Equilibria and catalytic properties of a chloro-bridged diimine copper(II) complex in the N,N,N′,N′-tetramethyl-p-phenylenediamine (TMPD) oxidation

Journal of the Brazilian Chemical Society

Volumn 15, Issue 6, 2004, Pages 872-883

  Alves, Wendel A ^a   De Almeida Filho, Saulo A ^a   De Almeida Santos, Regina H ^a   Paduan Filho, Armando ^a   Da Costa Ferreira, Ana M ^a  

^a UNIVERSITY OF SÃO PAULO   (Brazil)

Author keywords

Catalytic activity; Copper(II) complexes; Dinuclear species; Equilibria; Kinetics

Indexed keywords

CHLORIDE; CHLORIDE ION; CHLOROFORM; COPPER COMPLEX; IMINE; INORGANIC SALT; N,N,N',N' TETRAMETHYL 4 PHENYLENEDIAMINE; NITRATE; PERCHLORATE; PHENYLENEDIAMINE DERIVATIVE; SOLVENT; UNCLASSIFIED DRUG; WATER;

AQUEOUS SOLUTION; ARTICLE; CATALYSIS; CATALYST; COMPARATIVE STUDY; COMPLEX FORMATION; CONCENTRATION PROCESS; CORRELATION ANALYSIS; ELECTRON SPIN RESONANCE; EQUILIBRIUM CONSTANT; INFRARED SPECTROSCOPY; KINETICS; MOLECULAR STABILITY; OXIDATION; REACTION ANALYSIS; SOLVENT EFFECT; ULTRAVIOLET SPECTROSCOPY; X RAY CRYSTALLOGRAPHY;

EID: 12844276012     PISSN: 01035053     EISSN: None     Source Type: Journal    
DOI: 10.1590/S0103-50532004000600014     Document Type: Article

References (61)

