Upper limits of stratospheric IO and OIO inferred from center-to-limb-darkening-corrected balloon-borne solar occultation visible spectra: Implications for total gaseous iodine and stratospheric ozone

Journal of Geophysical Research: Atmospheres

Volumn 108, Issue 15, 2003, Pages

  Bosch H ^a   Camy Peyret, C ^b   Chipperfield, M P ^c   Fitzenberger, R ^a   Harder, H ^a   Platt, U ^a   Pfeilsticker, K ^a  

^a UNIVERSITY OF HEIDELBERG   (Germany)

^b CNRS   (France)

^c UNIVERSITY OF LEEDS   (United Kingdom)

Author keywords

Center to limb darkening correction; Differential optical absorption spectroscopy; Iodine chemistry; Solar occultation spectroscopy; Stratospheric ozone

Indexed keywords

ATMOSPHERIC CHEMISTRY; BALLOON OBSERVATION; IODINE; OZONE; SPECTROSCOPY; STRATOSPHERE;

EID: 1342333714     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/2002jd003078     Document Type: Article

References (67)

1. Alicke, B., K. Hebestreit, U. Platt, J. Carpenter, and T. W. Sturges, Measurements of iodine oxide in the midlatitudes, Ann. Geophys., 16, suppl. 11, C716, 1998.
2. Alicke, B., K. Hebestreit, J. Stutz, and U. Platt, Iodine oxide in the Marine boundary layer, Nature, 397, 572-573, 1999.
3. Aliwell, S. R., et al., Analysis for BrO in zenith-sky spectra: An intercomparison exercise for analysis improvements, J. Geophys. Res., 107(D14), 4199, doi:10.1029/2001JD000329, 2002.
4. Allan, B. J., J. M. C. Plane, and G. McFiggins, Observation of OIO in the remote marine boundary layer, Geophys. Res. Lett., 28, 1945-1948, 2001.
5. Andreae, M. O., et al., Methyl halide emissions from savanna fires in southern Africa, J. Geophys. Res., 101, 23,603-23,614, 1996.
6. Ashworth, S. H., B. J. Allan, and J. M. C. Plane, High resolution spectroscopy of the OIO radical: Implications for the ozone-depleting potential of iodine, Geophys. Res. Lett., 29(10), 1456, doi:10.1029/2001GL013851, 2002.
7. Bedjanian, Y., G. LeBras, and G. Poulet, Kinetics and mechanism of the IO + ClO reaction, J. Phys. Chem. A, 101, 4088-4096, 1997.
8. Bedjanian, Y., G. LeBras, and G. Poulet, Kinetics and mechanism of the IO + BrO reaction, J. Phys. Chem. A, 102, 10,510-10,511, 1998.
9. Bloss, W. J., D. M. Rowley, R. A. Cox, and R. L. Jones, Kinetics and products of the IO self reaction, J. Phys. Chem. A, 105, 7840-7854, 2001.
10. Bösch, H., C. Camy-Peyret, M. P. Chipperfield, R., Fitzenberger, H. Harder, C. Schiller, M. Schneider, T. Trautmann, and K. Pfeilsticker, Inter comparison of measured and modeled stratospheric UV/vis actinic fluxes at large solar zenith angles, Geophys. Res. Lett., 28, 1179-1182, 2001.
11. 2O profiles from IR solar occultation spectra, J. Atmos. Chem., 16, 31-40, 1993.
12. 3P), J. Atmos. Chem., 34, 134-162, 1999.
13. Chameides, W. L., and D. D. Davis, Iodine: Its possible role in the tropospheric photochemistry, J. Geophys. Res., 85, 7383-7398, 1980.
14. Chipperfield, M. P., Multiannual simulations with a 3-D CTM, J. Geophys. Res., 104, 1781-1806, 1999.
15. Cox, R. A., W. J. Bloss, R. L. Jones, and D. M. Rowley, OIO and the atmospheric cycle of iodine, Geophys. Res. Lett., 26, 1857-1860, 1999.
16. 2 + IO reaction, J. Phys. Chem. A, 103, 3228-3236, 1999.
17. Davis, D., J. Crawford, S. Liu, S. McKeen, A. Bandy, D. Thornton, F. Rowland, and D. Blake, Potential impact of iodine on tropospheric levels of ozone and other critical oxidants, J. Geophys. Res., 101, 2135-2147, 1996.
18. DeMore, W. B., et al., Chemical kinetics and photochemical data for use in stratospheric modeling, JPL Publ., 97-4, 1997.
19. Ferlemann, F., et al., Stratospheric BrO profiles measured at different latitudes and seasons: Instrument description, spectral and profile retrieval, Geophys. Res. Lett., 25, 3847-3850, 1998.
20. Ferlemann, F., N. Bauer, R. Fitzenberger, H. Harder, H. Osterkamp, D. Perner, U. Platt, M. Schneider, P. Vradelis, and K. Pfeilsticker, A new DOAS-instrument for stratospheric balloon-borne trace gas studies, Appl. Opt., 39, 2377-2386, 2000.
