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Volumn 44, Issue 4, 2005, Pages 632-634

Ruthenocene analogues with a novel C5B2 ligand: (η7-4-borataborepine)(η5-penta- methylcyclopentadienyl)ruthenium complexes

Author keywords

Boron; Heterocycles; Ring expansion; Ruthenium; Sandwich complexes

Indexed keywords

COMPLEXATION; ELECTRONS; MASS SPECTROMETRY;

EID: 13244257034     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200461719     Document Type: Article
Times cited : (9)

References (23)
  • 4
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    • a) W. Siebert, R. Hettrich, H. Pritzkow, Angew. Chem. 1994, 106, 215-217; Angew. Chem. Int. Ed. Engl. 1994, 33, 203-204;
    • (1994) Angew. Chem. Int. Ed. Engl. , vol.33 , pp. 203-204
  • 6
    • 13244275518 scopus 로고    scopus 로고
    • note
    • max = 28.3°) collected, 5778 unique reflections [R(int) = 0.0391]. R1 = 0.0401 (I > 2σ(I)), wR2 = 0.0926 (all data). CCDC-244072 (1a), CCDC-244073 (4a), CCDC-244074 (4b) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac.uk).
  • 10
    • 13244279980 scopus 로고    scopus 로고
    • note
    • 2 is folded by 40.7° along the B⋯B vector, very similar to its green iron analogue.[2] The Ru-C2 bond length [2.029, cf. Fe-C 1.899 Å] is markedly shorter than the other Ru-C bond lengths of the heterocycle.
  • 11
    • 13244278554 scopus 로고    scopus 로고
    • note
    • 102Ru: 550.2344, found: 550.2338, Δ = -0.7 mmu.
  • 16
    • 33748215301 scopus 로고
    • and references therein
    • b) A. J. Ashe III, J. W. Kamp, W. Klein, R. Rousseau, Angew. Chem. 1993, 105, 1112; Angew. Chem. Int. Ed. Engl. 1993, 32, 1065-1066, and references therein.
    • (1993) Angew. Chem. Int. Ed. Engl. , vol.32 , pp. 1065-1066
  • 18
    • 0142245926 scopus 로고
    • E. O. Fischer, S. Breitschaft, Angew. Chem. 1963, 75, 94-95; Angew. Chem. Int. Ed. Engl. 1963, 2, 44.
    • (1963) Angew. Chem. Int. Ed. Engl. , vol.2 , pp. 44
  • 20
    • 0030824441 scopus 로고    scopus 로고
    • A. J. Ashe III, S. Al-Ahmad, J. W. Kamp, V. G. Young, Jr., Angew. Chem. 1997, 109, 2104-2106; Angew. Chem. Int. Ed. Engl. 1997, 36, 2014-2016.
    • (1997) Angew. Chem. Int. Ed. Engl. , vol.36 , pp. 2014-2016
  • 22
    • 0141670329 scopus 로고    scopus 로고
    • X. Fang, D. Woodmansee, X. Bu, G. C. Bazan, Angew. Chem. 2003, 115, 4648-4652; Angew. Chem. Int. Ed. 2003, 42, 4510-4514.
    • (2003) Angew. Chem. Int. Ed. , vol.42 , pp. 4510-4514
  • 23
    • 13244295972 scopus 로고    scopus 로고
    • University of Münster, Germany
    • MO calculations for 1 and 4 are in progress (Dr. I. Hyla-Kryspin, University of Münster, Germany).
    • Hyla-Kryspin, I.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.