1. See, for instance: Kitajima, N.; Moro-oka, Y.; Chem. Rev. 1994, 94, 737; Tolman, W.B.; Acc. Chem. Res. 1997, 30, 227.
2. See, for instance: Kitajima, N.; Moro-oka, Y.; Chem. Rev. 1994, 94, 737; Tolman, W.B.; Acc. Chem. Res. 1997, 30, 227.
3. Ziessel, R.; Coord. Chem. Rev. 2001, 216-217, 195; Armaroli, N.; Chem. Soc. Rev. 2001, 30, 113.
4. Ziessel, R.; Coord. Chem. Rev. 2001, 216-217, 195; Armaroli, N.; Chem. Soc. Rev. 2001, 30, 113.
5. Sánchez-Ferrer, A.; Rodríguez-López, J.N.; García-Cánovas, F.; García-Carmona, F.; Biochim. Biophys. Acta 1995, 247, 1.
6. Duine, J.A.; Jongejan, J.A. In Bioinorganic Catalysis; Reedjik, J., ed., Marcel Dekker: New York, 1993, Chap. 14, p. 447.
7. Solomon, E.I.; Randall, D.W.; Glaser, T.; Coord. Chem. Rev. 2000, 200-202, 595.
8. Fox, S.; Karlin, K.D. In Active Oxygen in Biochemistry, Valentine, J.S.; Foote, C.S.; Greenberg, A.; Liebman, J.F., eds., Blackie Academic and Professional: London, 1995, chap. 4, p. 188.
9. Batra, G.; Mathur, P.; Inorg. Chem. 1992, 31, 1575; Sundberg, R.J.; Martin, R.B.; Chem. Rev. 1974, 74, 471.
10. Batra, G.; Mathur, P.; Inorg. Chem. 1992, 31, 1575; Sundberg, R.J.; Martin, R.B.; Chem. Rev. 1974, 74, 471.
11. Nishida Y.; Takahashi, K.; J. Chem. Soc., Dalton Trans. 1988, 691.
12. Pandiyan, T.; Palaniandavar, M.; Lakshminarayanan, M.; Manohar, H.; J. Chem. Soc., Dalton Trans. 1992, 3377.
13. Alves, W.A.; Bagatin, I.A.; Ferreira, A.M.D.C.; Inorg. Chim. Acta 2001, 321, 11.
14. Alves, W.A.; de Almeida-Filho, S.A.; de Almeida, M.V.; Paduan-Filho, A.; Becerra, C.C.; Ferreira, A.M.D.C.; J. Mol. Catal. A:Chemical 2003, 198, 63.
15. North, A.C.T.; Phillips, D.C.; Mathews, F.S.; Acta Crystr. 1968, A24, 359.
16. Farrugia, L.J.; J. Appl. Cryst. 1999, 32, 837.
17. Altomare, A.; Cascarano, G.; Giacovazzo, C.; Guagliardi, A.; J. Appl. Crystallogr. 1993, 26, 343.
18. Sheldrick, G.M.; SHELX97 - Programs for Crystal Structure Analysis (Release 97-2), 1998. Institut für Anorganische Chemie der Universität, Tammanstrasse 4, D-3400 Göttingen, Germany.
19. Spek, A.L.; Acta Cryst. 1990, Sect A, 46, C34.
20. Carlin, R.L.; Magnetochemistry, Springer: Berlin, 1986.
21. Geary, W.J.; Coord. Chem. Rev., 1971, 7, 81.
22. Lapinte, C.; Meyer, G.; Nadjo, L.; Riviere, H.; Nouv, J. Chim. 1984, 8, 165.
23. Alves, W.A.; de Almeida-Filho, S.A.; de Almeida Santos, R.H.; Ferreira, A.M.D.C.; Inorg. Chem. Comm. 2003, 6, 294.
24. Addison, A.W.; Rao, T.N.; Reedijk, J.; Rijn, J.V.; Verschoor, G.C.; J. Chem. Soc., Dalton Trans. 1984, 1349.
25. Tamboura, F.B.; Gaye, M.; Sall, A.S.; Barry, A.H.; Jouini, T.; Inorg. Chem. Comm. 2002, 5, 235.
26. Bastida, R.; de Blas, A.; Castro, R; Fenton, D.E.; Macias, A.; Rial, R.; Rodriguez, A.; Rodriguez-Blas, T.; J. Chem. Soc., Dalton Trans. 1996, 1493.
27. Lever, A.B.P.; Montovani, E.; Can. J. Chem. 1971, 49, 1957.
28. Pons, J.; Chadghan, A.; Casabó, J.; Avarez-Larena, A.; Piniella, J.F.; Ros, J.; Polyhedron 2001, 20, 2531.
