-
3
-
-
0036149685
-
-
(c) Fulton, J. R.; Holland, A. W.; Fox, D. J.; Bergman, R. G. Acc. Chem. Res. 2002, 35, 44.
-
(2002)
Acc. Chem. Res.
, vol.35
, pp. 44
-
-
Fulton, J.R.1
Holland, A.W.2
Fox, D.J.3
Bergman, R.G.4
-
6
-
-
0013272402
-
-
Togni, A., Grützmacher, H., Eds.; Wiley-VCH: Weinheim, Germany
-
Tani, K.; Kataoka, Y. In Catalytic Heterofunctionalization; Togni, A., Grützmacher, H., Eds.; Wiley-VCH: Weinheim, Germany, 2001.
-
(2001)
Catalytic Heterofunctionalization
-
-
Tani, K.1
Kataoka, Y.2
-
9
-
-
0034822546
-
-
(a) Zhao, J.; Hesslink, H.; Hartwig, J. F. J. Am. Chem. Soc. 2001, 123, 7220.
-
(2001)
J. Am. Chem. Soc.
, vol.123
, pp. 7220
-
-
Zhao, J.1
Hesslink, H.2
Hartwig, J.F.3
-
12
-
-
0000706580
-
-
(d) Bryndza, H. E.; Calabrese, J. C.; Marsi, M.; Roe, D. C.; Tam, W.; Bercaw, J. E. J. Am. Chem. Soc. 1986, 108, 4805.
-
(1986)
J. Am. Chem. Soc.
, vol.108
, pp. 4805
-
-
Bryndza, H.E.1
Calabrese, J.C.2
Marsi, M.3
Roe, D.C.4
Tam, W.5
Bercaw, J.E.6
-
15
-
-
0025248621
-
-
(a) Kim, Y.-J.; Osakada, K.; Takenaka, A.; Yamamoto, A. J. Am. Chem. Soc. 1990, 112, 1096.
-
(1990)
J. Am. Chem. Soc.
, vol.112
, pp. 1096
-
-
Kim, Y.-J.1
Osakada, K.2
Takenaka, A.3
Yamamoto, A.4
-
16
-
-
0000699661
-
-
(b) Kim, Y.-J.; Osakada, K.; Sugita, K.; Yamamoto, T.; Yamamoto, A. Organometallics 1988, 7, 2182.
-
(1988)
Organometallics
, vol.7
, pp. 2182
-
-
Kim, Y.-J.1
Osakada, K.2
Sugita, K.3
Yamamoto, T.4
Yamamoto, A.5
-
17
-
-
0001194637
-
-
(c) Komiya, S.; Akai, Y.; Tanaka, K.; Yamamoto, T.; Yamamoto, A. Organometallics 1985, 4, 1130.
-
(1985)
Organometallics
, vol.4
, pp. 1130
-
-
Komiya, S.1
Akai, Y.2
Tanaka, K.3
Yamamoto, T.4
Yamamoto, A.5
-
19
-
-
0038698792
-
-
Smith, G. D.; Hanson, B. E.; Merola, J. S.; Waller, F. J. Organometallics 1993, 12, 568.
-
(1993)
Organometallics
, vol.12
, pp. 568
-
-
Smith, G.D.1
Hanson, B.E.2
Merola, J.S.3
Waller, F.J.4
-
20
-
-
0030604646
-
-
Kapteijn, G. M.; Dervisi, A.; Verhoef, M. J.; van den Broek, M. A. F. H.; Grove, D. M.; van Koten, G. J. Organomet. Chem. 1996, 517, 123.
-
(1996)
J. Organomet. Chem.
, vol.517
, pp. 123
-
-
Kapteijn, G.M.1
Dervisi, A.2
Verhoef, M.J.3
Van Den Broek, M.A.F.H.4
Grove, D.M.5
Van Koten, G.6
-
21
-
-
0029890191
-
-
Dockter, D. W.; Fanwick, P. E.; Kubiak, C. P. J. Am. Chem. Soc. 1996, 118, 4846.
-
(1996)
J. Am. Chem. Soc.
, vol.118
, pp. 4846
-
-
Dockter, D.W.1
Fanwick, P.E.2
Kubiak, C.P.3
-
24
-
-
0000185976
-
-
Michelin, R. A.; Napoli, M.; Ros, R. J. Organomet. Chem. 1979, 175, 239.
-
(1979)
J. Organomet. Chem.
, vol.175
, pp. 239
-
-
Michelin, R.A.1
Napoli, M.2
Ros, R.3
-
26
-
-
0344239538
-
-
(b) Huang, T.-M.; You, Y.-J.; Yang, C.-S.; Tzeng, W.-H.; Chen, J.-T.; Cheng, M.-C.; Wang, Y. Organometallics 1991, 10, 1020.
