Preparation of anion-exchange resins from pine sulfuric acid lignin, one of the acid hydrolysis lignins

Journal of Wood Science

Volumn 49, Issue 5, 2003, Pages 423-429

  Matsushita, Yasuyuki ^a   Yasuda, Seiichi ^a  

^a NAGOYA UNIVERSITY   (Japan)

Author keywords

Acid hydrolysis lignin; Anion exchange resin; Epoxy reagents; Lignin; Mannich reaction

Indexed keywords

FORMALDEHYDE; HYDROLYSIS; ION EXCHANGE; LIGNIN; NEGATIVE IONS; SULFURIC ACID;

ANION-EXCHANGE RESINS; CHEMICAL CONVERSION;

ION EXCHANGE RESINS;

ANIONS; FORMALDEHYDE; HYDROLYSIS; ION EXCHANGE; ION EXCHANGERS; LIGNINS; SULFURIC ACID;

EID: 1342312046     PISSN: 14350211     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10086-002-0489-3     Document Type: Article

References (24)

1. Bailey B, Colucci C (1997) Research and development on the utilization of alcohol fuels at the National Renewable Energy Laboratory. Renewable Energy 10:273-278
2. Nguyen QA, Dickow JH, Duff BW, Farmer JD, Glassner DA, Ibsen KN, Ruth MF, Schell DJ, Thompson IB, Tucker MP (1996) NREL/DOE ethanol pilot-plant: current status and capabilities. Bioresource Technol 58:189-196
3. Himmel ME, Adney WS, Baker JO, Elander R, McMillan JD, Nieves RA, Sheehan JJ, Thomas SR, Vinzant TB, Zhang M (1997) Advanced bioethanol production technologies: a perspective. Fuel Chem Biomass ACS Symp Ser 666:2-45
4. Wyman CE (1994) Ethanol from lignocellulosic biomass: technology, economics and opportunities. Bioresource Technol 50:3-16
5. Wheals AE, Basso LC, Alves DMG, Amorim HV (1999) Fuel ethanol after 25 years. Trends Biotechnol 17:482-487
6. Cuzens JC, Miller JR (1997) Acid hydrolysis of bagasse for ethanol production. Renewable Energy 10:285-290
7. Saiki T (2000) Biomass ethanol project in America (in Japanese). Biosci Ind 58:362-365
8. Arbuzov VV, Ovchinnikov AI (1981) Method for improving the properties of compressed articles from hydrolysis lignin. Gidroliz Lesokhin Prom 6:13
9. Tzolova E, Christov Z (1978) Production of ion exchangers from technical hydrolysis lignin. Holzforschng 32:142-144
10. Tsolova E, Todorov T (1984) Study of the possible use of modified technical hydrolysis lignin as a filler in rubber mixes. Khim Ind 56:70-72
11. Enkvist T, Fremer KE, Lehtonen P, Mölsä U (1958) Some attempts to prepare anion exchangers from lignin. Svensk Papperstidn 61:811-814
12. Tai S, Nakano J, Migita N (1966) Studies on utilization of lignin. II. Preparation of anion exchanger from wood hydrolysis lignin. Mokuzai Gakkaisni 12:108-112
13. Yasuda S, Terashima N, Ito T (1981) Chemical structure of sulfuric acid lignin. IV. Reaction of arylglycerol-β-aryl ether with seventy-two percent sulfuric acid. Mokuzai Gakkaishi 27:879-884
14. 11C] with seventy-two percent sulfuric acid. Mokuzai Gakkaishi 28:383-387
15. Yasuda S, Tachi M, Takagi Y (1989) Phenolization of red pine sulfuric acid lignin and guaiacyl sulfuric acid lignin model in the presence of sulfuric acid catalyst. Mokuzai Gakkaishi 35:513-520
16. Yasuda S, Ito K, Hamaguchi E, Matsushita Y (1997) Ready chemical conversion of acid hydrolysis lignin into water-soluble lignosulfonate. I. Successive treatment of acid hydrolysis lignin by phenolation, hydroxymethylation and sulfonation. Mokuzai Gakkaishi 43:68-74
17. Yasuda S, Hamaguchi E, Asano K (1999) Ready chemical conversion of acid hydrolysis lignin into water-soluble lignosulfonate. III. Successive treatment of acid hydrolysis lignin and a lignin model compound by phenolation and arylsulfonation. J Wood Sci 45:245-249
18. Yasuda S, Asano K (2000) Preparation of strongly acidic cation-exchange resins from gymnosperm acid hydrolysis lignin. J Wood Sci 46:477-479
19. Matsushita Y, Yasuda S (2003) Reactivity of a condensed-type lignin model compound in Mannich reaction and preparation of cationic surfactant from sulfuric acid lignin. J Wood Sci 49:166-171
20. Browning BL (1967) Determination of lignin. In: Methods of wood chemistry. Interscience, New York, pp 785-787
21. Yasuda S, Hamaguchi E, Matsushita Y, Goto H, Imai T (1998) Ready chemical conversion of acid hydrolysis lignin into water-soluble lignosulfonate. II. Hydroxymethylation and subsequent sulfonation of phenolized lignin model compounds. J Wood Sci 44:116-124
22. Pulkkinen E, Mäkelä A, Mikkonen H (1989) Preparation and testing of cationic flocculants from kraft lignin. In: Lignin properties and materials. American Chemical Society, Washington, DC. pp 284-293
23. Fuchiwaki G, Nishikazi T (1974) Ion exchange resin. In: Kinousei koubunnshi zikkengaku, vol 7. Kyouritsushuppan, Tokyo, pp 23-27
24. Mikawa H, Sato K, Takasaki C, Ebisawa K (1956) Studies on the cooking mechanism of wood. XV. Mannich reaction on lignin model compounds and the estimation of the amount of the simple guaiacyl nucleus in thiolignin. Bull Chem Soc Jpn 29:259-265