Changes in layer organization of Na- and Ca-exchanged smectite materials during solvent exchanges for embedment in resin

Canadian Mineralogist

Volumn 36, Issue 6, 1998, Pages 1475-1483

  Elsass, Françoise ^a   Beaumont, Andrée ^a   Pernes, Miguel ^a   Jaunet, Anne Marie ^a   Tessier, Daniel ^a  

^a CEMAGREF   (France)

Author keywords

Embedment; Organization; Resin; Smectite; Solvent; X ray diffraction

Indexed keywords

CALCIUM; CATION EXCHANGE CAPACITY; CLAY MINERAL; SMECTITE; SODIUM;

EID: 13044302348     PISSN: 00084476     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (35)

1. AFNOR (1994): Qualité des sols. Recueil de normes françaises. Paris, France.
2. ANNABI-BERGAYA, F., CRUZ, M.I., GATINEAU, L. & FRIPIAT, J.J. (1979): Adsorption of alcohols by smectites. I. Distinction between internal and external surfaces. Clay Mineral. 14, 249-258.
3. _, _, _ & _ (1980): Adsorption of alcohols by smectites. II. Role of the exchangeable cations. Clay Mineral. 15, 219-223.
4. BEN RHAÏEM, H., PONS, C.H. & TESSIER, D. (1987): Factors affecting the microstructure of smectites: role of cation and history of applied stresses. Proc. Int. Clay Conf. (Denver, 1985) (L.G. Schlutz, H. van Olphen & F.A. Mumpton, eds.). Clay Minerals Society, Bloomington, Indiana (292-297).
5. _, TESSIER, D. & PONS, C.H. (1986): Comportement hydrique et évolution structurale et texturale des montmorillonites au cours d'un cycle de dessiccation - humectation. 1. Cas des montmorillonites calciques. Clay Mineral. 21, 9-29.
6. BRINDLEY, G.W., WIEWIÓRA, K. & WIEWIÓRA, A. (1969): Intercrystalline swelling of montmorillonite in some water - organic mixtures. Am. Mineral. 54, 1635-1644.
7. CARTER, D.L., HEILMAN, M.D. & GONZALEZ, C.L. (1965): Ethylene glycol monoethyl-ether for determining surface area of silicate minerals. Soil Sci. 100, 356-360.
8. CHENU, C. & TESSIER, D. (1995): Low temperature scanning electron microscopy of clay and organic constituents and their relevance to soil microstructures. Scanning Microsc. 9, 989-1010.
9. CIESIELSKI, H. & STERCKEMAN, T. (1997a): Determination of cation exchange capacity and exchangeable cations in soils by means of cobalt hexamine trichloride. Effects of experimental conditions. Agronomie 17, 1-8.
10. _ & _ (1997b): A comparison between three methods for the determination of cation exchange capacity and exchangeable cations in soils. Agronomie 17, 9-16.
11. FARMER, V.C., MCHARDY, W.J., ELSASS, F. & ROBERT, M. (1994): hk-ordering in aluminous nontronite and saponite synthesized near 90°C: effects of synthesis conditions on nontronite composition and ordering. Clays Clay Minerals 42, 180-186.
12. FOSTER, R.H. & DE, P.K. (1971): Optical and electron microscopic investigation of shear induced structures in lightly consolidated (soft) and heavily consolidated (hard) kaolinite. Clays Clay Minerals 19, 31-47.
13. GAULTIER, J.P. & MAMY, J. (1988): Etude de la fixation du potassium dans les montmorillonites bi-ioniques K-Ca. Phosphore et potassium dans les relations sol-plante. Institut National de la Recherche Agronomique, Paris, France (33-53).
14. KIM, JIN-WOOK, PEACOR, D.R., TESSIER, D. & ELSASS, F. (1995): A technique for maintaining texture and permanent expansion of smectite interlayers for TEM observations. Clays Clay Minerals 43, 51-57.
15. LAGALY, G. (1981): Characterization of clays by organic compounds. Clay Mineral. 16, 1-21.
16. _ (1982): Layer charge heterogeneity in vermiculites. Clays Clay Minerals 30, 215-222.
17. _ & WEISS, A. (1969): Determination of the layer charge in mica-type layer silicates. In Proc. Int. Clay Conf. (Tokyo) (L. Heller, ed.). Israel Univ. Press, Jerusalem, Israel (61-80).
