Towards the design of linear homo-trinuclear metal complexes based on a new phenol-functionalised diazamesocyclic ligand: Structural analysis and magnetism

European Journal of Inorganic Chemistry

Volumn , Issue 2, 2005, Pages 294-304

  Du, Miao ^a   Zhao, Xiao Jun ^a,b   Guo, Jian Hua ^a   Bu, Xian He ^b   Ribas, Joan ^c  

^a TIANJIN NORMAL UNIVERSITY   (China)

^b NANKAI UNIVERSITY   (China)

^c UNIVERSITY OF BARCELONA   (Spain)

Author keywords

Copper(II) and nickel(II); Crystal structures; Functionalised diazamesocyclic ligand; Magnetochemistry; Trinuclear complexes

Indexed keywords

COPPER COMPOUNDS; ELECTRON SPIN RESONANCE SPECTROSCOPY; IONS; MAGNETIC MOMENTS; MAGNETIC SUSCEPTIBILITY; METAL COMPLEXES; NICKEL COMPOUNDS; PHENOLS; SINGLE CRYSTALS; TEMPERATURE; THERMOANALYSIS; X RAY DIFFRACTION ANALYSIS;

COMPLEX 1; COPPER(II) AND NICKEL(II); CRYSTALS STRUCTURES; FUNCTIONALIZED; FUNCTIONALIZED DIAZAMESOCYCLIC LIGAND; MAGNETOCHEMISTRY; TRIMETALLIC; TRINUCLEAR; TRINUCLEAR COMPLEX; TWO TERMINALS;

LIGANDS;

COPPER ION; LIGAND; METAL COMPLEX; N,N' BIS(2 HYDROXYBENZYL) 1,4 DIAZACYCLOHEPTANE; NICKEL; PHENOL DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; COMPLEX FORMATION; CONDUCTANCE; INFRARED SPECTROSCOPY; MAGNETISM; MOLECULAR INTERACTION; STRUCTURE ANALYSIS; THERMAL ANALYSIS; X RAY DIFFRACTION;

EID: 13844298673     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200400618     Document Type: Article

References (79)