29. Matthews, C.J.; Avery, K.; Xu, Z.; Thompson, L.K.; Zhao, L.; Miller, D.O.; Biradha, K.; Poirier, K.; Zaworotko, M.J.; Wilson, C.; Goeta, A.E.; Howard, J.A.K.; Inorg. Chem. 1999, 38, 5266.
30. Miyasaka, H.; Okamura, S.; Nakashima, T.; Matsumoto, N.; Inorg. Chem. 1997, 36, 4329.
31. Sant'Ana, A.C.; Alves, W.A.; Santos, R.H.A.; Ferreira, A.M.D.C.; Temperini, M.L.A.; Polyhedron 2003, 22, 1673.
32. Hathaway, B.J.; Tomlinson, A.A.G.; Coord. Chem. Rev. 1970, 5, 1; Hathaway, B.J.; J. Chem. Soc., Dalton Trans. 1972, 1196.
33. Hathaway, B.J.; Tomlinson, A.A.G.; Coord. Chem. Rev. 1970, 5, 1; Hathaway, B.J.; J. Chem. Soc., Dalton Trans. 1972, 1196.
34. Chaudhuri, P.; Oder, K.; J. Chem. Soc., Dalton Trans. 1990, 1597.
35. Monzani, E.; Casella, L.; Zoppellaro, G.; Gullotti, M.; Pagliarin, R.; Bonomo, R.P.; Tabbi, G.; Nardin, G.; Randaccio, L.; Inorg. Chim. Acta 1998, 282, 180; Monzani, E.; Quinti, L.; Perotti, A.; Casella, L.; Gullotti, M.; Randaccio, L.; Geremia, S.; Nardin, G.; Faleschini, P.; Tabbì, G.; Inorg. Chem., 1998, 37, 553.
36. Monzani, E.; Casella, L.; Zoppellaro, G.; Gullotti, M.; Pagliarin, R.; Bonomo, R.P.; Tabbi, G.; Nardin, G.; Randaccio, L.; Inorg. Chim. Acta 1998, 282, 180; Monzani, E.; Quinti, L.; Perotti, A.; Casella, L.; Gullotti, M.; Randaccio, L.; Geremia, S.; Nardin, G.; Faleschini, P.; Tabbì, G.; Inorg. Chem., 1998, 37, 553.
37. Smith, T.D.; Pilbrow, J.R.; Coord. Chem. Rev., 1974, 13; 173;
38. Calzado, C.J., Cabrero, J.; Malrieu, J.P.; Caballol, R.; J. Chem. Phys. 2002, 116, 985.
39. Sakaguchi, U.; Addison, A.W.; J. Chem, Soc., Dalton Trans. 1979, 600.
40. Santos, M.L.P.; Faljoni-Alario, A.; Mangrich, A.S.; Ferreira, A.M.D.C.; J. Inorg. Biochem. 1998, 71, 71; Müller, J.; Schübl, D.; Maichle-Mössmer, C.; Strähle, J.; Weser, U.; J. Inorg. Biochem. 1999, 75, 63.
41. Santos, M.L.P.; Faljoni-Alario, A.; Mangrich, A.S.; Ferreira, A.M.D.C.; J. Inorg. Biochem. 1998, 71, 71; Müller, J.; Schübl, D.; Maichle-Mössmer, C.; Strähle, J.; Weser, U.; J. Inorg. Biochem. 1999, 75, 63.
42. Bleaney, B.; Bowers, K.D.; Proc. R. Soc., London 1952, Ser. A 214, 4519.
43. Marsh, W.E.; Patel, K.C.; Hatfield, W.E.; Hodgson, D.J.; Inorg. Chem. 1983, 22, 511; Hatfield, W.E.; Weller, R.R.; Hall, J.W.; Inorg. Chem. 1980, 19, 3825.
44. Marsh, W.E.; Patel, K.C.; Hatfield, W.E.; Hodgson, D.J.; Inorg. Chem. 1983, 22, 511; Hatfield, W.E.; Weller, R.R.; Hall, J.W.; Inorg. Chem. 1980, 19, 3825.
45. Rodríguez, M.; Llobet, A.; Corbella, M.; Martell, A.E.; Reibenspies, J.; Inorg. Chem. 1999, 38, 2328; Rodríguez-Fortea, A.; Alemany, P.; Alvarez, S.; Ruiz, E.; Inorg. Chem. 2002, 41, 3769; Saha M.K.; Dey, D.K.; Samanta, B.; Edwards, A.J.; Clegg, W.; Mitra, S.; J. Chem. Soc., Dalton Trans. 2003, 488.
46. Rodríguez, M.; Llobet, A.; Corbella, M.; Martell, A.E.; Reibenspies, J.; Inorg. Chem. 1999, 38, 2328; Rodríguez-Fortea, A.; Alemany, P.; Alvarez, S.; Ruiz, E.; Inorg. Chem. 2002, 41, 3769; Saha M.K.; Dey, D.K.; Samanta, B.; Edwards, A.J.; Clegg, W.; Mitra, S.; J. Chem. Soc., Dalton Trans. 2003, 488.
