Synthesis and characterization of saturated and unsaturated polysulfide polymers and their thermal degradation processes investigated by flash pyrolysis-gas chromatography/mass spectrometry

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 43, Issue 3, 2005, Pages 638-649

  Sundarrajan, Subramanian ^a   Surianarayanan, Mahadevan ^a   Srinivasan, Kalathur Sabdham Vangepuram ^a  

^a CENTRAL LEATHER RESEARCH INSTITUTE   (India)

Author keywords

Degradation; Mass spectrometry; Polysulfides; Pyrolysis; Synthesis

Indexed keywords

BUTADIENE; DEGRADATION; DIFFERENTIAL SCANNING CALORIMETRY; FOURIER TRANSFORM INFRARED SPECTROSCOPY; GAS CHROMATOGRAPHY; GEL PERMEATION CHROMATOGRAPHY; MASS SPECTROMETRY; POLYETHYLENES; PYROLYSIS; SYNTHESIS (CHEMICAL); THERMODYNAMIC STABILITY; THERMOGRAVIMETRIC ANALYSIS; UNSATURATED POLYMERS;

HYDROXY-TERMINATED POLYBUTADIENE (HTTB); PYROLYTIC PRODUCTS; THIOPHENE; VINYL POLYMERS;

POLYSULFIDES;

EID: 13144251203     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/pola.20535     Document Type: Article

References (39)

1. The Chemistry of Sulfides; Tobolsky, A. V., Ed.; Wiley-Interscience: New York, 1968.
2. Sander, S. R.; Karo, W. In Polymer Synthesis III Organic Chemistry: A Series of Monographs; Academic: New York, 1980; Chapter 3, p 68.
3. Montaudo, G.; Puglisi, C.; Scamporrino, E.; Vitalini, D. J Polym Sci Part A: Polym Chem 1987, 25, 475.
4. Machon, J. P.; Nicco, A. Eur Polym J 1971, 7, 1693.
5. Machon, J. P.; Nicco, A.; Mariage, A.; Philippe, T. Eur Polym J 1972, 8, 547.
6. Catsiff, E. H.; Gillis, M. N.; Gobran, R. H. J Polym Sci Part A-l: Polym Chem 1971, 9, 1271.
7. Sundarrajan, S.; Surianarayanan, M.; Srinivasan, K. S. V.; Kishore, K. Macromolecules 2002, 35, 3331.
8. Du, T. Thermochim Acta 1989, 138, 189.
9. Beck, W. H. Combust Flame 1987, 70, 171.
10. Ganesh, K.; Sundarrajan, S.; Kishore, K.; Ninan, K. N.; George, B.; Surianarayanan, M. Macromolecules 2000, 33, 326.
11. Chen, J. K.; Brill, T. B. Combust Flame 1991, 87, 217.
12. Montaudo, G.; Puglisi, C.; de Leeuw, J. W.; Hargers, W.; Kishore, K.; Ganesh, K. Macromolecules 1996, 29, 6466.
13. Montaudo, G.; Puglisi, C.; Blazo, M.; Kishore, K.; Ganesh, K. J Anal Appl Pyrolysis 1994, 29, 207.
14. Montaudo, G.; Przybylski, M.; Ringsdorf, H. Makromol Chem 1975, 176, 1763.
15. Montaudo, G.; Puglisi, C.; Scamporrino, E.; Vitalini, D. Macromolecules 1986, 19, 2157.
16. Montaudo, G.; Puglisi, C.; Scamporrino, E.; Vitalini, D. Polymer 1987, 28, 477.
17. Sundarrajan, S.; Srinivasan, K. S. V. Macromol Rapid Commun 2003, 24, 724.
18. Bottino, F.; Foti, S.; Montaudo, G.; Pappalardo, S.; Luderwald, I.; Przybylski, M. J Polym Sci Polym Chem Ed 1978, 16, 3131.
19. Montaudo, G.; Puglisi, C.; Berti, C.; Marianucci, E.; Pilati, F. J Polym Sci Part A: Polym Chem 1989, 27, 2277.
20. Montaudo, G.; Puglisi, C.; Berti, C.; Marianucci, E.; Pilati, F. J Polym Sci Part A: Polym Chem 1989, 27, 2657.
21. Montaudo, G.; Puglisi, C.; Samperi, F. J Polym Sci Part A: Polym Chem 1994, 32, 1807.
22. Bruno, G.; Foti, S.; Maravigna, P.; Montaudo, G.; Przybylski, M. Polymer 1977, 18, 1149.
23. Montaudo, G.; Puglisi, C.; Samperi, F. Makromol Chem Phys 1994, 195, 1225.
24. Montaudo, G.; Przybylski, M.; Ringsdorf, H. Makromol Chem 1975, 176, 1753.
25. Ehlers, G. F. L.; Fish, K. R.; Powell, W. R. J Polym Sci Part A-1: Polym Chem 1969, 7, 2955.
26. Christopher, N. S. J.; Cotter, J. L.; Knight, G. J.; Wight, N. W. J Appl Polym Sci 1968, 12, 863.
27. Zitomer, F.; Diedwardo, A. H. J Macromol Sci Chem 1974, 8, 119.
28. Reents, W. D., Jr.; Kaplan, M. L. Polymer 1982, 23, 310.
29. Montaudo, G.; Puglisi, C.; Scamporrino, E.; Vitalini, D. J Anal Appl Pyrolysis 1987, 10, 283.
30. Peters, O. A.; Still, R. H. Polym Degrad Stab 1993, 42, 41.
31. Budgell, D. R.; Day, M.; Cooney, J. D. Polym Degrad Stab 1994, 43, 109.
32. Chien, J. C. W.; Uden, P. C.; Fan, J. L. J Polym Sci Polym Chem Ed 1982, 20, 2159.
33. Montaudo, G.; Puglisi, C.; Scamporrino, E.; Vitalini, D. J Polym Sci Part A: Polym Chem 1986, 24, 301.
34. Fan, J. L.; Chien, J. C. W. J Polym Sci Polym Chem Ed 1983, 21, 3453.
35. Grassie, N.; Scott, G. Polymer Degradation and Stabilisation; Cambridge University Press: Cambridge, England, 1985; Chapter 2, p 33.
36. Perrin, D. D.; Armarego, W. L. F. Purification of Laboratory Chemicals; Pergamon: New York, 1988.
37. Sundarrajan, S.; Srinivasan, K. S. V. Macromol Rapid Commun 2004, 25, 1406.
38. Marvel, C. S.; Kotch, A. J Am Chem Soc 1951, 73, 481.
39. Cis-trans isomerization has taken place in polyacetylene in this temperature range without any decomposition. The lower temperature in this study is due to the known low thermal stability of the C - S bond. See Ito, T.; Shirakawa, H.; Ikeda, S. J Polym Sci Polym Chem Ed 1975, 13, 1943.