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Volumn 37, Issue 7, 2004, Pages 2329-2331

Novel Anionic Ring-Opening Polymerization of Seven-Membered Monothiocarbonate Depending on Initiators

Author keywords

[No Author keywords available]

Indexed keywords

INFRARED SPECTROSCOPY; INITIATORS (CHEMICAL); ISOMERIZATION; MOLECULAR WEIGHT; MONOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PRECIPITATION (CHEMICAL); RING OPENING POLYMERIZATION; SULFUR;

EID: 14644403330     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma049832y     Document Type: Article
Times cited : (8)

References (25)
  • 17
    • 0021533291 scopus 로고
    • Ivin, K. J., Saegusa, T., Eds.; Elsevier: London
    • Sigwalt, P.; Spassky, S. In Ring-Opening Polymerization; Ivin, K. J., Saegusa, T., Eds.; Elsevier: London, 1984; Vol. 2, p 603.
    • (1984) Ring-opening Polymerization , vol.2 , pp. 603
    • Sigwalt, P.1    Spassky, S.2
  • 20
    • 16544373864 scopus 로고    scopus 로고
    • note
    • 2S: C, 45.43; H, 6.10; S, 24.26. Found: C, 45.42; H, 6.28; S, 24.05.
  • 21
    • 16544386137 scopus 로고    scopus 로고
    • note
    • 2S: C, 45.43; H, 6.10; S, 24.26. Found: C, 45.61; H, 6.24; S, 24.05.
  • 22
    • 16544376413 scopus 로고    scopus 로고
    • note
    • Isomerization of a five-membered analogue of 7TC, 1,3-dioxoran-2-thione, takes place by treatment with KI. See ref 6. For other catalytic isomerization of thiocarbonyl moieties in thiocarbonates to carbonyl moieties, see refs 23 and 24.
  • 25
    • 16544377262 scopus 로고    scopus 로고
    • note
    • This kind of difference in the polymerization pathway was also observed in the anionic polymerization of ε-thiono-caprolactone, in which nucleophilicity of the initiators was discussed. For details see ref 13.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.