21. Fitzenberger, R., H. Bösch, C. Camy-Peyret, M. P. Chipperfield, H. Harder, U. Platt, B.-M. Sinnhuber, T. Wagner, and K. Pfeilsticker, First profile measurements of tropospheric BrO, Geophys. Res. Lett., 27, 2921-2924, 2000.
22. Frieß, U., M. P. Chipperfield, C. Otten, U. Platt, J. Pyle, T. Wagner, and K. Pfeilsticker, Intercomparison of measured and modelled BrO slant column amounts for the Arctic winter and spring 1994/95, Geophys. Res. Lett., 26, 1861-1864, 1999.
23. Frieß, U., K. Pfeilsticker, I. Pundt, T. Wagner, and U. Platt, Spectroscopic measurements of tropospheric iodine oxide at Neumayer station, Antarctica, Geophys. Res. Lett., 28, 1941-1944, 2001.
24. 3 columns during the eclipse of February 26, 1998, as measured by visible spectroscopy, J. Geophys. Res., 105, 3583-3593, 2000.
25. Gilles, M. K., L. G. Turnipseed, J. B. Burkholder, A. R. Ravishankara, and S. Solomon, Kinetics of the IO radical, 2. Reaction of IO with BrO, J. Phys. Chem. A, 101, 5526-5534, 1997.
26. Greenblatt, G. D., J. J. Orlando, J. B. Burkholder, and A. R. Ravishankara, Absorption measurements of oxygen between 330 nm and 1140 nm, J. Geophys. Res., 95, 18,577-18,582, 1990.
27. Harder, H., et al., Stratospheric BrO profiles measured at different latitudes and seasons: Atmospheric observations, Geophys. Res. Lett., 25, 3843-3846, 1998.
28. Harder, H., H. Bösch, C. Camy-Peyret, M. P. Chipperfield, R. Fitzenberger, S. Payan, D. Perner, U. Platt, B. M. Sinnhuber, and K. Pfeilsticker, Comparison of measured and modeled stratospheric BrO: Implications for the total amount of stratospheric bromine, Geophys. Res. Lett., 27, 3695-3698, 2000.
29. Harwood, M. H., J. B. Burkholder, M. Hunter, R. W. Fox, and A. R. Ravishankara, Absorption cross sections, and self-reaction kinetics of the IO radical, Phys. Chem. A, 101, 853-863, 1997.
30. Hebestreit, K., Halogenoxide in der planetaren Grenzschicht mittlerer Breiten, Ph.D. thesis, Univ. of Heidelberg, Heidelberg, Germany, 2001.
31. Himmelmann, S., J. Orphal, H. Bovensmann, A. Richter, A. Ladstätter-Weissenmayer, and J. P. Burrows, First observation of the OIO molecule by time-resolved flash photolysis absorption spectroscopy, Chem. Phys. Lett., 251, 330-334, 1996.
32. Hoffmann, T., C. D. O'Dowd, and J. H. Seinfeld, Iodine oxide homogeneous nucleation: An explanation for coastal new particle production, Geophys. Res. Lett., 28, 1949-1952, 2001.
33. 4, Phys. Chem. Chem. Phys., 3, 1679-1687, 2001.
34. Hölscher, D., and R. Zellner, Absorption cross section of the IO radical and kinetics of the IO + IO and IO + NO reactions, in Proceedings of the Fifth European Symposium on Stratospheric Ozone 1999, EU Rep. 19340, pp. 264-267, Eur. Union, Brussels, 2000.
35. Honninger, G., Referenzspektren reaktiver Halogenverbindungen für DOAS-Messungen, Diploma thesis, Univ. of Heidelberg, Heidelberg, Germany, 1999.
36. Huebert, B. J., and R. M. Martin, Gas-phase far UV absorption spectrum of HBr and HI, J. Phys. Chem., 72, 3046-3048, 1968.
37. J) production, J. Phys. Chem. A, 104, 8001-8010, 2000.
38. Kinnersley, J. S., The climatology of the stratospheric THIN AIR model, Q. J. R. Meteorol. Soc., 122, 219-252, 1996.
39. 3, Phys. Chem. Chem Phys., 3, 393-401, 2001.
40. Kurucz, R. L., I. Furenhild, J. Brault, and L. Testermann, Solar flux atlas from 296 to 1300 nm, Natl. Sol. Obs. Atlas 1, Sunspot, N. M., June 1984.
41. Lary, D. J., and J. A. Pyle, Diffuse radiation, twilight and photochemistry, J. Atmos. Chem., 13, 373-392, 1991.
42. 2 mixtures, J. Phys. Chem., 99, 11,701-11,707, 1995.
43. Lumpe, J. D., et al., Comparison of POAM III ozone measurements with correlative aircraft and balloon data during SOLVE, J. Geophys. Res., 107, 8316, doi:10.1029/2001JD000472, 2002 [printed 108(D5), 2003].
