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16544373864
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note
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2S: C, 45.43; H, 6.10; S, 24.26. Found: C, 45.42; H, 6.28; S, 24.05.
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21
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16544386137
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note
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2S: C, 45.43; H, 6.10; S, 24.26. Found: C, 45.61; H, 6.24; S, 24.05.
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22
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16544376413
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note
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Isomerization of a five-membered analogue of 7TC, 1,3-dioxoran-2-thione, takes place by treatment with KI. See ref 6. For other catalytic isomerization of thiocarbonyl moieties in thiocarbonates to carbonyl moieties, see refs 23 and 24.
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24
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0030759402
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Sato, Y.4
Kakimoto, K.5
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25
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16544377262
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note
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This kind of difference in the polymerization pathway was also observed in the anionic polymerization of ε-thiono-caprolactone, in which nucleophilicity of the initiators was discussed. For details see ref 13.
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