Deacetylation of 2′-O-Ts-3′,5′-di-O-acetylpurine nucleosides via a free radical reaction

Journal of Chemical Research - Part S

Volumn , Issue 11, 2003, Pages 706-707

  Liu, Qi Bin ^a   Feng, Feng ^a   Qu, Gui Rong ^a  

^a HENAN NORMAL UNIVERSITY   (China)

Author keywords

AIBN; Deacetylation; Free radical; n Bu3SnH

Indexed keywords

PURINE NUCLEOSIDE;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; DEACETYLATION; REACTION TIME;

EID: 1342290002     PISSN: 03082342     EISSN: None     Source Type: Journal    
DOI: 10.3184/030823403322863012     Document Type: Article

References (9)

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7. A similar cleavage of benzoates by tin hydride has been reported. See: D.R. Kelly, J.G. Mahdi, Tetrahedron Lett., 2002, 43, 511.
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9. For entry 4: After refluxing at 75°C for 4h, 2′-OTs-3′ ,5′-di-O-acetyl-2-amino-6-chloropurine nucleoside was converted into 2′-OTs-3′,5′-di-O-acetyl-2-aminopurine nucleoside.