47. Rodríguez, M.; Llobet, A.; Corbella, M.; Martell, A.E.; Reibenspies, J.; Inorg. Chem. 1999, 38, 2328; Rodríguez-Fortea, A.; Alemany, P.; Alvarez, S.; Ruiz, E.; Inorg. Chem. 2002, 41, 3769; Saha M.K.; Dey, D.K.; Samanta, B.; Edwards, A.J.; Clegg, W.; Mitra, S.; J. Chem. Soc., Dalton Trans. 2003, 488.
48. Lucas, C.R.; Liu, S.; Thompson, L.K.; Inorg. Chem. 1990, 29, 85; Schuitema, A.M.; Stassen, A.F.; Driessen, W.L.; Reedijk, J.; Inorg. Chim. Acta 2002, 337, 48 ; Keij, F.S.; Haasnoot, J.G.; Oosterling, A.J.; Reedijk, J.; O'Connor, C.J.; Zhang, J.H.; Spek, A.L.; Inorg. Chim. Acta 1991, 181, 185; Hoog, P.; Gamez, P.; Lüken, M.; Roubeau, O.; Krebs, B.; Reedijk, J.; Inorg. Chim. Acta 2004, 357, 213.
49. Lucas, C.R.; Liu, S.; Thompson, L.K.; Inorg. Chem. 1990, 29, 85; Schuitema, A.M.; Stassen, A.F.; Driessen, W.L.; Reedijk, J.; Inorg. Chim. Acta 2002, 337, 48 ; Keij, F.S.; Haasnoot, J.G.; Oosterling, A.J.; Reedijk, J.; O'Connor, C.J.; Zhang, J.H.; Spek, A.L.; Inorg. Chim. Acta 1991, 181, 185; Hoog, P.; Gamez, P.; Lüken, M.; Roubeau, O.; Krebs, B.; Reedijk, J.; Inorg. Chim. Acta 2004, 357, 213.
50. Lucas, C.R.; Liu, S.; Thompson, L.K.; Inorg. Chem. 1990, 29, 85; Schuitema, A.M.; Stassen, A.F.; Driessen, W.L.; Reedijk, J.; Inorg. Chim. Acta 2002, 337, 48 ; Keij, F.S.; Haasnoot, J.G.; Oosterling, A.J.; Reedijk, J.; O'Connor, C.J.; Zhang, J.H.; Spek, A.L.; Inorg. Chim. Acta 1991, 181, 185; Hoog, P.; Gamez, P.; Lüken, M.; Roubeau, O.; Krebs, B.; Reedijk, J.; Inorg. Chim. Acta 2004, 357, 213.
51. Lucas, C.R.; Liu, S.; Thompson, L.K.; Inorg. Chem. 1990, 29, 85; Schuitema, A.M.; Stassen, A.F.; Driessen, W.L.; Reedijk, J.; Inorg. Chim. Acta 2002, 337, 48 ; Keij, F.S.; Haasnoot, J.G.; Oosterling, A.J.; Reedijk, J.; O'Connor, C.J.; Zhang, J.H.; Spek, A.L.; Inorg. Chim. Acta 1991, 181, 185; Hoog, P.; Gamez, P.; Lüken, M.; Roubeau, O.; Krebs, B.; Reedijk, J.; Inorg. Chim. Acta 2004, 357, 213.
52. Abuhijleh, A.L.; Polyhedron 1996, 15, 285.
53. Nishida, Y.; Takeuchi, M.; Oishi, N.; Kida, S.; Inorg. Chim. Acta 1985, 96, 81; Nishida, Y.; Shimo, H.; Maehara, H.; Kida, S.; J. Chem. Soc., Dalton Trans. 1985, 1945.
54. Nishida, Y.; Takeuchi, M.; Oishi, N.; Kida, S.; Inorg. Chim. Acta 1985, 96, 81; Nishida, Y.; Shimo, H.; Maehara, H.; Kida, S.; J. Chem. Soc., Dalton Trans. 1985, 1945.
55. Nishida, Y.; Takeuchi, M.; Oishi, N.; Kida, S.; Inorg. Chim. Acta 1983, 75, 169.
56. Karlin, K.D.; Gultneh, Y.; Prog. Inorg. Chem. 1987, 35, 219.
57. Harrison, J.E.; Schultz, J.; J. Biol. Chem. 1976, 257, 1371; Foote, C.S.; Goyne, T.E.; Lehrer, R.I.; Nature 1983, 301, 715.
58. Harrison, J.E.; Schultz, J.; J. Biol. Chem. 1976, 257, 1371; Foote, C.S.; Goyne, T.E.; Lehrer, R.I.; Nature 1983, 301, 715.
59. Northrop, D.B.; J. Chem. Educ. 1998, 75, 1153.
60. Michaelis, L.; Schubert, M.P.; Granick, S.; J. Am. Chem. Soc. 1939, 61, 1981.
61. Lü, J.-M.; Wen, X.-L.; Wu, L.-M.; Liu, Y-C.; Liu, Z.-L.; J. Phys. Chem. 2001, A 105, 6971.