Synthesis, characterization, and hydrolysis products of (η2-tBu2pz)AlH(μ:η1, η1-tBu2pz)2AlH2 - Structural characterization of a complex containing η1-, η2-, and μ:η1,η1-Pyrazolato ligands and a complex containing a terminal hydroxo ligand

European Journal of Inorganic Chemistry

Volumn , Issue 2, 2005, Pages 330-337

  Yu, Zhengkun ^a,b   Knox, John E ^a   Korolev, Audrey V ^a,c   Heeg, Mary Jane ^a   Schlegel, H Bernhard ^a   Winter, Charles H ^a  

^a WAYNE STATE UNIVERSITY   (United States)

^b DALIAN INSTITUTE OF CHEMICAL PHYSICS   (China)

^c Sigma Aldrich Co 5485   (United States)

Author keywords

Aluminum; Hydrogen bond; Molecular orbital calculations; N ligands; Pyrazolato ligands

Indexed keywords

ALUMINUM; ALUMINUM COMPOUNDS; CHELATION; COMPLEXATION; DIMERS; HYDROLYSIS; LIGANDS; MOLECULAR ORBITALS;

HYDROLYSIS PRODUCTS; HYDROXO LIGANDS; LIGAND COORDINATION; MOLAR RATIO; MOLECULAR ORBITAL CALCULATIONS; N LIGANDS; N-LIGANDS; PYRAZOLATO LIGAND; SPECTRAL DATA; STRUCTURAL CHARACTERIZATION;

HYDROGEN BONDS;

LIGAND; PYRAZOLE DERIVATIVE;

ARTICLE; CALCULATION; COMPLEX FORMATION; CRYSTAL STRUCTURE; ENERGY; HYDROGEN BOND; HYDROLYSIS; SPECTROSCOPY; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 13944276749     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200400660     Document Type: Article

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