Experimental data on the speciation of sulfur as a function of oxygen fugacity in basaltic melts

Geochimica et Cosmochimica Acta

Volumn 69, Issue 2, 2005, Pages 497-503

  Jugo, Pedro J ^a,b   Luth, Robert W ^a   Richards, Jeremy P ^a  

^a UNIVERSITY OF ALBERTA   (Canada)

^b GOETHE UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

BASALT; FUGACITY; IGNEOUS GEOCHEMISTRY; MELT; OXYGEN; SPECIATION (CHEMISTRY); SULFUR;

EID: 13144290140     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.gca.2004.07.011     Document Type: Article

References (28)

1. L.L. Baker M.J. Rutherford Crystallization of anhydrite-bearing magmas Trans. R. Soc. Edinburgh: Earth Sci. 87 1996 243-250
2. L.L. Baker M.J. Rutherford Sulfur diffusion in rhyolite melts Contrib. Mineral. Petrol. 123 1996 335-344
3. C. Ballhaus R.F. Berry D.H. Green Oxygen fugacity controls in the Earth's upper mantle Nature 348 1990 437-440
4. C. Ballhaus R.F. Berry D.H. Green High-pressure experimental calibration of the olivine-orthopyroxene-spinel oxygen geobarometer. Implications for the oxidation state of the upper mantle Contrib. Mineral. Petrol. 107 1991 27-40
5. D. Canil D. Virgo C.M. Scarfe Oxidation state of mantle xenoliths from British Columbia, Canada Contrib. Mineral. Petrol. 104 1990 453-462
6. M.R. Carroll M.J. Rutherford Sulfur speciation in hydrous experimental glasses of varying oxidation states. Results from measured wavelength shifts of sulfur X-rays Am. Mineral. 73 1988 845-849
7. J.C.M. De Hoog K.H. Hattori R.P. Hoblitt Oxidized sulfur-rich mafic magma at Mount Pinatubo, Philippines Contrib. Mineral. Petrol. 146, 2004 750-761
8. A.A. Gurenko H.-U. Schmincke Petrology, geochemistry, S, Cl, and F abundances and S oxidation state of sideromelane glass shards from Pleistocene ash layers north ands south of Gran Canaria (ODP Leg 157) Contrib. Mineral. Petrol. 131 1998 95-110
9. A.A. Gurenko H.-U. Schmincke S concentrations and its speciation in Miocene basaltic magmas north and south of Gran Canaria (Canary Islands): Constraints from glass inclusions in olivine and clinopyroxene Geochim. Cosmochim. Acta 64 2000 2321-2337
10. J.S. Huebner M. Sato The oxygen fugacity-temperature relationships of manganese oxide and nickel oxide buffers Am. Mineral. 55 1970 934-952
11. P.J. Jugo Experimental study on the speciation and solubility of sulfur and the behavior of highly siderophile elements in sulfide- and sulfate-saturated basaltic melts at 1300°C and 1GPa 2003 University of Alberta Ph.D. thesis
12. T. Katsura S. Nagashima Solubility of sulfur in some magmas at 1 atmosphere Geochim. Cosmochim. Acta 38 1974 517-531
13. A. Kilinc I.S.E. Carmichael M.L. Rivers R.O. Sack The ferric-ferrous ration of natural silicate liquids equilibrated in air Contrib. Mineral. Petrol. 83 1983 136-140
14. H. Kucha R. Wouters O. Arkens Determination of sulfur and iron valence by microprobe Scanning Microscopy 3 1989 89-97
15. S.J. Matthews D.H.D. Moncrieff M.R. Carroll Empirical calibration of the sulphur valence oxygen barometer from natural and experimental glasses: Method and applications Mineral. Mag. 63 1999 421-431
16. D.A. McKeown I.S. Muller H. Gan I.L. Pegg W.C. Stolte Determination of sulfur enviroments in borosilicate waste glasses using X-ray absorption near-edge spectroscopy J. Non-Crystalline Solids 333 2004 74-84
17. N. Métrich R. Clocchiatti Sulfur abundance and its speciation in oxidized alkaline melts Geochim. Cosmochim. Acta 60 1996 4151-4160
18. IV) in arc magmas: Implications for volcanic sulfur emissions Geophys. Res. Lett. 29/11 2002 doi:10.1029/2001GL014607
19. 2 melts under various oxygen partial pressures at 1100°C, 1250°C and 1300°C Bull. Chem. Soc. Jpn. 46 1973 3099-3103
20. K. Nilsson C.L. Peach Sulfur speciation, oxidation state and sulfur concentration in backarc magmas Geochim. Cosmochim. Acta 57 1993 3807-3813
21. E. Paris G. Giuli M.R. Carroll I. Davioli The valence and speciation of sulfur in glasses by X-ray absorption spectroscopy Can. Mineral. 39 2001 331-339
22. M.R. Rampino S.H. Ambrose Volcanic winter in the Garden of Eden: The Toba super-eruption and the Late Pleistocene human population crash (eds. F.W. McCoy G. Heiken) In Volcanic Hazards and Disasters in Human Antiquity 2000 71-82 Spec. Paper 345. Geol. Soc. Am.
23. P.L. Roeder R.F. Emslie Olivine-liquid equilibrium Contrib. Mineral. Petrol. 29 1970 275-289
24. J.C. Stormer I.S.E. Carmichael The free energy of sodalite and the behavior of chloride, fluoride and sulfate in silicate magmas Am. Mineral. 56 1971 292-306
25. 2+-Mg cation-partitioning between olivine and basaltic liquid on pressure, temperature and composition: An experimental study to 30 kbars Contrib. Mineral. Petrol. 101 1989 261-273
26. P.J. Wallace I.S.E. Carmichael Sulfur in basaltic melts Geochim. Cosmochim. Acta 56 1992 1863-1874
27. P.J. Wallace I.S.E. Carmichael S speciation in submarine basaltic glasses as determined by measurements of SKα X-ray wavelength shifts Am. Mineral. 79 1994 161-167
28. K.T. Winther E.B. Watson G.M. Korenwosky Magmatic sulfur compounds and sulfur diffusion in albite melt at 1 GPa and 1300-1500°C Am. Mineral. 83 1998 1141-1151