-
(1991)
Organometallics
, vol.10
, pp. 1020
-
-
Huang, T.-M.1
You, Y.-J.2
Yang, C.-S.3
Tzeng, W.-H.4
Chen, J.-T.5
Cheng, M.-C.6
Wang, Y.7
-
27
-
-
0037716645
-
-
Yasuda, H.; Choi, J.-C.; Lee, S.-C.; Sakakura, T. Organometallics 2002, 21, 1216.
-
(2002)
Organometallics
, vol.21
, pp. 1216
-
-
Yasuda, H.1
Choi, J.-C.2
Lee, S.-C.3
Sakakura, T.4
-
28
-
-
0000383322
-
-
(a) Bennett, M. A.; Jin, H.; Li, S.; Rendina, L. M.; Willis, A. C. J. Am. Chem. Soc. 1995, 117, 8335.
-
(1995)
J. Am. Chem. Soc.
, vol.117
, pp. 8335
-
-
Bennett, M.A.1
Jin, H.2
Li, S.3
Rendina, L.M.4
Willis, A.C.5
-
31
-
-
0038023343
-
-
Baerends, E. J.; Ellis, D. E.; Ros, P. Chem. Phys. 1973, 2, 41.
-
(1973)
Chem. Phys.
, vol.2
, pp. 41
-
-
Baerends, E.J.1
Ellis, D.E.2
Ros, P.3
-
33
-
-
0032221816
-
-
(c) Fonseca Guerra, C.; Snijders, J. G.; te Velde, G.; Baerends, E. J. Theor. Chem. Acta 1998, 99, 391.
-
(1998)
Theor. Chem. Acta
, vol.99
, pp. 391
-
-
Fonseca Guerra, C.1
Snijders, J.G.2
Te Velde, G.3
Baerends, E.J.4
-
38
-
-
30244483094
-
-
(a) Snijders, J. G.; Baerends, E. K.; Ros, P. Mol. Phys. 1979, 38, 1909.
-
(1979)
Mol. Phys.
, vol.38
, pp. 1909
-
-
Snijders, J.G.1
Baerends, E.K.2
Ros, P.3
-
39
-
-
0344178884
-
-
(b) Ziegler, T.; Tschinke, V.; Baerends, E. J.; Snijders, J. G.; Ravenek, W. J. Phys. Chem. 1989, 93, 3050.
-
(1989)
J. Phys. Chem.
, vol.93
, pp. 3050
-
-
Ziegler, T.1
Tschinke, V.2
Baerends, E.J.3
Snijders, J.G.4
Ravenek, W.5
-
40
-
-
0037880444
-
-
(c) van Lenthe, E.; Baerends, E. J.; Snijders, J. G. J. Chem. Phys. 1993, 99, 4597.
-
(1993)
J. Chem. Phys.
, vol.99
, pp. 4597
-
-
Van Lenthe, E.1
Baerends, E.J.2
Snijders, J.G.3
-
43
-
-
1442311831
-
-
note
-
The computed geometries were not significantly altered through use of either larger basis sets (ADF basis sets IV and V on the ligands) or the PW91 and BLYP functionals.
-
-
-
-
44
-
-
1442287247
-
-
note
-
We did initially search for five-coordinate forms of Pt(Me)(OMe)-(CO)(dhpe) and located one species with both chelate arms and CO in equatorial positions (E = -3.5 kcal/mol). However, it is not clear how such a species could be formed directly from 1. This five-coordinate species can be formed from 2c by recoordination of the remote phosphine arm.
-
-
-
-
45
-
-
1442360711
-
-
note
-
We thank Prof. C. J. Elsevier for emphasizing the importance of this isomerization process to us.
-
-
-
-
46
-
-
1442336280
-
-
note
-
We rejected the possibility of complete decoordination of the chelating phosphine to give a three-coordinate species, {Pt(CO)(Me)-(OMe)}, which could itself then rearrange on the grounds of the highly unfavorable entropy that would be associated with chelate loss.
-
-
-
-
48
-
-
0025248621
-
-
(a) Kim, Y.-J.; Osakada, K.; Takenaka, A.; Yamamoto, A. J. Am. Chem. Soc. 1990, 112, 1096.
-
(1990)
J. Am. Chem. Soc.
, vol.112
, pp. 1096
-
-
Kim, Y.-J.1
Osakada, K.2
Takenaka, A.3
Yamamoto, A.4
-
49
-
-
0000375699
-
-
(b) Braun, T.; Parsons, S.; Perutz, R. N.; Voith, M. Organometallics 1999, 18, 1710.
-
(1999)
Organometallics
, vol.18
, pp. 1710
-
-
Braun, T.1
Parsons, S.2
Perutz, R.N.3
Voith, M.4
-
50
-
-
0031593030
-
-
(c) Holland, P. L.; Andersen, R. A.; Bergman, R. G.; Huang, J. Nolan, S. P. J. Am. Chem. Soc. 1997, 119, 12800.
