Non-Arrhenius behavior for oxidative degradation of chlorosulfonated polyethylene materials

Polymer Degradation and Stability

Volumn 87, Issue 2, 2005, Pages 335-346

  Gillen, Kenneth T ^a   Bernstein, Robert ^a   Celina, Mathew ^a  

^a SANDIA NATIONAL LABORATORIES   (United States)

Author keywords

Aging; Arrhenius extrapolation; Chlorosulfonated polyethylene rubber; Lifetime prediction; Oxygen consumption

Indexed keywords

DEGRADATION; EXTRAPOLATION; OXIDATION; PROCESS CONTROL; RUBBER;

GAS CONSTANTS; LIFETIME PREDICTION; OXYGEN CONSUMPTION;

POLYETHYLENES;

EID: 12744262662     PISSN: 01413910     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymdegradstab.2004.09.004     Document Type: Article

References (24)

1. Gugumus F. The use of accelerated tests in the evaluation of antioxidants and light stabilizers. In: Scott G, editor. Developments in polymer stabilization-8. London: Elsevier Applied Science; 1987 [chapter 6].
2. Richters P. Initiation process in the oxidation of polypropylene. Macromolecules 1970;3:262.
3. Howard JB, Gilroy HM. Some observations on the long-term behavior of stabilized polyethylene. Polym Eng Sci 1975; 15:268.
4. Chan MG, Gilroy HM, Martin WM. Long-term aging properties of polyolefins. Proceedings of polyolefins IV, Society of Plastics Engineers Regular Technical Conference, Houston, Texas; 1984. p. 167.
5. Bernstein BS, Lee PN. Proceedings of 24th international wire and cable symposium; November 1975. p. 202.
6. Gijsman P, Hennekens J, Vincent J. The influence of temperature and catalyst residues on the degradation of unstabilized polypropylene. Polym Degrad Stab 1993;39:271.
7. Rosik L, Kovarova J, Pospisil J. Lifetime prediction of ABS polymers based on thermoanalytical data. J Thermal Anal 1996; 46:465.
8. Gugumus F. Effect of temperature on the lifetime of stabilized and unstabilized PP films. Polym Degrad Stab 1999;63:41.
9. Gillen KT, Celina M, Keenan MR. Methods for predicting more confident lifetimes of seals in air environments. Rubber Chem Technol 2000;73:265.
10. Wise J, Gillen KT, Clough RL. An ultrasensitive technique for testing the Arrhenius extrapolation assumption for thermallyaged elastomers. Polym Degrad Stab 1995;49:403.
11. Gillen KT, Celina M, Clough RL, Wise J. Extrapolation of accelerated aging data - Arrhenius or erroneous? Trends Polym Sci 1997;5:250.
12. Gillen KT, Celina M. The wear-out approach for predicting the remaining lifetime of materials. Polym Degrad Stab 2001;71:15.
13. Gillen KT, Celina M, Bernstein R. Validation of improved methods for predicting long-term clastomeric seal lifetimes from compression stress-relaxation and oxygen consumption techniques. Polym Degrad Stab 2003;82:25.
14. Celina M, Wise J, Ottesen DK, Gillen KT, Clough RL. Oxidation profiles of thermally aged neoprene. Polym Degrad Stab 2000;68: 171.
15. Celina M, Gillen KT, Graham AC, Assink RA, Minier LM. Thermal degradation studies of a polyurethane propellant binder. Rubber Chem Technol 2000;73:678.
16. Gillen KT, Bernstein R, Derzon DK. Evidence of non-Arrhenius behavior from laboratory aging and 24-year field aging of polychloroprene rubber materials. Polym Degrad Stab 2005; 87(1):57-67.
17. Baseden GA. In: Morton M, editor. Rubber technology. New York: Van Nostrand Reinhold Co.; 1987. p. 360.
18. Gillen KT, Clough RL, Quintana CA. Modulus profiling of polymers. Polym Degrad Stab 1987;17:31.
19. Celina M, Gillen KT, Clough RL. Inverse temperature and annealing phenomena during degradation of crosslinked polyolefins. Polym Degrad Stab 1998;61:231.
20. Nelson CF, Gauthier G, Carlin F, Attal M, Gaussens G, Le Tutour P, et al. Long-term radiation aging and loss-of-coolant accident (LOCA) testing of electrical cables, Sandia National Laboratories report SAND94-0485; October, 1996.
21. Celina M, Wise J, Ottesen DK, Gillen KT, Clough RL. Oxidation of thermally aged nitrile rubber. Polym Degrad Stab 1998;60:493.
22. Brydson JA. Rubbery materials and their compounds. London: Elsevier Applied Science; 1988 [chapter 14].
23. Verbank JJ. Stabilisation of specialty rubbers. In: Scott G, editor. Developments in polymer stabilization-4. London: Applied Science Publishers Ltd.; 1981. p. 262f.
24. Pauly S. Permeability and diffusion data. In: Brandrup J, Immergut EH, Grulke EA, editors. Polymer handbook. 4th ed. New York: John Wiley and Sons; 1999. p. VI/543.