Nickel-catalyzed regioselective synthesis of tetrasubstituted alkene using alkylative carboxylation of disubstituted alkyne

Organic Letters

Volumn 7, Issue 2, 2005, Pages 195-197

  Shimizu, Kazuya ^a   Takimoto, Masanori ^a   Sato, Yoshihiro ^a   Mori, Miwako ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE; ALKYNE DERIVATIVE; CARBON DIOXIDE; CARBOXYL GROUP; CARBOXYLIC ACID DERIVATIVE; NICKEL; ZINC;

ARTICLE; CARBOXYLATION; CATALYSIS; CHEMICAL PROCEDURES; CHEMICAL REACTION; REACTION ANALYSIS; SYNTHESIS; THERMODYNAMICS;

EID: 13444261089     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol047912g     Document Type: Article

References (41)

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40. 1) in Va, although we first thought that the silyl substitution next to the metal (as in IV) is thermodynamically favored.
41. 4, and concentrated. The residue was purified using an appropriate procedure.