Efficient synthesis of functionalised 4-hydroxycyclopent-2-en-1-ones by cyclisation of 1,3-bis(silyl) enol ethers and 1,3-dicarbonyl dianions with 1,2-diketones

European Journal of Organic Chemistry

Volumn , Issue 3, 2005, Pages 532-542

  Holtz, Edith ^a   Köhler, Valentin ^a   Appel, Bettina ^a   Langer, Peter ^a,b  

^a UNIVERSITY OF GREIFSWALD   (Germany)

^b UNIVERSITY OF ROSTOCK   (Germany)

Author keywords

Aldol reactions; Cyclisations; Dianions; Regioselectivity; Silyl enol ethers

Indexed keywords

1,2 DIKETONE DERIVATIVE; 1,3 BIS(SILYL) ENOL ETHER; 1,3 DICARBONYL DERIVATIVE; 4 HYDROXYCYCLOPENT 2 EN 1 ONE DERIVATIVE; CARBONYL DERIVATIVE; CYCLOPENTENONE DERIVATIVE; DIKETONE; ETHER DERIVATIVE; ETHYL 3 HYDROXY 2,3 DIMETHYL 5 OXOCYCLOPENT 1 ENECARBOXYLATE; SILANE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CYCLIZATION; DIASTEREOISOMER; MASS SPECTROMETRY; MOLECULAR WEIGHT; MUKAIYAMA REACTION; NUCLEAR OVERHAUSER EFFECT; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION TIME; STEREOCHEMISTRY; SYNTHESIS; TEMPERATURE;

EID: 14344255016     PISSN: 1434193X     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejoc.200400553     Document Type: Article

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