1. [1a] D. Gatteschi, Adv. Mater. 1994, 6, 635-645.
2. [1b] R. E. P. Winpenny, Comments Inorg. Chem. 1999, 20, 233-262.
3. [1c] S. Leininger, B. Olenyuk, P. J. Stang, Chem. Rev. 2000, 100, 853-908.
4. [1d] E. I. Solomon, R. K. Szilagyi, S. D. George, L. Basumallick, Chem. Rev. 2004, 104, 419-458.
5. [1e] D. Gatteschi, R. Sessoli, Angew. Chem. Int. Ed. 2003, 42, 268-297.
6. [1f] M. A. Halcrow, G. Christou, Chem. Rev. 1994, 94, 2421-2481.
7. For examples, see: [2a] G. A. van Albada, I. Mutikainen, U. Turpeinen, J. Reedijk, Eur. J. Inorg. Chem. 1998, 547-549.
8. [2b] L. Cronin, P. H. Walton, Inorg. Chim. Acta 1998, 269, 241-245.
9. [2c] T. C. Higgs, K. Spartalian, C. J. O'Connor, B. F. Matzanke, C. J. Carrano, Inorg. Chem. 1998, 37, 2263-2272.
10. For examples, see: [3a] R. Prins, M. Biagini-Cingi, M. Drillon, R. A. G. de Graaff, J. G. Haasnoot, A. M. Manotti-Lanfredi, P. Rabu, J. Reedijk, F. Uggozzoli, Inorg. Chim. Acta 1996, 248, 35-44.
11. [3b] P. A. Angaridis, P. Baran, R. Boca, F. Cervantes-Lee, W. Haase, G. Mezei, R. G. Raptis, R. Werner, Inorg. Chem. 2002, 41, 2219-2228.
12. For examples, see: S. Ferrer, J. G. Haasnoot, J. Reedijk, E. Muller, M. B. Cingi, M. Lanfranchi, A. M. M. Lanfredi, J. Ribas, Inorg. Chem. 2000, 39, 1859-1867.
13. For examples, see: [5a] R. L. Beddoes, J. A. Conner, D. Dubowski, A. C. Jones, O. S. Mills, R. Price, J. Chem. Soc., Dalton Trans. 1981, 2119-2126.
14. [5b] L. Gutiérrez, G. Alzuet, J. A. Real, J. Cano, J. Borrás, A. Castiñeiras, Inorg. Chem. 2000, 39, 3608-3614.
15. For examples, see: X. M. Liu, M. P. de Miranda, E. J. L. McInnes, C. A. Kilner, M. A. Halcrow, Dalton Trans. 2004, 59-64.
16. For examples, see: J. Ribas, A. Escuer, M. Monfort, R. Vicente, R. Cortes, L. Lezama, T. Rojo, Coord. Chem. Rev. 1999, 195, 1027-1068.
17. [8a] M. Du, X. H. Bu, G. C. Wang, Y. M. Guo, R. H. Zhang, Inorg. Chim. Acta 2001, 320, 190-197.
18. [8b] M. Du, Y. M. Guo, X. H. Bu, Inorg. Chim. Acta 2002, 335, 136-140.
19. [9a] X. H. Bu, M. Du, L. Zhang, Z. L. Shang, R. H. Zhang, M. Shionoya, J. Chem. Soc., Dalton Trans. 2001, 729-735.
20. [9b] X. H. Bu, M. Du, Z. L. Shang, L. Zhang, Q. H. Zhao, R. H. Zhang, M. Shionoya, Eur. J. Inorg. Chem. 2001, 1551-1558.
21. [9c] M. Du, Z. L. Shang, X. B. Leng, X. H. Bu, Polyhedron 2001, 20, 3065-3071.
22. [10a] X. H. Bu, M. Du, Z. L. Shang, R. H. Zhang, D. Z. Liao, M. Shionoya, T. Clifford, Inorg. Chem. 2000, 39, 4190-4199.
23. [10b] X. H. Bu, M. Du, L. Zhang, D. Z. Liao, J. K. Tang, R. H. Zhang, M. Shionoya, J. Chem. Soc., Dalton Trans. 2001, 593-598.
24. [10c] M. Du, Y. M. Guo, X. H. Bu, J. Ribas, M. Monfort, New J. Chem. 2002, 26, 645-650.
25. [11a] M. Du, X. H. Bu, Y. M. Guo, L. Zhang, D. Z. Liao, J. Ribas, Chem. Commun. 2002, 1478-1479.
26. [11b] M. Du, X. H. Bu, Y. M. Guo, J. Ribas, C. Diaz, Chem. Commun. 2002, 2550-2551.
27. [11c] M. Du, X. H. Bu, Y. M. Guo, J. Ribas, Chem. Eur. J. 2004, 10, 1345-1354.
28. C. A. Grapperhaus, M. Y. Darensbourg, Acc. Chem. Res. 1998, 31, 451-459 and references cited therein.
29. [13a] D. L. An, Y. M. Guo, M. Du, X. S. Shi, X. H. Bu, Chin. J. Struct. Chem. 2004, 23, 126-130.
30. [13b] M. Du, Y. M. Guo, S. T. Chen, X. H. Bu, J. Mol. Struct. 2002, 641, 29.
31. [13c] Y. M. Guo, M. Du, X. H. Bu, J. Mol. Struct. 2002, 610, 27-31.
32. [13d] M. Du, Y. M. Guo, X. H. Bu, J. Ribas, M. Monfort, New J. Chem. 2002, 26, 939-945.
33. [13e] Y. M. Guo, Doctor Dissertation, 2001, Nankai University.
34. [14a] H. Okawa, M. Koikawa, S. Kida, D. Luneau, H. Oshio, J. Chem. Soc., Dalton Trans. 1990, 469-475.
35. [14b] F. Akagi, Y. Nakao, K. Matsumoto, S. Takamizawa, W. Mori, S. Suzuki, Chem. Lett. 1997, 181-182.
36. [14c] W. L. Driessen, L. Chang, C. Finazzo, S. Gorter, D. Rehorst, J. Reedijk, M. Lutz, A. L. Spek, Inorg. Chim. Acta 2003, 350, 25-31.
37. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley, New York, 1986.
38. E. V. RybakAkimova, D. H. Busch, P. K. Kahol, N. Pinto, N. W. Alcock, H. J. Clase, Inorg. Chem. 1997, 36, 510-520.
