Family of mixed-valence oxovanadium(IV/V) dinuclear entities incorporating N4O3-coordinating heptadentate ligands: Synthesis, structure, and EPR spectra

Inorganic Chemistry

Volumn 44, Issue 3, 2005, Pages 703-708

  Mondal, Amrita ^a   Sarkar, Sumana ^a   Chopra, Deepak ^b   Row, T N Guru ^b   Pramanik, Kausikisankar ^a   Rajak, Kajal Krishna ^a  

^a JADAVPUR UNIVERSITY   (India)

^b INDIAN INSTITUTE OF SCIENCE   (India)

Author keywords

[No Author keywords available]

Indexed keywords

2,6 BIS[[[(2 HYDROXYBENZYL)[N',N' (DIMETHYLAMINO)ETHYL]]AMINO]METHYL] 4 METHYLPHENOL; 2,6 BIS[[[(5 BROMO 2 HYDROXYBENZYL)[N',N' (DIMETHYLAMINO)ETHYL]]AMINO]METHYL] 4 METHYLPHENOL; 2,6 BIS[[[(5 CHLORO 2 HYDROXYBENZYL)[N',N' (DIMETHYLAMINO)ETHYL]]AMINO]METHYL] 4 METHYLPHENOL; 2,6 BIS[[[(5 METHOXY 2 HYDROXYBENZYL)[N',N' (DIMETHYLAMINO)ETHYL]]AMINO]METHYL] 4 METHYLPHENOL; 2,6 BIS[[[(5 METHYL 2 HYDROXYBENZYL)[N'N' (DIMETHYLAMINO)ETHYL]]AMINO]METHYL] 4 METHYLPHENOL; 2,6 BIS[[[(5 TERT BUTYL 2 HYDROXYBENZYL)[N',N' (DIMETHYLAMINO)ETHYL]]AMINO]METHYL] 4 METHYLPHENOL; ACETONE; BIS(ACETYLACETONATO)OXOVANADIUM; DICHLOROMETHANE; LIGAND; METAL; NITROGEN; NITROGEN DERIVATIVE; OXOVANADIUM DERIVATIVE; OXYGEN DERIVATIVE; UNCLASSIFIED DRUG; VANADIUM; VANADIUM DERIVATIVE;

ARTICLE; CHEMICAL BOND; COMPLEX FORMATION; CRYSTAL STRUCTURE; ELECTRON; ELECTRON SPIN RESONANCE; FREEZING; GEOMETRY; INFRARED SPECTROSCOPY; PROTON NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; ROOM TEMPERATURE; SOLID STATE; STOICHIOMETRY; SYNTHESIS; TEMPERATURE; ULTRAVIOLET SPECTROSCOPY; X RAY CRYSTALLOGRAPHY;

EID: 13444274719     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic048919x     Document Type: Article

References (38)

