rikukawa, and K. Sanui Proton-conducting polymer electrolyte membranes based on hydrocarbon polymers Prog. Polym. Sci. 25 2000 1463 1502
35. H.W. Hill Jr., and D.G. Brady Poly(arylene sulfide)s 2nd ed. Mark Bikales Overberger Menges Encyclopedia of Polymer Science and Technology vol. 11 1988 Wiley New York 531 557
36. 2 J. Polym. Sci. A: Polym. Chem. 27 1989 3043 3051
37. K. Miyatake, H. Iyotani, K. Yamamoto, and E. Tsuchida Synthesis of poly(phenylene sulfide sulfonic acid) via poly(sulfonium cation) as a thermostable proton-conducting polymer Macromolecules 29 1996 6969 6971
38. K. Sakai Review. Determination of pore size and pore size distribution. 2. Dialysis membranes J. Membr. Sci. 96 1994 91 130
39. 2Cl groups J. Macromol. Sci., Pure Appl. Chem. 33 1996 789 802
40. 2 valence vibrations in the ir spectra of aromatic sulfonyl chlorides Spectrochim. Acta A 24 1968 1501 1515
41. B. Mattsson, H. Ericson, L.M. Torell, and F. Sundholm Degradation of a fuel cell membrane, as revealed by micro-Raman spectroscopy Electrochim. Acta 45 2000 1405 1408
42. G. Hübner, and E. Roduner EPR investigation of HO radical initiated degradation reactions of sulfonated aromatics as model compounds for fuel cell proton conducting membranes J. Mater. Chem. 9 1999 409 418
43. R.B. Hodgdon Jr. Polyelectrolytes prepared from perfluoroalkylaryl macromolecules J. Polym. Sci. A 6 1 1968 171 191
44. R.A. Assink, C. Arnold Jr., and R.P. Hollandsworth Preparation of oxidatively stable cation-exchange membranes by the elimination of tertiary hydrogens J. Membr. Sci. 56 1991 143 151