39. G. R. Desiraju, T. Steiner, The Weak Hydrogen Bond in Structural Chemistry and Biology, Oxford University Press, 1999.
40. O. Kahn, Molecular Magnetism, VCH Publishers, New York, 1993.
41. A. Bencini, D. Gatteschi, EPR of Exchange Coupled Systems, Springer-Verlag, Berlin, 1989.
42. L. Banci, A. Bencini, D. Gatteschi, Inorg. Chem. 1983, 22, 2681-2683.
43. R. Veit, J. J. Girerd, O. Kahn, F. Robert, Y. Jeannin, Inorg. Chem. 1986, 25, 4175-4180.
44. R. Costa, A. García, J. Ribas, T. Mallah, Y. Journaux, X. Solans, V. Rodríguez, Inorg. Chem. 1993, 32, 3733-3742 and references cited therein.
45. L. Gutiérrez, G. Alzuet, J. A. Real, J. Cano, J. Borrás, A. Castineiras, Eur. J. Inorg. Chem. 2002, 2094-2102.
46. V. H. Crawford, H. W. Richardson, J. R. Wason, D. J. Hodgson, W. E. Hatfield, Inorg. Chem. 1976, 15, 2107-2110.
47. [25a] L. Mertz, W. Haase, J. Chem. Soc., Dalton Trans. 1980, 875-879.
48. [25b] M. Handa, N. Koga, S. Kida, Bull. Chem. Soc., Jpn. 1988, 61, 3853-3857.
49. K. Nieminen, Ann. Acad. Sci. Fennicae A II 1982, 197, 1-60.
50. L. Walz, H. Paulus, W. Haase, J. Chem. Soc., Dalton Trans. 1985, 913-920.
51. A. Bencini, D. Gatteschi, Inorg. Chim. Acta 1978, 31, 11-18.
52. P. J. Hay, J. C. Thibault, R. Hoffman, J. Am. Chem. Soc. 1975, 97, 4884-4899.
53. [30a] O. Kahn, Inorg. Chim. Acta 1982, 62, 3-14.
54. [30b] J. Commarmond, P. Plumere, J. M. Lehn, Y. Agnus, P. Louis, R. Weiss, O. Kahn, I. Morgenstern-Badarau, J. Am. Chem. Soc. 1982, 104, 6330-6340.
55. H. Astheimer, W. Haase, J. Chem. Phys. 1986, 85, 1427-1432.
56. [32a] E. Ruiz, P. Alemany, S. Alvarez, J. Cano, J. Am. Chem. Soc. 1997, 119, 1297-1303.
57. [32b] E. Ruiz, P. Alemany, S. Alvarez, J. Cano, Inorg. Chem. 1997, 36, 3683-3688.
58. C. Blanchet-Boiteux, J. M. Muesca, J. Phys. Chem. A 2000, 704, 2091-2097.
59. R. J. Butcher, E. Sinn, Inorg. Chem. 1976, 15, 1604-1608 and references cited therein.
60. A. W. Addison, T. N. Rao, J. Reedijk, J. V. Rijn, G. C. Verschoor, J. Chem. Soc., Dalton Trans. 1984, 1349-1356.
61. [36a] M. F. Charlot, S. Jeannin, Y. Jeannin, O. Kahn, J. Lucrece-Abaul, J. Martin-Frere, Inorg. Chem. 1979, 18, 1675-1681.
62. [36b] M. F. Charlot, S. Jeannin, Y. Jeannin, O. Kahn, J. Lucrece-Abaul, J. Martin-Frere, Inorg. Chem. 1980, 19, 1410-1411.
63. [37a] S. Youngme, G. A van Albada, H. Kooijman, O. Roubeau, W. Somjitsripunya, A. L. Spek, C. Pakawatchai, J. Reedijk, Eur. J. Inorg. Chem. 2002, 2367-2374.
64. [37b] I. Castro, M. Julve, G. de Munno, G. Bruno, J. A. Real, F. Lloret, J. Faus, J. Chem. Soc., Dalton Trans. 1992, 1739-1744.
65. [38a] S. Youngme, W. Somjitsripunya, K. Chinnakali, S. Chantraproma, H. K. Fun, Polyhedron 1999, 18, 857-862.
66. [38b] L. P. Wu, M. E. Keniry, B. J. Hathaway, Acta Crystallogr., Sect. C 1992, 48, 35-40.
67. L. K. Thompson, S. K. Mandal, S. S. Tandon, J. N. Bridson, M. K. Park, Inorg. Chem. 1996, 55, 3117-3125.
68. A. M. Greenaway, C. J. O'Connor, J. W. Overman, E. Sinn, Inorg. Chem. 1981, 20, 1508-1513.
69. J. P. Costes, F. Dahan, J. P. Laurent, Inorg. Chem. 1985, 24, 1018-1022.
70. J. M. Seco, U. Amador, M. J. González-Garmendia, Inorg. Chim. Acta 2000, 303, 256-264.
71. G. A. van Albada, I. Mutikainen, I. Riggio, U. Turpeinen, J. Reedijk, Polyhedron 2002, 21, 141-146.
72. H. Saimiya, Y. Sunatsuki, M. Kojima, S. Kashino, T. Kambe, M. Hirotsu, H. Akashi, K. Nakajima, T. Tokii, Dalton Trans. 2002, 3737-3742.
73. J. Galy, J. Jaud, O. Kahn, P. Tola, Inorg. Chim. Acta 1979, 36, 229-236.
74. E. Sinn, Inorg. Chem. 1976, 75, 366-369.
75. S. K. Mandal, L. K. Thompson, K. Nag, J. P. Charland, E. J. Gabe, Inorg. Chem. 1987, 26, 1391-1395.
76. J. A. Bertrand, E. Fujita, P. G. Eller, Inorg. Chem. 1974, 13, 2067-2071.
77. R. Range, Tetrahedron 1971, 27, 1499-1502.
78. Bruker AXS, SAINT Software Reference Manual, Madison, WI, 1998.
79. G. M. Sheldrick, SHELXTL NT Version 5.1. Program for Solution and Refinement of Crystal Structures, University of Göttingen, Germany, 1997.