The relation between ligand structures, coordination stereochemistry, and electronic and thermodynamic properties

Coordination Chemistry Reviews

Volumn 123, Issue 1-2, 1993, Pages 1-48

  Comba, Peter ^a  

^a UNIVERSITY OF BASEL   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 13244259405     PISSN: 00108545     EISSN: None     Source Type: Journal    
DOI: 10.1016/0010-8545(93)85051-5     Document Type: Article

References (236)

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5. Aspects of the Stereochemistry of Six-Coordination
6. From crystal statics to chemical dynamics
7. Fractional bonds: relations among their lengths, strengths, and stretching force constants
8. Complexes of 2,2?,2?-Nitrilotriphenol. Part 1. A Study of Bimolecular Nucleophilic Substitution at the Boron Atom
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10. Spectroscopy of 3d Complexes
11. Do the ``Ligand Field'' Parameters in Lanthanides Represent Weak Covalent Bonding?
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13. A perturbation representation of weak covalent bonding
14. The shapes of main-group molecules; A simple semi-quantitative molecular orbital approach
15. Local and cooperative Jahn-Teller interactions in model structures
16. Static and dynamic Jahn-Teller distortions in CuN6 complexes. Crystal structures and EPR spectra of complexes between copper(II) and rigid, tridentate cis,cis-1,3,5-triaminocyclohexane (tach: Cu(tach)2(ClO4)2, Cu(tach)2(NO3)2. Crystal structure of Ni(tach)2(NO3)2
17. Hindered ligand systems. IV. Complexes of cis,cis-1,3,5-tris(pyridine-2-carboxaldimino)cyclohexane. Trigonal-prismatic vs. octahedral coordination
18. Complexes with sulphur and selenium donor ligands. Part II. Crystal spectra of some tris(bidentate ligand)?metal(III) complexes
19. Analysis of trigonal-prismatic and octahedral preferences in hexaamine cage complexes
20. The Functional Group in Ligand-Field Studies: the Empirical and Theoretical Status of the Angular Overlap Model
21. EPR spectrum and metal-ligand bonding parameters of a low-spin (hexaamine)iron(III) complex
22. ESR STUDY OF COPPER(II) COMPLEXES OF α-AMINO ACIDS. COORDINATION MODES AND METAL-LIGAND BONDS IN FROZEN AQUEOUS SOLUTIONS
23. Electron spin resonance spectra of tetragonal chromium(III) complexes. I. trans-[Cr(NH3)4XY]n+ and trans-Cr(py)4XY]n+ in frozen solutions and powders. Correlation between zero-field splittings and ligand field parameters via complete d-electron calculations
24. Molecular Mechanics
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26. Chiral Tetraamines Based on (S)-2-(Aminomethyl)pyrrolidine: Template synthesis and properties of copper(II) complexes
27. The mode of stereoselective association between complex cation and complex anion.
28. Energy-Minimized Structures and Calculated and Experimental Isomer Distributions in the Hexaaminecobalt(III) system [Co(trap)2]3+ (trap = 1,2,3-propanetriamine)
29. Stereochemical properties of copper(II) complexes of (RS)-3-aminohexahydroazepine: Crystal and molecular structures of [(R)-3-aminohexahydroazepine][(S)-3-aminohexahydroazepine]copper(II) diperchlorate, [Cu(R-ahaz)(S-ahaz)](ClO4)2 and related complexes.
30. Anionopentaaminecobalt(III) complexes with polyamine ligands. XIX. Computer simulated intermediates for dissociative aquation reactions
31. The structures and energy minimization analyses of the macrotricyclic cage complex [Co(nosartacn)]3+and its precursor [Co(taetacn)]3+
32. Molecular mechanics studies of the conformation of the macrocycle ?-2,12-dimethyl-3,7,11,17-tetra-azabicyclo[11.3.1]heptadeca-1(17),13,15-triene (L1) in the free state and in a series of nickel complexes. Crystal and molecular structure of L1
33. The crystal structure of R,S,R,S-(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)nickel(II) bis(trifluoromethanesulphonate)?acetone hydrate, [Ni(tmtactd)][CF3SO3]2�Me2CO�H2O, and a strain-energy minimization analysis of four-, five-, and six-co-ordinate nickel(II)?tmtactd solvento complexes
34. STEREOCHEMISTRY OF COMPLEXES WITHN-ALYKLATED AMINO ACIDS. I. CRYSTAL STRUCTURE AND CONFORMATIONAL ANALYSIS OFbis-(L-N, N-DIMETHYLVALINATO)COPPER(II)
35. Conformational analysis of coordination compounds. XI. Molecular structure of tetraammine{(±)-pentane-2,4-diamine)cobalt(III) dithionate
36. Strain energy minimization study of the mechanism of, and the barrier to, conformational interconversion in five-membered diamine chelate rings
37. Origin of macrocyclic enthalpy
38. The N?M?N bond angle in the chelate ring of ethylenediamine. The crystal structure of tetra-aqua(ethylenediamine)nickel(II) nitrate