18. MCKEE, T.R. & BROWN, J.L. (1977): Preparation of specimens for electron microscopic examination. In Minerals in Soil Environments (J.B. Dixon, S.B. Weed, J.A. Kittrick, M.H. Milford & J.L. White, eds.). Soil Science of America, Madison, Wisconsin (809-846).
19. MÉRING, J. (1946): On the hydratation of montmorillonite. Trans. Faraday Soc. 42B, 205-219.
20. MOORE, D.M. & REYNOLDS, R.C., JR. (1989): X-Ray Diffraction and the Identification and Analysis of Clay Minerals. Oxford University Press, Oxford, U.K.
21. NADEAU, P.H., WILSON, M.J., MCHARDY, W.J. & TAIT, J.M. (1984): Interstratified clays as fundamental particles. Science 225, 923-925.
22. NORRISH, K. (1954): The swelling of montmorillonite. Faraday Soc. Disc. 18, 120-134.
23. PEACOR, D.R. (1992): Analytical electron microscopy: X-ray analysis. In Minerals and Reactions at the Atomic Scale: Transmission Electron Microscopy (P.R. Buseck, ed.). Rev. Mineral. 27, 113-140.
24. PONS, C.H., BEN RHAÏEM, H., TESSIER, D. & CLINARD, C. (1987): Apport de la diffusion aux petits angles de rayons X à l'étude de la microstructure des matériaux argileux. In Micromorphologie des Sols (N. Fedoroff, L.M. Bresson & M.A. Courty, eds.). Association Française pour l'Etude du Sol, Plaisir, France (37-42).
25. _, ROUSSEAUX, F. & TCHOUBAR, D. (1981): Utilisation du rayonnement synchrotron en diffusion aux petits angles pour l'étude du gonflement des smectites. I. Etude du système eau - montmorillonite-Na en fonction de la température. Clay Mineral. 16, 23-42.
26. _, _ & _ (1982): Utilisation du rayonnement synchrotron en diffusion aux petits angles pour l'étude du gonflement des smectites. II. Etude de différents systèmes eau - smectites en fonction de la température. Clay Mineral. 17, 327-338.
27. RIGHI, D. & ELSASS, F. (1996): Characterization of soil clay minerals: decomposition of X-ray diffraction diagrams and high resolution electron microscopy. Clays Clay Minerals 44, 781-800.
28. ROBERT, M. & TESSIER, D. (1974): Méthodes de préparation des argiles des sols pour des études minéralogiques. Annales Agronomiques 25, 859-882.
29. SPURR, A.R. (1969): A low viscosity epoxy resin embedding medium for electron microscopy. J. Ultrastruct. Res. 26, 31-43.
30. TESSIER, D. (1984): Etude expérimentale de l'organisation des matériaux argileux. Thèse de doctorat d'Etat, Université de Paris VII, Institut National de la Recherche Agronomique, Paris, France.
31. _ (1987): Validité des techniques de déshydratation pour l'étude de la micro-organisation des sols; apport des matériaux argileux purs. In Micromorphologie des Sols (N. Fedoroff, L.M. Bresson & M.A. Courty, eds.). Association Française pour l'Etude du Sol, Plaisir, France (23-29).
32. _ (1991): Behaviour and microstructure of clay minerals. In Soil Colloids and their Associations in Aggregates (M.F. de Boodt, M.H.B. Hayes & A. Herbillon, eds.). Plenum Press, New York, N.Y. (387-415).
33. _, BEAUMONT, A., INIGO INIGO, A. & PERNES, M. (1997): Clay particle orientation and how it affects shrinkswell properties. Eleventh Int. Clay Conf. (Ottawa), Abstr., 74.
34. _ & PÉDRO, G. (1987): Mineralogical characterization of 2:1 clays in soils: importance of the clay texture. In Proc. Int. Clay Conf. (Denver, 1985) (L.G. Schultz, H. van Olphen & F.A. Mumpton, eds.). Clay Minerals Society, Bloomington, Indiana (78-84).
35. VALI, H. & KÖSTER, H.M. (1986): Expanding behaviour, structural disorder, regular and random irregular interstratification of 2:1 layer-silicates studied by high-resolution images of transmission electron microscopy. Clay Mineral. 21, 827-859.