메뉴 건너뛰기




Volumn 32, Issue 26, 1999, Pages 8791-8799

Functionalized 4-(dialkylamino)-4′-nitrostilbenes as reactive fluorescent probes for monitoring the photoinitiated polymerization of MMA

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC POLYMERS; EMISSION SPECTROSCOPY; FLUORESCENCE; NITROGEN COMPOUNDS; PHOTOPOLYMERIZATION; SUBSTITUTION REACTIONS; SYNTHESIS (CHEMICAL);

EID: 12944284771     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9907688     Document Type: Article
Times cited : (33)

References (49)
  • 1
    • 0031191655 scopus 로고    scopus 로고
    • (a) For a review on fluorescent sensors and switches, see: de Silva, A. P.; Nimal Gunaratne, H. Q.; Gunnlaugsson, T.; Huxley, A. J. M.; McCoy, C. P.; Rademacher, J. T.; Rice, T. E. Chem. Rev. 1997, 97, 1515. (b) For a review on fluorescent probes for monitoring photoinitiated polymerization processes, see: Neckers, D. C.; Jager, W. F. Chemistry & Technology of UB & EB Formulations for Coatings, Inks and Paints; John Wiley and Sons: New York, 1998: Vol. 7, Chapter 3.
    • (1997) Chem. Rev. , vol.97 , pp. 1515
    • De Silva, A.P.1    Nimal Gunaratne, H.Q.2    Gunnlaugsson, T.3    Huxley, A.J.M.4    McCoy, C.P.5    Rademacher, J.T.6    Rice, T.E.7
  • 2
    • 0003505854 scopus 로고    scopus 로고
    • John Wiley and Sons: New York, Chapter 3
    • (a) For a review on fluorescent sensors and switches, see: de Silva, A. P.; Nimal Gunaratne, H. Q.; Gunnlaugsson, T.; Huxley, A. J. M.; McCoy, C. P.; Rademacher, J. T.; Rice, T. E. Chem. Rev. 1997, 97, 1515. (b) For a review on fluorescent probes for monitoring photoinitiated polymerization processes, see: Neckers, D. C.; Jager, W. F. Chemistry & Technology of UB & EB Formulations for Coatings, Inks and Paints; John Wiley and Sons: New York, 1998: Vol. 7, Chapter 3.
    • (1998) Chemistry & Technology of UB & EB Formulations for Coatings, Inks and Paints , vol.7
    • Neckers, D.C.1    Jager, W.F.2
  • 14
    • 12944302501 scopus 로고    scopus 로고
    • note
    • In our research group we have developed a fiber optics based fluorimeter that uses a CCD recorder that can take emission spectra in as little as 25 ms; see refs 2a and 2b.
  • 25
    • 12944326779 scopus 로고    scopus 로고
    • Ph.D. Thesis, University of Amsterdam
    • (c) For the use of D-σ-A probes in polymers, see: Verheij, H. J. Fluorescence Probing of Polymers. Ph.D. Thesis, University of Amsterdam, 1997.
    • (1997) Fluorescence Probing of Polymers
    • Verheij, H.J.1
  • 28
    • 12944278660 scopus 로고
    • For the use of DMANS as a solvatochromic probe in microheterogeneous media, see: Shin, D. M.; Whitten, D. G. J. Phys. Chem. 1988, 92, 2944.
    • (1988) J. Phys. Chem. , vol.92 , pp. 2944
    • Shin, D.M.1    Whitten, D.G.2
  • 29
    • 33845183682 scopus 로고
    • For the fluorescence of DMANS in various solvents, see: (a) Gruen, H.; Görner, H. J. Phys. Chem. 1989, 93, 7144. (b) Lippert, E.; Lüder, W.;Moll, F.; Nägele, W.; Boos, H.;Prigge, H.; Seibold-Blankenstein. Angew. Chem. 1961, 73, 695.
    • (1989) J. Phys. Chem. , vol.93 , pp. 7144
    • Gruen, H.1    Görner, H.2
  • 31
    • 0031551701 scopus 로고    scopus 로고
    • For the emission of reactive fluorescent probes and fluorescent reactants during thermal polymerizations, see: (a) Phelan, J. C.; Sung, C. S. P. Macromolecules 1997, 30, 6845. (b) Huang, X. Y.; Yu, W.; Sung, C. S. P. Macromolecules 1990, 23, 390. (c) Sung, C. S. P.; Mathisen, R. Polymer 1987, 28, 941.
    • (1997) Macromolecules , vol.30 , pp. 6845
    • Phelan, J.C.1    Sung, C.S.P.2
  • 32
    • 0025251395 scopus 로고
