Poly(hemiacetal ester)s: New class of polymers with thermally dissociative units in the main chain

Macromolecules

Volumn 32, Issue 26, 1999, Pages 9059-9061

  Otsuka, Hideyuki ^a   Endo, Takeshi ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; CARBOXYLIC ACIDS; CATALYSTS; DISSOCIATION; SYNTHESIS (CHEMICAL); THERMODYNAMIC PROPERTIES;

POLYHEMIACETAL ESTERS; THERMAL DISSOCIATION;

POLYESTERS;

EID: 12944309852     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9909408     Document Type: Article

References (21)

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19. No ring-opening polymerization of THP was confirmed.
20. General procedure: dicarboxylic acid (5.0 mmol) and ethylene glycol divinyl ether (5.0 mmol) in dry tetrahydrofuran (2.5 mL) were stirred at room temperature in the presence of 1 mol % of PPTS. After 24 h, the reaction mixture was treated with solid base and purified by high-pressure liquid chromatography if necessary.
21. Otsuka, H.; Fujiwara, H.; Endo, T. To be submitted for publication.