A unique approach to metal-induced Bergman cyclization: Long-range enediyne activation by ligand-to-metal charge transfer

Angewandte Chemie - International Edition

Volumn 44, Issue 4, 2005, Pages 592-595

  Bhattacharyya, Sibaprasad ^a   Pink, Maren ^a   Baik, Mu Hyun ^a   Zaleski, Jeffrey M ^a  

^a INDIANA UNIVERSITY   (United States)

Author keywords

Charge transfer; Cyclization; Enediynes; Molybdenum; Radicals

Indexed keywords

CHARGE TRANSFER; COMPLEXATION; MOLYBDENUM; POLARIZATION;

BERGMAN CYCLIZATION; CHARGE REPULSION; ELECTRONIC POLARIZATION EFFECT;

AROMATIC HYDROCARBONS;

ALKENYLDIALKYNE DERIVATIVE; LIGAND; METAL; UNCLASSIFIED DRUG;

ARTICLE; CYCLIZATION; ION TRANSPORT; PHASE TRANSITION; POLARIZATION; REACTION ANALYSIS; TEMPERATURE DEPENDENCE;

CYCLIZATION; LIGANDS; METALS; MODELS, MOLECULAR;

EID: 13244275128     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200461825     Document Type: Article

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