    • For the emission of reactive fluorescent probes and fluorescent reactants during thermal polymerizations, see: (a) Phelan, J. C.; Sung, C. S. P. Macromolecules 1997, 30, 6845. (b) Huang, X. Y.; Yu, W.; Sung, C. S. P. Macromolecules 1990, 23, 390. (c) Sung, C. S. P.; Mathisen, R. Polymer 1987, 28, 941.
    • (1990) Macromolecules , vol.23 , pp. 390
    • Huang, X.Y.1    Yu, W.2    Sung, C.S.P.3
  • 33
    • 0023348708 scopus 로고
    • For the emission of reactive fluorescent probes and fluorescent reactants during thermal polymerizations, see: (a) Phelan, J. C.; Sung, C. S. P. Macromolecules 1997, 30, 6845. (b) Huang, X. Y.; Yu, W.; Sung, C. S. P. Macromolecules 1990, 23, 390. (c) Sung, C. S. P.; Mathisen, R. Polymer 1987, 28, 941.
    • (1987) Polymer , vol.28 , pp. 941
    • Sung, C.S.P.1    Mathisen, R.2
  • 35
    • 12944327271 scopus 로고    scopus 로고
    • Extrusion of probe molecules may lead to enrichment of nonreactive probes in those regions that polymerize later in the process
    • Extrusion of probe molecules may lead to enrichment of nonreactive probes in those regions that polymerize later in the process.
  • 36
    • 12944304060 scopus 로고    scopus 로고
    • Polymer bound fluorescent probes such as P2 and P4 will be discussed in a subsequent paper
    • Polymer bound fluorescent probes such as P2 and P4 will be discussed in a subsequent paper.
  • 38
    • 12944303019 scopus 로고    scopus 로고
    • U.S. Patent 4,957,655, Sept 18, 1990, submitted to Hoechst Celanese
    • The synthesis of 2 is reported in: Garo, K.; Donald, R.; Alan, B.; Calundann, G. W.; East, A. J. U.S. Patent 4,957,655, Sept 18, 1990, submitted to Hoechst Celanese.
    • Garo, K.1    Donald, R.2    Alan, B.3    Calundann, G.W.4    East, A.J.5
  • 40
    • 12944312610 scopus 로고    scopus 로고
    • Absorption spectra of 1-5 were almost identical. Small blue shifts, typically 2 nm for each substituent, were observed
    • Absorption spectra of 1-5 were almost identical. Small blue shifts, typically 2 nm for each substituent, were observed.
  • 41
    • 12944280165 scopus 로고    scopus 로고
    • 2 + 2) in which ε is the dielectric constant and n is the optical refractive index of the solvent; see ref 11a
    • 2 + 2) in which ε is the dielectric constant and n is the optical refractive index of the solvent; see ref 11a.
  • 42
    • 12944327272 scopus 로고    scopus 로고
    • The occurrence of dual emission from an ICT state and a non-CT state closely resembles the photophysics described for TICT probes; see ref 8b
    • The occurrence of dual emission from an ICT state and a non-CT state closely resembles the photophysics described for TICT probes; see ref 8b.
  • 43
    • 12944319241 scopus 로고    scopus 로고
    • 5
    • 5.
  • 48
    • 12944325221 scopus 로고    scopus 로고
    • note
    • A series of polymers with chromophore contents up to 10% were obtained by copolymerization of 2 with MMA in benzene solution (experimental). A higher degree of functionalization did not decrease the molecular weight of the polymer significantly. This proves that incorporation of 2 does not terminat the polymerization and suggests an even distribution of 2 in the polymer.
  • 49
    • 12944325704 scopus 로고    scopus 로고
    • GPC chromatograms have a bimodal shape with maxima at 50 000 and 160 000, similar to those reported for thermal polymerizations of MMA; see ref 26a
    • GPC chromatograms have a bimodal shape with maxima at 50 000 and 160 000, similar to those reported for thermal polymerizations of MMA; see ref 26a.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.