A Water-Soluble m-Phenylene Ethynylene Foldamer

Organic Letters

Volumn 6, Issue 4, 2004, Pages 469-472

  Stone, Matthew T ^a   Moore, Jeffrey S ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

3 PHENYLENE ETHYNYLENE; ACETONITRILE; BENZENE DERIVATIVE; ETHYLENE DERIVATIVE; HEXAETHYLENE GLYCOL; OLIGOMER; PINENE; UNCLASSIFIED DRUG; WATER;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL COMPOSITION; CONFORMATION; ULTRAVIOLET SPECTROSCOPY;

EID: 1342290297     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol036238k     Document Type: Article

References (20)

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14. The program Dynafit was used for the nonlinear least-squares fitting: Kuzmic, P. Anal. Biochem. 1996, 237, 260-273.
15. Connors, K. A. Binding Constants: The Measurement of Molecular Complex Stability; Wiley: New York, 1987.
16. Note that points on the Benesi-Hildebrand plots corresponding to substoichiometric equivalents of (-)-α-pinene were eliminated because the linearity of these plots assumes that at equilibrium, the [unbound guest] is roughly equal to [guest-host] + [unbound guest], which does not hold true at these concentrations.
17. Wilchek, M.; Bayer, E. A. Biomol. Eng. 1999, 16, 1-4.
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19. Slower kinetics of binding were also observed for a dumbbell-shaped guest in a solution of 40% water in acetonitrile where the host-guest complex that formed resembled a rotaxane-like structure. The slower rate was attributed to the large conformational distortion required of the host.
20. Tanatani, A.; Hughes, T. S.; Moore, J. S. Angew. Chem., Int. Ed 2002, 41, 325-328.