Expansive rearrangement of N-vinylthiazolidines to 2,3,4,7-tetrahydro-1,4- thiazepines and their transformation in 3-thia-6-azabicyclo[3.2.1]oct-6-enes

Synlett

Volumn , Issue 2, 2005, Pages 239-242

  Calvo, Luis ^a   González Ortega, Alfonso ^a   Pérez, Mónica ^a   Sañudo, María Carmen ^a  

^a UNIVERSITY OF VALLADOLID   (Spain)

Author keywords

3 Thia 6 azabicyclo 3.2.1 oct 6 ene 1 carbonitrile; N vinylthiazolidine; Rearrangement; Thiazepine; Weinreb amide

Indexed keywords

1H,3H PYRROLO[1,2 C]THIAZOLE DERIVATIVE; 2,3,4,7 TETRAHYDRO 1,4 THIAZEPINE DERIVATIVE; 3 (2 CYANO 1 METHYLVINYL)N METHOXY N METHYLTHIAZOLIDINE 4 CARBOXAMIDE; 3 THIA 6 AZABICYCLO[3.2.1]OCT 6 ENE DERIVATIVE; 6 CYANO N METHOXY N,5 DIMETHYL 2,3,4,7 TETRAHYDRO 1,4 THIAZEPINE 3 CARBOXAMIDE; 8 HYDROXY 3 THIA 6 AZABICYCLO[3.2.1]OCT 6 ENE 1 CARBONITRILE DERIVATIVE; AMIDE; CYANIDE; HETEROCYCLIC COMPOUND; N VINYLTHIAZOLIDINE DERIVATIVE; ORGANOLITHIUM COMPOUND; PYRROLE DERIVATIVE; REAGENT; THIAZEPINE DERIVATIVE; THIAZOLE DERIVATIVE; THIAZOLIDINE DERIVATIVE; UNCLASSIFIED DRUG; VINYL DERIVATIVE;

ARTICLE; CHEMICAL BOND; CHEMICAL MODIFICATION; CHEMICAL REACTION; CHIRALITY; CYCLIZATION; DIASTEREOISOMER; DRUG STRUCTURE; DRUG SYNTHESIS; GRIGNARD REACTION; HEAT TREATMENT; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; REPRODUCIBILITY; STEREOCHEMISTRY; TECHNIQUE; TEMPERATURE DEPENDENCE;

EID: 13844274938     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2004-836069     Document Type: Article

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23. 3).