Coupled diffusion on the NO + H2 reaction on Pt(1 0 0): Chemical wave pattern formation by defects

Chemical Engineering Journal

Volumn 106, Issue 3, 2005, Pages 229-240

  Caballero, Francisco Vidal ^a   Vicente, Luis ^b  

^a Tecnologico de Estudios Superiores de Ecatepec   (Mexico)

^b UNIVERSIDAD NACIONAL AUTÓNOMA DE MÉXICO   (Mexico)

Author keywords

Adsorption; Kinetics; Mathematical; Modelling; Nonlinear dynamics

Indexed keywords

ANISOTROPY; CATALYSTS; CHAOS THEORY; MATHEMATICAL MODELS; PLATINUM; PRESSURE EFFECTS; REACTION KINETICS;

CATALYTIC REDUCTION; KINETIC OSCILLATIONS; MEAN FIELD MODEL; PATTERN FORMATION;

DIFFUSION;

NITRIC OXIDE;

EID: 14044255972     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2004.12.002     Document Type: Article

References (23)

1. K.C. Taylor, Automotive Catalytic Converters, Springer, Berlin, 1984.
2. W.C. Egelhoff Jr., The Chemical physics of solid surfaces and heterogeneous catalysis, in: D.A. King, D.P. Woodruff (Eds.), Fundamental Studies of Heterogeneous Catalysis, vol. 4, Elsevier, Amsterdam, 1982.
3. Th. Fink, J-P. Dath, R. Imbihl, G. Ertl, Kinetic oscillation in the NO+ CO reaction on Pt(1 0 0): experiments and mathematical modeling, J. Chem. Phys. 95 (1991) 2109-2126.
4. J. Siera, P. Cobden, K. Tanaka, B. Nieuwenhuys, The nitric oxide-hydrogen reaction over Platinum (100): oscillatory behavior of activity and selectivity, Catal. Lett. 10 (1991) 335-342.
5. H.H. Madden, R. Imbihl, Interaction of NO and H with Pt(1 0 0), Appl. Surf. Sci. 48/49 (1991) 130-134.
6. P.D. Cobden, J. Siera, B.E. Nieuwenhuys, Oscillatory reduction of nitric oxide with hydrogenover Pt(1 0 0), J. Vac. Sci. Technol. A10 (1992) 2487-2494.
7. 2 reactions on Pt(1 0 0): steady state and oscillatory kinetics, J. Chem. Phys. 98 (1993) 5526-5539.
8. St.J. Dixon-Warren, A.T. Pasteur, D.A. King, Nonlinear effects in the hydrogen/deuterium catalytic exchange reaction over Pt(1 0 0), J. Chem. Phys. 103 (1995) 2261-2271.
9. M. Gruyters, A.T. Pasteur, D.A. King, Simulation of oscillatory behaviour in the reduction of NO by hydrogen on Pt1 0 0: the role of non-linear restructuring, J. Chem. Soc., Faraday Trans. 92 (1996) 2941-2949.
10. R. Imbihl, Oscillatory reactions on single crystals surfaces, Prog. Surf. Sci. 44 (1993) 185-343.
11. R. Imbihl, G. Ertl, Oscillatory kinetics in heterogeneous catalysts, Chem. Rev. 95 (1995) 697-733.
12. M.M. Slinko, N.I. Jaeger, Oscillating Heterogeneous Catalytic Systems, Elsevier, Amsterdam, 1994.
13. 2/Pt(1 0 0) reaction: "surface explosion", kinetic oscillations, and chaos, J. Chem. Phys. 108 (1998) 3740-3749.
14. 2 reaction on Pt(1 0 0): effect of diffusion and blocking sites, Chem. Eng. Sci. 58 (2003) 5087-5102.
15. A.G. Makeev, R. Imbihl, J. Chem. Phys. 113 (2000) 3854-3863.
16. 2 reaction on a Rh(1 0 0) surface, J. Chem. Phys. 114 (2001) 9083-9098.
17. M. Tammaro, J.W. Evans, Reactive removal of unstable mixed NO + CO adlayers: chemical diffusion and reaction front propagation, J. Chem. Phys. 108 (1998) 7795-7806.
18. C.W. Gear, Numerical Initial Value Problems in Ordinary Differential Equations, Prentice-Hall, Englewood Cliffs, NJ, 1971.
19. 2 reaction on Pt1 0 0 with low-energy emission and reflection microscopy: PEEM studies, J. Chem. Soc., Faraday Trans. 92 (1996) 4815-4821.
20. 2 reaction on Pt1 0 0 with low-energy electron microscopy, J. Chem. Soc., Faraday Trans. 94 (1998) 963-970.
21. J.P. Hovi, J. Vaari, H.P. Kaukonen, R.M. Nieminen, Simulations of the effect of preadsorbed poisons and promoters on irreversible surface reactions, Comp. Mater. Sci. 1 (1992) 33.
22. F. Chávez, L. Vicente, A. Perera, M. Moreau, Dynamics of front propagation in the catalytic CO oxidation on Pt(1 0 0), J. Chem. Phys. 110 (1999) 8119-8128.
23. E.V. Albano, M. Borwko (Eds.), Computational methods in surface and colloid science, Marcel Dekker, NY, 2000.