39. Molecular mechanics and crystallographic study of hole sizes in nitrogen-donor tetraaza macrocycles
40. Anomalous metal ion size selectivity of tetraaza macrocycles
41. Origin of the high ligand field strength and macrocyclic enthalpy in complexes of nitrogen-donor macrocycles
42. Stereochemical activity of lone pairs. The crystal and molecular structures of the salts of chloro(1,4,7,10,13,16-hexaoxacyclo-octadecane)tin(II). Calculation of macrocyclic cavity size by force field methods
43. Studies in the flexibility of macrocycle ligands. Calculation of macrocycle cavity size by force-field methods. Crystal and molecular structures of [CoLCl][ClO4]2 and [CuL][PF6]2{L = 2,13-dimethyl-3,6,9,12,18-penta-azabicyclo[12.3.1]octadeca-1(18),14,16-triene}
44. Letters
45. Application of strain energy minimisation to geometric isomers of metal complexes
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47. The structure ofu-fac-(Diethylenetriamine)[di(3-aminopropyl)amine]cobalt(III) perchlorate, [Co(dien)(dpt)] (ClO4)3, and an energy minimization analysis of the [Co(dien)(dpt)]3+system
48. Energy-Minimized Structures and Calculated and Experimental Isomer distributions in the hexaamine-cobalt(III) system [Co(L)2]3+ with the chiral facially-coordinating triamine (l = butane-1,2,4-triamine)
49. Stereoselective Coordination to Chiral Matrices. Cobalt(III). Chemistry of Simple Facially Coordinating Chiral Triamines
50. Strain affected electron transfer: the [Co(tmen)3]2+/3+ couple (tmen = tetramethylethylenediamine)
51. Steric Crowding in Coordination Compounds: Electron-transfer kinetics of the [Co(tmen)3]3+/2+ couple (tmen = 2,3-dimethylbutane-2,3-diamine)
52. Stochastic search for the conformations of bicyclic hydrocarbons
53. A new approach to probing conformational space with molecular mechanics: random incremental pulse search
54. A New Method for Molecular Mechanics
55. Electronegativity equalization: application and parametrization
56. Electronegativity and bond energy
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60. Hydrogen bonding in MM2
61. Crystallographic and molecular mechanics study of the copper perchlorate complex of a larger reinforced macrocycle
62. Electron spin resonance and electronic spectra and crystal and molecular structures of copper(II) amino acid complexes
63. The Chelate, Cryptate and Macrocyclic Effects
64. Empirical force-field calculations of strain-energy contributions to the thermodynamics of complex formation. Part 1. The difference in stability between complexes containing five- and six-membered chelate rings
65. Bicapped tetrahedral, trigonal prismatic, and octahedral alternatives in main and transition group six-coordination
66. Molecular Structure and Dynamics of Aminopolycarboxylates and their Lanthanide Ion Complexes.
67. Diastereoisomerism and diastereoselectivity in metal complexes
68. Elektronentransferbarrieren als Funktion der Ligandenstruktur in CoN63+/CoN62+-Paaren Beziehungen zwischen der Struktur und der Redoxreaktivit�t
69. The stabilization of monovalent copper ions by complexation with saturated tertiary amine ligands in aqueous solutions. The case of 2,5,9,12-tetramethyl-2,5,9,12-tetraazatridecane
70. Encapsulated metal ions
71. Developments in the synthesis and reactivity of encapsulated metal ions
72. 6, 13-Diamino-6,13-dimethyl-1,4,8,11-tetra-azacyclotetradecane, L7, a new, potentially sexidentate polyamine ligand. Variable co-ordination to cobalt (III) and crystal structure of the complex[CO(L7)]Cl2[ClO4]
73. Oxidation-reduction behavior of complexes containing macrocyclic ligands. Electrochemical comparison of complexes with the metals iron through zinc
74. A spectrochemical and electrochemical study of complexes of cobalt with macrocyclic ligands having various degrees of unsaturation
75. Reduction potentials of pentaammine complexes of cobalt(III), rhodium(III) and iridium(III): physical correlations
76. Dicopper(II) Complexes of Spiro Macrobicycles With Aza and Thia Aza Donor Sets
77. Template syntheses of chiral tetradentate ligands derived from L-amino acids. Structural and spectroscopic characterization of the free ligands and of their copper(II) complexes
78. Comparisons of thirteen- to sixteen-membered tetra-azacycloalkane copper(II) complexes derived from template syntheses involving nitroethane and formaldehyde. Crystal structures of (10-methyl-10-nitro-1,4,8,12-tetra-azacyclopentadecane)copper(II) and (3-methyl-3-nitro-1,5,9,13-tetra-azacyclohexadecane)copper(II) perchlorates