Tertiary amine-initiated zwitterionic polymerization of pivalolactone - A reinvestigation by means of MALDI-TOF mass spectrometry

Journal of Macromolecular Science - Pure and Applied Chemistry

Volumn 42 A, Issue 2, 2005, Pages 139-148

  Kricheldorf, Hans R ^a   Garaleh, Mazen ^a   Schwarz, Gert ^a  

^a UNIVERSITY OF HAMBURG   (Germany)

Author keywords

MALDI TOF; Pivalolactone; Ring opening polymerization; Zwitterions

Indexed keywords

AMINATION; ANIONIC POLYMERIZATION; CARBON DIOXIDE; KETONES; MASS SPECTROMETRY; RING OPENING POLYMERIZATION; SOLVENTS;

MALDI-TOF; PIVALOLACTONE; REACTION PRODUCTS; ZWITTERIONS;

POLYMERIZATION;

EID: 14544293059     PISSN: 10601325     EISSN: None     Source Type: Journal    
DOI: 10.1081/MA-200046969     Document Type: Article

References (20)

1. Gresham, T.L.; Janssen, J.E.; Shaver, W.; Bankert, R.A.; Fiedrorek, F.T. β-propiolactone. XI. reactions with ammonia and amines. J. Amer. Chem. Soc. 1951, 73, 3168-3171.
2. Etienne, Y.P.; Soulas, R.M.; Thiebaut, R.J. Linear polypropiolactone. Polym. Sci. C 1963, 4, 1061.
3. Yamashitu, Y.; Ito, K.; Nakakita, F. Initiation mechanism for the anionic polymerization of β-propiolactone by pyridine. Makromol. Chem. 1969, 127, 292-295.
4. Boehlke, K.; Han, M.J.; Jaacks, V.; Mathes, N.; Zimmerschied, K. Über die bildung von Makro-Zwitterionen bei ionischen polymerisationen. Angew. Chem. 1969, 81, 336-337.
5. Mathes, N.; Jaacks, V. Macrozwitterions. 4. Formation of macrozwitterions in the polymerization of β-propiolactone initiated by betaine. Makromol. Chem. 1971, 142, 209-225.
6. Eisenbach, C.D.; Schnecko, H.; Kern, W. Studies of macrozwitterion preparation by using 3-dimethylaminopropyllithium, a new initiator for polymer synthesis. Polym. Preprints (Amer. Chem. Soc., Div. Polym. Chem.) 1975, 16 (2), 13-17.
7. Eisenbach, C.D.; Schnecko, H.; Kern, W. Versuch der darstellung von makrozwitterionen mit hilfe von dimethylaminopropyl-lithium, einem neuartigen initiator. Chemiker-Zeitung 1975, 99, 241.
8. Saegusa, T.; Ikeda, H.; Fuju, H. Alternating copolymerization of 2-oxazoline with β-propiolactone. Macromolecules 1972, 5 (4), 354-358.
9. Saegusa, T.; Kobayashi, S.; Kimura, Y. Polymerization via betaine. II. alternating copolymerization of 2-oxazoline with β-lactones. Macromolecules 1974, 7, 1-4.
10. Saegusa, T.; Kobayashi, S.; Kimura, Y.; Ikeda, H. No catalyst copolymerization by spontaneous initiation. New method of preparation of alternating copolymers. J. Macromol. Sci. Chem. 1975, A9 (5), 641-661.
11. Saegusa, T.; Kimura, Y.; Kobayashi, S. Polymerization via Zwitterion. 14. Alternating copolymerizations of cyclic imino ethers with acrylic acid and with β-propiolactone. Macromolecules 1977, 10 (2), 236-239.
12. Wilson, D.R.; Beaman, R.G. Cyclic amine initiation of polypivalolactone. J. Polym. Sci. Part A-1 1970, 8, 2161-2170.
13. Johnston, D.S. Macrozwitterion polymerization. Adv. Polym. Sci. 1982, 42, 51-106.
14. Han, M.J.; Chang, J.Y.; Lee, Y.Y. Formation of macrozwitterions in the cationic polymerization of 2-methyl-2-oxazoline initiated by O-sulfobenzoic anhydride. Macromolecules 1982, 15, 255-258.
15. McEwen, I.J. Alternating copolymers from macrozwitterions. Progr. Polym. Sci. 1984, 10, 317-340.
16. Odian, G.; Gunatillake, P.A. Zwitterion Polymerization of 2-methyl-2-oxazoline and acrylic acid. Macromolecules 1984, 17, 1297-1307.
17. Endo, T.; Fukuda, H.; Hirota, M. Reaction of cyclic ketene acetal and carbon disulfide through macrozwitterion. J. Amer. Chem. Soc. 1984, 106, 4035-4036.
18. Miura, M.; Akutsu, F.; Kunimoto, F.; Ito, H.; Nagakubo, K. Grafting via macrozwitterions. Graft copolymerization of acrylic acid from diphenyl-4-vinylphenylphosphine sites on a polymer backbone. Makromol. Chem., Rapid Commun. 1984, 5, 109-117.
19. Tijsma, E.J.; Van der Does, L.; Bantjes, A. Synthesis, structure, and properties of polymers based on pivalolactone. J.M.S.-Rev. Macrom. Chem. Phys. 1994, 34, 515-553.
20. Kricheldorf, H.R.; Schwarz, G. Cyclic Polymers by kinetically controlled step-growth polymerization. Macromol. Rapid Commun. 2003, 24, 359-381.