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19
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14544291497
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note
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0 > 1 mm.
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20
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2342590725
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Fialkowski, M.; Campbell, C. J.; Bensemann, I. T.; Grzybowski, B. A. Langmuir 2004, 20, 3513.
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Fialkowski, M.1
Campbell, C.J.2
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Grzybowski, B.A.4
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21
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14544286832
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note
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3 solution placed on dry gelatin did not produce PP patterns. Immediately after application, a thick layer of precipitate formed along the perimeter of each drop; this layer prevented the transport of silver cations into the gel (and also the spreading of the droplet).
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-
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22
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14544303633
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note
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(i) Stamps were prepared from an 8% w/w solution of high-strengthgel agarose (OmniPur, EM Science, Darmstadt, Germany) in deionized water. This solution was heated in a microwave chamber for 90 s to dissolve the agarose and then degassed for 40 s to remove air bubbles. Next, an 8-mm-thick layer of the hot solution was poured onto the surface of an oxidized PDMS (poly(dimethylsilioxane)) master having the negative of the desired bas-relief pattern embossed on its surface. After gelation at room temperature, the layer was cut into 1 cm × 1 cm stamps. (ii) Thin gelatin films were prepared from a 10% w/w solution of gelatin (gelatin B, Bloom, Sigma-Aldrich) in deionized water. This solution was stirred and heated to 75 °C for 30 min before potassium dichromate (0.5% w/w) was added. The mixture was heated for another 3 min, poured onto the surface of an oxidized Petri dish (VWR), and dried under vacuum for 24 h.
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-
-
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23
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14544297396
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note
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w through a theoretical model described in detail in ref 20.
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-
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24
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14544290516
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-
note
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0≈d/(D + d) before PP starts.
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-
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25
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14544282857
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note
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35 suggested that this layer has a different molecular structure than the bulk of the gel; anomalous wetting and absorptivity properties of this layer reflect this difference.
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-
-
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26
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14544305524
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note
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+ cations below the stamped feature are constantly being depleted, the flux of silver ions entering the gel does not change appreciably as long as the reaction front propagates.
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27
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14544297837
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note
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7 left therein.
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28
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14344281117
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Droz, M.; Magnin, J.; Zrinyi, M. J. Chem. Phys. 1999, 110, 9618.
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Droz, M.1
Magnin, J.2
Zrinyi, M.3
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30
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14544280159
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note
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The alternative, post-nucleation model is not able to account for the observed scaling laws.
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31
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14544271873
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note
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1 = 0.9.
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33
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0037471074
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Grzybowski, B. A.; Wiles, J. A.; Whitesides, G. M. Phys. Rev. Lett. 2003, 90, 083903.
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Phys. Rev. Lett.
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Grzybowski, B.A.1
Wiles, J.A.2
Whitesides, G.M.3
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35
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0037435687
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Harmon, M. E.; Kuckling, D.; Frank, C. W. Macromolecules 2003, 36, 162.
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Harmon, M.E.1
Kuckling, D.2
Frank, C.W.3
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