Understanding the structural deactivation of ruthenium catalysts on an atomic scale under both oxidizing and reducing conditions

Angewandte Chemie - International Edition

Volumn 44, Issue 6, 2005, Pages 917-920

  Aßmann, Jens ^b   Crihan, Daniela ^a   Knapp, Marcus ^a   Lundgren, Edvin ^c   Löffler, Elke ^b   Muhler, Martin ^b   Narkhede, Vijay ^b   Over, Herbert ^a   Schmid, Michael ^d   Seitsonen, Ari P ^e   Varga, Peter ^d  

^a JUSTUS LIEBIG UNIVERSITY   (Germany)

^b RUHR UNIVERSITY BOCHUM   (Germany)

^c LUND UNIVERSITY   (Sweden)

^d VIENNA UNIVERSITY OF TECHNOLOGY   (Austria)

^e UNIVERSITY OF ZURICH   (Switzerland)

Author keywords

Catalytic activity; Heterogeneous catalysis; Oxidation; Ruthenium; Surface chemistry

Indexed keywords

CARBON MONOXIDE; CATALYSTS; OXIDATION; REDUCTION; STRUCTURE (COMPOSITION);

INDUSTRIAL CATALYSTS; REDUCING CONDITIONS; STRUCTURAL DEACTIVATION; SYNERGISTIC STRATEGY;

RUTHENIUM COMPOUNDS;

RUTHENIUM;

ARTICLE; ATOMIC PARTICLE; CATALYST; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; ENZYME ACTIVE SITE; OXIDATION; REACTION ANALYSIS; REDUCTION; STRUCTURE ANALYSIS; SURFACE PROPERTY;

EID: 13744249638     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200461805     Document Type: Article

References (18)

1. J. M. Thomas, W. J. Thomas, Principles and Practice of Heterogeneous Catalysis, VCH, Weinheim, 1996.
2. See for example, various articles in Frontiers in Surface and Interface Science (Eds.: C. B. Duke, E. W. Plummer), Surf. Sci. 2001, 500.
3. Handbook of Heterogeneous Catalysis, Vol. 5 (Eds.: G. Ertl, H. Knözinger, J. Weitkamp), Wiley, New York, 1997.
4. J. T. Kiss, R. D. Gonzalez, J. Phys. Chem. 1984, 88, 892-903.
5. N. W. Cant, P. C. Hicks, B. S. Lennon, J. Catal. 1978, 54, 372-383.
6. H. Over, Y. D. Kim, A. P. Seitsonen, S. Wendt, E. Lundgren, M. Schmid, P. Varga, A. Morgante, G. Ertl, Science 2000, 287, 1474-1477.
7. H. Over, M. Muhler, Prog. Surf. Sci. 2003, 72, 3-17.
8. J. Aßmann, E. Löffler, A. Birkner, M. Muhler, J. Catal. 2003, 85, 235-249.
9. H. Over, A. P. Seitsonen, Science 2002, 297, 2003-2004.
10. Y. D. Kim, H. Over, G. Krabbes, G. Erk, Topics Catal. 2001, 14, 95-100.
11. H. Over, M. Knapp, E. Lundgren, A. P. Seitsonen, M. Schmid, P. Varga, ChemPhysChem 2004, 5, 167-174.
12. "Ruthenium Dioxide, a Versatile Oxidation Catalyst: First Principles Analysis": A. P. Seitsonen, H. Over in High Performance Computing in Science and Engineering in Munich 2002, Springer, Heidelberg, 2003, pp. 171-180.
13. J. Aßmann, V. Narkhede, L. Khodeir, E. Löffler, O. Hinrichsen, A. Birkner, H. Over, M. Muhler, J. Phys. Chem. B 2004, 108, 14634-14642.
14. a) S. Trasatti, Electrochim. Acta 2000, 45, 2377-2385;
15. b) R. Mason, A. Mills, D. Milton, J. Less-Common Met. 1989, 155, 89-109.
16. K. Yamaguchi, N. Mizuno, Angew. Chem. 2002, 114, 4720-4724; Angew. Chem. Int. Ed. 2002, 41, 4538-4542.
17. K. Yamaguchi, N. Mizuno, Angew. Chem. 2002, 114, 4720-4724; Angew. Chem. Int. Ed. 2002, 41, 4538-4542.
18. B.-Z. Zhan, M. A. White, T.-K. Sham, J. A. Pincock, R. J. Doucet, K. V. R. Rao, K. N. Robertson, T. S. Cameron, J. Am. Chem. Soc. 2003, 125, 2195-2199.