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The generalization of our discussion for this case, when the polymer exhibits a lower Θ-point, i.e., a precipitate with decreasing temperature, is straightforward.
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ad in the chain consisting of N monomers and applying the Stirling approximation.
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As the surfactants are charged, the variation of the surfactant concentration changes, generally speaking, the ionic strength of the solution. However, typically the concentration of added salt is much higher than CAC so that the screening of the Coulomb interactions in the solution are dominated by salt ions. Therefore we can consider the surfactant concentration and the ionic strength of the solution as two independent parameters.
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We are thankful to B. Dünweg who has attracted our attention to this analogy.
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