1. Young, C. G. Coord. Chem. Rev. 1989, 96, 89-251.
2. Boas, L. V.; Pessoa, J. C. In Comprehensive Coordination Chemistry; Wilkinson, G., Ed.; Pergamon: Oxford, U.K., 1987; Vol. 3, p 453.
3. Stankiewicz, P. J.; Tracey, A. S.; Crans, D. C. In Metal Ions in Biological Systems; Sigel, H., Sigel, A., Eds.; Marcel Dekker: New York, 1995; pp 287-324.
4. Crans, D. C. Comments Inorg. Chem. 1994, 16, 1-33.
5. Crans, D. C. Comments Inorg. Chem. 1994, 16, 35-76.
6. Mahroof-Tahir, M.; Keramidas, A. D.; Goldfrab, R. B.; Anderson, O. P.; Miller, M. M.; Crans, D. B. Inorg. Chem. 1997, 36, 1657-1668.
7. Pessoa, J. C.; Calhorda, M. J.; Cavaco, I.; Correia, I.; Duarte, M. T.; Felix, V.; Henriques, R. T.; Piedade, M. F. M.; Tomaz, I. J. Chem. Soc., Dalton Trans. 2002, 4407-4415.
8. Ghosh, S.; Nanda, K. K.; Addison, A. W.; Butcher, R. J. Inorg. Chem. 2002, 41, 2243-2249.
9. Dutta, S. K.; Samanta, S.; Kumar, S. B.; Ran, O. H.; Burckel, P.; Pinkerton, A. A.; Chaudhury, M. Inorg. Chem. 1999, 38, 1982-1988.
10. Holwerda, R. A.; Whittlesey, B. R. Inorg. Chem. 1998, 37, 64-68.
11. Mondal, S.; Ghosh, P.; Chakravorty, A. Inorg. Chem. 1997, 36, 59-63.
12. Schulz, D.; Weyhermüller, T.; Wieghardt, K.; Nuber, B. Inorg. Chim. Acta 1995, 240, 217-229.
13. Chakravarty, J.; Dutta, S.; Chakravorty, A. J. Chem. Soc., Dalton Trans. 1993, 2857-2858.
14. Pessoa, J. C.; Silva, J. A. L.; Vieira, A. L.; Vilas-Boas, L.; O'Brien, P. J. Chem., Dalton Trans. Soc. 1992, 1745-1749.
15. Launay, J.-P.; Jeannin, Y.; Daoudi, M. Inorg. Chem. 1985, 24, 1052-1059.
16. Kojima, A.; Okazaki, K.; Ooi, S.; Saito, K. Inorg. Chem. 1983, 22, 1168-1174.
17. Babonneau, F.; Sanchez, C.; Livage, J.; Launay, J. P.; Daoudi, M.; Jeannin, Y. Nouv. J. Chim. 1982, 6, 353-357.
18. Nishizawa, M.; Hirotsu, K.; Ooi, S.; Saito, K. J. Chem. Soc., Chem. Commun. 1979, 707-708.
19. Riechel, T. L.; Sawyer, D. T. Inorg. Chem. 1975, 14, 1869-1975.
20. Copeland, E. P.; Kahwa, I. A.; Mague, J. T.; McPherson, G. L. J. Chem., Dalton Trans. 1997, 2849-2852.
21. Fukuda, I.; Matsushima, H.; Maeda, K.; Koikawa, M.; Tokii, T. Chem. Lett. 1997, 463-464.
22. (a) Robin,M. B.; Day, P. Adv. Inorg. Chem. Radiochem. 1967, 10, 247-422.
23. (b) Wong, K. Y.; Schatz, P. N. Prog. Inorg. Chem. 1981, 28, 369.
24. (a) Rajak, K. K.; Baruah, B.; Rath, S. P.; Chakravorty, A. Inorg. Chem. 2000, 39, 1598-1601.
25. (b) Rajak, K. K.; Rath, S. P.; Mondal S.; Chakravorty, A. Inorg. Chem. 1999, 38, 3283-3289.
26. Manos, M. J.; Tasiopoulos, A. J.; Tolis, E. J.; Lalioto, N.; Woollins, J. D.; Slawin, A. M. Z.; Sigalas, M. P.; Kabanos, T. A. Chem.-Eur. J. 2003, 9, 695-703.
27. (a) Wertz, J. E.; Bolton, J. R. Electron Spin Resonance; McGraw-Hill: New York, 1972; pp 208-210.
28. (b) Pilbrow, J. R. Transition Ion Electron Paramagnetic Resonance; Clarendon Press: Oxford, U.K., 1990; p 339.
29. Basu, P.; Pal, S.; Chakravorty, A. J. Chem. Soc., Dalton Trans. 1991, 3217-3221.
30. Cornman, C. R.; Kampf, J.; Lah, M. S.; Pecoraro, V. L. Inorg. Chem. 1992, 31, 2035-2047.
31. Hausan, G. R.; Kabanos, T. A.; Keramidas, A. D.; Mentzafos, D.; Terzis, A. Inorg. Chem. 1992, 31, 2587-2594.
32. Rowe, R. A.; Jones, M. M. Inorg. Synth. 1957, 5, 113-116.
33. Kannappan, R.; Mahalakshmy, R.; Rajendiram, T. M.; Venkatesan, R.; Sambasiva Rao, P. Proc.-Indian Acad. Sci., Chem. Sci. 2003, 115, 1-14.
34. Furniss, B. S.; Hannaford, A. J.; Smith, P. W. G.; Tatchell, A. R. In Vogel's Textbook of practical organic chemistry; Pearson Education: Singapore, 2004; pp 395-412.
35. Lahiri, G. K.; Bhattacharya, S.; Ghosh, B. K.; Chakravorty, A. Inorg. Chem. 1987, 26, 4324-4431.
36. SMART, SAINT, SADABS, XPREP, SHELXTL; Bruker AXS Inc.: Madison, WI, 1998.
37. Sheldrick, G. M. SHELXTL, version 5.03; Siemens Analytical Instruments, Inc: Madison, WI, 1994.
38. Johnson, C. K. ORTEP; Report ORNL-5138; Oak Ridge National Laboratory: Oak Ridge, TN, 1976.