SCOPUS 정보 검색 플랫폼

Volumn 19, Issue 46, 1978, Pages 4487-4490

Reduction of cyclic enone with bulky trialkylborohydrides

Author keywords

[No Author keywords available]

Indexed keywords

EID: 13144267081 PISSN: 00404039 EISSN: None Source Type: Journal
DOI: 10.1016/S0040-4039(01)95259-1 Document Type: Article

Times cited : (16)

References (8)

1
- 33847799728
- and references cited therein.
- (1976) J. Am. Chem. Soc. , vol.98 , pp. 3383
- Krishnamurthy¹ Brown²

3
- 84914391632
- Product ratios were determined by integration of the vinyl proton of the 180MHz or 60MHz PMR spectra of the products. The vinyl proton of the β-allylic alcohols occur as a broadened singlet at slightly higher field than the vinyl proton (doublet, J=4.5 Hz) of the α-anylic alcohols.

5
- 84914391630
- Complexation of L-Selectride with the C-9α oxygen could effectively hinder the underside (α-face) of the molecule, necessitating approach of another molecule of reducing agent from the top (β-face). The C-9α substituent is too far removed from the carbonyl carbon to assist in delivering the reducing agent via intramolecular assistance from the α-face.

6
- 0343410809
- The chemistry of 2-methyltetrahydropyran-4-one: An L-Selectride reaction that gives predominantly the equatorial alcohol
- For a recent example of intramolecular assistance by an ether oxygen during a Selectride reduction see
- (1977) Canadian Journal of Chemistry , vol.56 , pp. 789
- Wigfield¹ Feiner²

7
- 1542533545
- 3 see
- (1977) J. Am. Chem. Soc. , vol.99 , pp. 6237
- Brown¹ Khuri² Krishnamurthy³

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