Characterization of a succinyl-CoA radical-Cob(II)alamin spin triplet intermediate in the reaction catalyzed by adenosylcobalamin-dependent methylmalonyl-CoA mutase

Biochemistry

Volumn 44, Issue 9, 2005, Pages 3153-3158

  Mansoorabadi, Steven O ^a   Padmakumar, Rugmini ^b   Fazliddinova, Nisso ^b   Vlasie, Monica ^b   Banerjee, Ruma ^b   Reed, George H ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

^b UNIVERSITY OF NEBRASKA LINCOLN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BIOCHEMISTRY; CATALYSIS; COMPUTER SIMULATION; DEUTERIUM; ELECTRON SPIN RESONANCE SPECTROSCOPY; SUBSTITUTION REACTIONS;

ADENOSYLCOBALAMIN (ADOCBL); ELECTRON-ELECTRON SPIN COUPLING; EULER ANGLES; ZERO-FIELD SPLITTING (ZFS);

ENZYME KINETICS;

COBAMAMIDE; HOLOENZYME; METHYLMALONYL COENZYME A MUTASE;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; ELECTRON SPIN RESONANCE; ENZYME ACTIVITY; ENZYME MECHANISM; ENZYME PURIFICATION; ENZYME SYNTHESIS; PRIORITY JOURNAL; SIMULATION;

ACYL COENZYME A; BACTERIAL PROTEINS; BINDING SITES; CARBON ISOTOPES; CATALYSIS; COBALT; COBAMIDES; COENZYME A LIGASES; DEUTERIUM; ELECTRON SPIN RESONANCE SPECTROSCOPY; FREE RADICALS; METHYLMALONYL-COA MUTASE; MODELS, MOLECULAR; SPIN LABELS; SUBSTRATE SPECIFICITY; VITAMIN B 12;

EID: 14644401110     PISSN: 00062960     EISSN: None     Source Type: Journal    
DOI: 10.1021/bi0482102     Document Type: Article

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