44. McFiggans, G., J. M. C. Plane, B. J. Allan, L. J. Carpenter, H. Coe, and C. O'Dowd, A modeling study of iodine chemistry in the marine boundary layer, J. Geophys. Res., 105, 14,371-14,385, 2000.
45. 2, Atmos. Chem. Phys. Discuss., 2, 765-788, 2002.
46. + in the mass spectra of aerosols in the upper troposphere and lower stratosphere, Geophys. Res. Lett., 27, 3217-3220, 2000.
47. Murphy, D. M., D. S. Thompson, and A. Middlebrook, Bromine, iodine, and chlorine in single aerosol particles at Cape Grim, Geophys. Res. Lett., 24, 3197-3200, 1997.
48. Murphy, D. M., D. S. Thompson, and M. J. Mahoney, In situ measurements of organics, meteoritic material, mercury, and other elements in aerosol at 5 to 19 kilometers, Science, 282, 1664-1669, 1998.
49. 2 from solar and stellar occultation measurements in the Arctic vortex: Comparison with models and ILAS satellite measurements, J. Geophys. Res., 104, 21,585-21,593, 1999.
50. Pfeilsticker, K., W. T. Sturges, H. Bösch, C. Camy-Peyret, M. P. Chipperfield, A. Engel, R. Fitzenberger, M. Müller, S. Payan, and B.-M. Sinnhuber, Lower stratospheric organic and inorganic bromine budget for the arctic winter 1998/99, Geophys. Res. Lett., 27, 3305-3308, 2000.
51. 2 dimer, Geophys. Res. Lett., 28, 4595-4598, 2001.
52. Platt, U., Differential optical absorption spectroscopy (DOAS), in Air Monitoring by Spectroscopic Techniques, Chem. Anal. Ser., vol. 127, edited by M. W. Sigrist, pp. 27-84, John Wiley, Hoboken, N. J., 1994.
53. Pundt, I., J.-P. Pommereau, C. Phillips, and E. Lateltin, Upper limits of iodine oxide in the lower stratosphere, J. Atmos. Chem., 30, 173-185, 1998.
54. Rothman, L., et al., The HITRAN molecular spectroscopic database and HAWKS, J. Quant. Spectrosc. Radiat. Transfer, 60, 665-710, 1998.
55. Rowley, D. M., J. C. Mössinger, R. A. Cox, and R. L. Jones, The UV-visible cross section and atmospheric photolysis rate of HOI, J. Atmos. Chem., 34, 137-151, 1999.
56. Rowley, D. M., W. J. Bloss, R. A. Cox, and R. L. Jones, Kinetics of the IO + BrO reaction, J. Phys. Chem. A, 105, 7855-7864, 2001.
57. Sander, S. P., Kinetics and mechanism of the IO + IO reaction, J. Phys. Chem., 90, 2194-2199, 1986.
58. Sander, S. P., R. R. Friedl, W. B. DeMore, D. M. Golden, R. F. Hampson, R. E. Huie, G. K. Moortgat, A. R. Ravishankara, C. E. Kolb, and M. J. Molina, Chemical kinetics and photochemical data for use in stratospheric modeling, supplement to Evaluation 12: Update of key reactions, JPL Publ., 00-3, 2000.
59. Scheffler, H., and H. Elsässer, Physik der Sterne und der Sonne, BI Wissenschaftsverlag, Zürich, 1974.
60. Solomon, S., and A. L. Schmeltekopf, On the interpretation of zenith sky measurements, J. Geophys. Res., 92, 8311-8319, 1987.
61. Solomon, S., R. R. Garcia, and A. R. Ravishankara, On the role of iodine in ozone depletion, J. Geophys. Res., 99, 20,491-20,499, 1994.
62. Stutz, K., and U. Platt, Numerical analysis and estimation of the statistical error of differential optical absorption spectroscopy measurements with least-square methods, Appl. Opt., 35, 6041-6053, 1996.
63. Turnipseed, A. A., M. K. Gilles, J. B. Burkholder, and A. R. Ravishankara, Iodine chemistry in the stratosphere: Kinetics of the IO + ClO and IO + BrO reactions, Eos Trans. AGU, 76(46), F116, Fall Meet. Suppl., 1995.
64. Turnipseed, A. A., M. K. Gilles, J. B. Burkholder, and A. R. Ravishankara, Kinetics of the IO radical: 1. Reaction of IO + ClO, J. Phys. Chem. A, 101, 5517-5525, 1997.
65. Wennberg, P. O., J. W. Brault, T. F. Hanisco, R. J. Salawitch, and G. H. Mount, The atmospheric column abundance of IO: Implications for stratospheric ozone, J. Geophys. Res., 102, 8887-8898, 1997.
66. Wittrock, F., R. Müller, A. Richter, H. Bovensmann, and J. P. Burrows, Measurements of iodine monoxide (IO) above Spitsbergen, Geophys. Res. Lett., 27, 1471-1474, 2000.
67. World Meteorological Organization (WMO), Scientific assessment of ozone depletion 1998, WMO Global Ozone Res. Monit. Proj. Rep. 47, chap. 7, Geneva, Switzerland, 1999.