-
(1997)
J. Am. Chem. Soc.
, vol.119
, pp. 12800
-
-
Holland, P.L.1
Andersen, R.A.2
Bergman, R.G.3
Huang, J.4
Nolan, S.P.5
-
51
-
-
33751499202
-
-
(d) Segilson, A. L.; Cowan, R. L.; Trogler, W. C. Inorg. Chem. 1991, 30, 3371.
-
(1991)
Inorg. Chem.
, vol.30
, pp. 3371
-
-
Segilson, A.L.1
Cowan, R.L.2
Trogler, W.C.3
-
52
-
-
0036471571
-
-
(e) Cámpora, J.; López, J. A.; Maya, C.; Palma, P.; Carmona, E.; Valerga, P. J. Organomet. Chem. 2002, 643, 331.
-
(2002)
J. Organomet. Chem.
, vol.643
, pp. 331
-
-
Cámpora, J.1
López, J.A.2
Maya, C.3
Palma, P.4
Carmona, E.5
Valerga, P.6
-
53
-
-
0031593023
-
-
(f) Holland, P. L.; Smith, M. E.; Andersen, R. A.; Bergman, R. G. J. Am. Chem. Soc. 1997, 119, 12815.
-
(1997)
J. Am. Chem. Soc.
, vol.119
, pp. 12815
-
-
Holland, P.L.1
Smith, M.E.2
Andersen, R.A.3
Bergman, R.G.4
-
54
-
-
1442311830
-
-
note
-
Details of 8b and 8c and their related transition states are given as Supporting Information.
-
-
-
-
55
-
-
1442287246
-
-
note
-
R = 21.4 kcal/mol, respectively).
-
-
-
-
56
-
-
1442287248
-
-
note
-
2 (by 2.8 kcal/mol) can again be understood in terms of the stronger C-O bond formed compared to the C-C bond formed in the acyl.
-
-
-
-
57
-
-
35549009616
-
-
Carson, A. S.; Fine, D. H.; Gray, P.; Laye, P. G. J. Chem. Soc. B 1971, 1611.
-
(1971)
J. Chem. Soc. B
, pp. 1611
-
-
Carson, A.S.1
Fine, D.H.2
Gray, P.3
Laye, P.G.4
-
58
-
-
0003998388
-
-
Weast, R. C., Ed.; CRC Press: Boca Raton, FL
-
CRC Handbook of Chemistry and Physics; Weast, R. C., Ed.; CRC Press: Boca Raton, FL, 1981.
-
(1981)
CRC Handbook of Chemistry and Physics
-
-
-
59
-
-
0034339551
-
-
(a) Kajiyama, K.; Hirai, Y.; Otsuka, T.; Yuge, H.; Miyamoto, T. K. Chem. Lett. 2000, 29, 784.
-
(2000)
Chem. Lett.
, vol.29
, pp. 784
-
-
Kajiyama, K.1
Hirai, Y.2
Otsuka, T.3
Yuge, H.4
Miyamoto, T.K.5
-
62
-
-
0000426436
-
-
(b) Faw, R.; Montgomery, C. D.; Rettig, S. J.; Shurmer, B. Inorg. Chem. 1998, 37, 4136.
-
(1998)
Inorg. Chem.
, vol.37
, pp. 4136
-
-
Faw, R.1
Montgomery, C.D.2
Rettig, S.J.3
Shurmer, B.4
-
63
-
-
0037824580
-
-
(c) Kajiyama, K.; Nakamoto, A.; Miyazawa, S.; Miyamoto, T. K. Chem. Lett. 2003, 32, 332.
-
(2003)
Chem. Lett.
, vol.32
, pp. 332
-
-
Kajiyama, K.1
Nakamoto, A.2
Miyazawa, S.3
Miyamoto, T.K.4
-
64
-
-
0001452631
-
-
(d) Toyota, K.; Yamamoto, Y.; Akiba, K. J. Organomet. Chem. 1999, 586, 171.
-
(1999)
J. Organomet. Chem.
, vol.586
, pp. 171
-
-
Toyota, K.1
Yamamoto, Y.2
Akiba, K.3
-
65
-
-
33845377914
-
-
(e) Lattman, M.; Morse, S. A.; Cowley, A. H.; Lasch, J. G.; Norman, N. C. Inorg. Chem. 1985, 24, 1364.
-
(1985)
Inorg. Chem.
, vol.24
, pp. 1364
-
-
Lattman, M.1
Morse, S.A.2
Cowley, A.H.3
Lasch, J.G.4
Norman, N.C.5
-
67
-
-
0001432963
-
-
(a) Vierling, P.; Riess, J. G.; Grand, A. Inorg. Chem. 1986, 25, 4144.
-
(1986)
Inorg. Chem.
, vol.25
, pp. 4144
-
-
Vierling, P.1
Riess, J.G.2
Grand, A.3
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