Photocatalyzed oxidation and mineralization of branched and oxidized C4 and C5 aliphatic acids in UV-irradiated aqueous titania dispersions. Adsorption and degradation dynamics

Journal of Photochemistry and Photobiology A: Chemistry

Volumn 170, Issue 1, 2005, Pages 51-60

  Serpone, Nick ^a,d   Martin, Jean ^b   Horikoshi, Satoshi ^c   Hidaka, Hisao ^c  

^a UNIVERSITY OF PAVIA   (Italy)

^b Pharmetics Inc   (Canada)

^c MEISEI UNIVERSITY   (Japan)

^d Dept of Electrical and Computer Engineering   (Canada)

Author keywords

Branched carboxylic acids; Oxidized carboxylic acids; Photodegradation; Photomineralization

Indexed keywords

2 METHYLBUTYRIC ACID; ALIPHATIC CARBOXYLIC ACID; BUTYRIC ACID DERIVATIVE; CARBON; CARBOXYLIC ACID; HYDROGEN; HYDROXIDE; ISOBUTYRIC ACID; ISOVALERIC ACID; ORGANIC CARBON; PIVALIC ACID; RADICAL; TITANIUM DIOXIDE; VALERIC ACID DERIVATIVE;

ADSORPTION; AIR; AQUEOUS SOLUTION; ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; CONTROLLED STUDY; CORRELATION ANALYSIS; DARKNESS; DISPERSION; HYDROXYLATION; METHYLATION; MINERALIZATION; MOLECULAR DYNAMICS; PHOTOCATALYSIS; PHOTODEGRADATION; PHOTOOXIDATION; TIME; TOTAL ORGANIC CARBON; ULTRAVIOLET IRRADIATION;

EID: 13544254531     PISSN: 10106030     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jphotochem.2004.07.018     Document Type: Article

References (26)

1. N. Serpone D. Lawless R. Khairutdinov E. Pelizzetti J. Phys. Chem. 99 1995 16655
2. D. Lawless N. Serpone D. Meisel J. Phys. Chem. 95 1991 5166
3. (a) N. Serpone E. Pelizzetti Photocatalysis - Fundamentals and Applications 1989 Wiley Interscience New York
4. (b) E. Pelizzetti C. Minero V. Maurino Adv. Colloid Interface Sci. 32 1990 271
5. (c) D.F. Ollis H. Al-Ekabi Photocatalytic Purification and Treatment of Water and Air 1993 Elsevier Amsterdam
6. (d) M.A. Fox M.T. Dulay Chem. Rev. 93 1993 341
7. (e) D.W. Bahnemann, in: E. Pelizzetti M. Schiavello (Eds.). Photochemical Conversion and Storage of Solar Energy 1991 Kluwer Dordrecht, The Netherlands 251-276
8. S.T. Cragg Aliphatic carboxylic acids, saturated in: Patty's Toxicology 5th Edn. 2001 John Wiley & Sons Inc. New York
9. D.L. Camper G.H. Loew J.R. Collins Intern. J. Quantum Chem. Quantum Biol. Symp. 17 1990 173
10. C.J. Moudgal J.C. Lipscomb R.M. Bruce Toxicology 147 2000 109
11. M.G. Narotsky E.Z. Francis R.J. Kavlock Fund. Appl. Toxicol. 22 1994 251
12. L. Legal B. Moulin J.M. Jallon Pestic. Biochem. Phyisol. 65 1999 90
13. N. Serpone J. Martin S. Horikoshi H. Hidaka J. Photochem. Photobiol. A: Chem. 269 2005 235
14. J. Schwitzgebel J.G. Ekerdt H. Gerisher A. Heller J. Phys. Chem. 95 1995 5633
15. A. Mills S. Le Hunte J. Photochem. Photobiol. A: Chem. 108 1997 1
16. 2-photocatalyzed degradations of water pollutants: Influences of adsorption, pH and photon flux in: Photocatalytic Purification and Treatment of Water and Air 1993 Elsevier Amsterdam
17. W. Tsang J. Am. Chem. Soc. 107 1985 2872
18. T. Brinck H.-N. Lee M. Jonsson J. Phys. Chem. A 103 1999 7094
19. T. Sakata T. Kawai K. Hashimoto J. Phys. Chem. 88 1984 2344
20. A. Emeline A. Frolov V. Ryabchuk N. Serpone J. Phys. Chem. B 107 2003 7109
21. N. Serpone D. Lawless R. Terzian C. Minero E. Pelizzetti Heterogeneous photocatalysis: Photochemical conversion of inorganic substances in the environment: Hydrogen sulfide, cyanides, and metals, in: E. Pelizzetti M. Schiavello (Eds.). Photochemical Conversion and Storage of Solar Energy 1991 Kluwer The Netherlands 451-476
22. C. Minero V. Maurino E. Pelizzetti Marine Chem. 58 1997 361
23. D. Bahnemann J. Cunningham M.A. Fox E. Pelizzetti P. Pichat N. Serpone Photocatalytic treatment of waters, in: G.R. Helz R.G. Zepp D.G. Crosby (Eds.). Aquatic and Surface Photochemistry 1994 Lewis Publications Boca Raton, FL 261-316
24. A. Albini, personal communication to N. Serpone, June 2004
25. R.W. Matthews Photocatalysis in water purification. Possibilities, problems and prospects Photocatytic Purification and Treatment of Water and Air 1993 Elsevier Science Publisher
26. A. Taghidzadeh, M.F. Lawrence, L. Miller, M.A. Anderson, N. Serpone, J. Photochem. Photobiol. A: Chem. 130 (2000) 145