Yang-Yang anomaly in fluid criticality: experiment and scaling theory

Physical Review Letters

Volumn 85, Issue 4, 2000, Pages 696-699

  Fisher, Michael E ^a   Orkoulas, G ^a  

^a UNIVERSITY OF MARYLAND   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALGORITHMS; CARBON DIOXIDE; CURVE FITTING; ESTIMATION; EXTRAPOLATION; MATHEMATICAL MODELS; PROPANE; SPECIFIC HEAT OF GASES; TEMPERATURE; THERMODYNAMICS; VAPOR PRESSURE;

FLUID CRITICALITY; SCALING THEORY;

PHASE EQUILIBRIA;

EID: 12944333198     PISSN: 00319007     EISSN: None     Source Type: Journal    
DOI: 10.1103/PhysRevLett.85.696     Document Type: Article

References (25)

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2. M. I. Bagatskii, A. V. Voronel', and V. G. Gusak, Zh. Eksp. Teor. Fiz. 43, 728 (1962) [Sov. Phys. JETP 16, 517 (1963)]; A. V. Voronel' et al., ibid. 45, 823 (1963) [Sov. Phys. JETP 18, 568 (1964)].
3. M. I. Bagatskii, A. V. Voronel', and V. G. Gusak, Zh. Eksp. Teor. Fiz. 43, 728 (1962) [Sov. Phys. JETP 16, 517 (1963)]; A. V. Voronel' et al., ibid. 45, 823 (1963) [Sov. Phys. JETP 18, 568 (1964)].
4. M. I. Bagatskii, A. V. Voronel', and V. G. Gusak, Zh. Eksp. Teor. Fiz. 43, 728 (1962) [Sov. Phys. JETP 16, 517 (1963)]; A. V. Voronel' et al., ibid. 45, 823 (1963) [Sov. Phys. JETP 18, 568 (1964)].
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8. σ(T) at criticality. But note [Y-C. Kim (private communication)] that classical theory, because of its underlying analytic character, cannot provide hints regarding the existence or magnitude of the Yang-Yang anomaly.
9. σ(T) at criticality. But note [Y-C. Kim (private communication)] that classical theory, because of its underlying analytic character, cannot provide hints regarding the existence or magnitude of the Yang-Yang anomaly.
10. I. M. Abdulagatov, L. N. Levina, Z. R. Zakaryaev, and O. N. Mamchenkova, Fluid Phase Equilib. 127, 205 (1997).
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18. See A. D. Bruce and N. B. Wilding, Phys. Rev. Lett. 68, 193 (1992); used, e.g., by G. Orkoulas and A. Z. Panagiotopoulos, J. Chem. Phys. 110, 1581 (1999).
19. See A. D. Bruce and N. B. Wilding, Phys. Rev. Lett. 68, 193 (1992); used, e.g., by G. Orkoulas and A. Z. Panagiotopoulos, J. Chem. Phys. 110, 1581 (1999).
20. μ.
21. μ appropriately in (3), etc.].
22. See a detailed analysis by G. Orkoulas, M. E. Fisher, and C. Üstün (to be published). Dr. Abdulagatov kindly approved of the discards and corrections made to his data in [5]; [7].
23. c [5], have relatively small effects.
24. G. Orkoulas, M. E. Fisher, and A. Z. Panagiotopoulos (to be published).
25. Details will be presented elsewhere.