The role of functional monomer-template complexation on the performance of atrazine molecularly imprinted polymers

Analytical Letters

Volumn 38, Issue 1, 2005, Pages 57-69

  Svenson, Johan ^a   Zheng, Ning ^a   Föhrman, Ulrika ^a   Nicholls, Ian A ^a  

^a LINNAEUS UNIVERSITY   (Sweden)

Author keywords

Atrazine; Molecularly imprinted polymers; Monomer complexation; Template

Indexed keywords

ACETIC ACID; ATRAZINE; CHLOROFORM; HERBICIDE; METHACRYLIC ACID; MONOMER; POLYMER; PYRIDINE DERIVATIVE; TRIAZINE DERIVATIVE;

ARTICLE; BINDING AFFINITY; COMPLEX FORMATION; DISSOCIATION CONSTANT; DRUG MIXTURE; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; MOLECULAR IMPRINTING; POLYMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; RADIOASSAY; SYNTHESIS;

EID: 13144282678     PISSN: 00032719     EISSN: None     Source Type: Journal    
DOI: 10.1081/AL-200043443     Document Type: Article

References (21)

1. Andersson, H.S., Karlsson, J.G., Piletsky, S.A., Koch-Schmidt, A.-C., Mosbach, K., and Nicholls, I.A. 1999. Study of the nature of recognition in molecularly imprinted polymers II [1] - Influence of monomer-template ratio and sample load on retention and selectivity. J. Chrom. A. 848: 39-49.
2. Andersson, H.S., Koch-Schmidt, A.-C., Ohlson, S., and Mosbach, K. 1996. Study of the nature of recognition in molecularly imprinted polymers. J. Mol. Rec. 9: 675-682.
3. Andersson, H.S. and Nicholls, I.A. 1997. Spectroscopic evaluation of molecular imprinting polymerization systems. Bioorg. Chem. 25: 203-211.
4. Bruno, T.J. and Svoronos, P.D.N. 1993. CRC Handbook of Basic Table for Chemical Analysis; CRC Press: New York, 212.
5. Glad, M., Norrlöw, O., Sellergren, B., Siegbahn, N., and Mosbach, K. 1985. Use of silane monomers for molecular imprinting and enzyme entrapment in polysiloxane-coated porous silica. J. Chrom. 347: 11-23.
6. Günther, H. 2001. Chemical shifts through hydrogen bonding. In NMR Spectroscopy, 2nd ed., ed. H. Günther, 97-99. New York: Wiley.
7. Haupt, K. and Mosbach, K. 2000. Molecularly imprinted polymers and their use in biomimetic sensors. Chem. Rev. 100: 2495-2504.
8. Karlsson, J.G., Andersson, L.I., and Nicholls, I.A. 2001. Probing the molecular basis for ligand-selective recognition in molecularly imprinted polymers selective for the local anaesthetic bupivacaine. Anal. Chim. Acta. 435: 57-64.
9. Matsui, J., Fujiwara, K., and Takeuchi, T. 2000. Atrazine-selective polymers prepared by molecular imprinting of trialkylmelamines as dummy template species of atrazine. Anal. Chem. 72: 1810-1813.
10. Mayes, A.G., Andersson, L.I., and Mosbach, K. 1994. Sugar binding polymers showing high anomeric and epimeric discrimination obtained by noncovalent molecular imprinting. Anal. Biochem. 222: 483-488.
11. Muldoon, M.T. and Stanker, L.H. 1997. Molecularly imprinted solid phase extraction of atrazine from beef liver extracts. Anal. Chem. 69: 803-808.
12. Nicholls, I.A. 1995. Thermodynamic considerations for the design of and ligand recognition by molecularly imprinted polymers. Chem. Lett.: 1035-1036.
13. Piletsky, S.A., Piletskaya, E.V., Elgersma, A.V., Yano, K., Karube, I., Parthometz, Y.P., and El'skaya, A.V. 1995. Atrazine sensing by molecularly imprinted membranes. Biosens. Bioelectron. 10: 959-964.
14. Ramström, O., Andersson, L.I., and Mosbach, K. 1993. Recognition sites incorporating both pyridinyl and carboxy functionalities prepared by molecular imprinting. J. Org. Chem. 58: 7562-7564.
15. Sellergren, B. 2000. Imprinted polymers with memory for small molecules, proteins, or crystals. Angew. Chem. Int. Ed. 39: 1031-1037.
16. Sellergren, B., Lepistö, M., and Mosbach, K. 1988. Highly enantioselective and substrate-selective polymers obtained by molecular imprinting utilizing noncovalent interactions. NMR and chromatographic studies on the nature of recognition. J. Am. Chem. Soc. 110: 5853-5860.
17. Siemann, M., Andersson, L.I., and Mosbach, K. 1996. Selective recognition of the herbicide atrazine by noncovalent molecularly imprinted polymers. J. Agric. Food Chem. 44: 141-145.
18. 1H Nuclear magnetic resonance study of the molecular imprinting of (-)-nicotine: template self-association, a molecular basis for cooperative ligand binding. J. Chrom. A. 1024: 39-44.
19. Takeuchi, T., Dobashi, D., and Kimura, K. 2000. Molecular imprinting of biotin derivatives and its application to competitive binding assay using nonisotopic labelled ligands. Anal. Chem. 72: 2418-2422.
20. Whitcombe, M.J., Martin, L., and Vulfson, E.N. 1998. Predicting the selectivity of imprinted polymers. Chromatographia 47: 457-464.
21. Wulff, G. 2002. Enzyme-like catalysis by molecularly imprinted polymers. Chem. Rev. 102: 1-27.