Systematic design of chemical oscillators using complexation and precipitation equilibria

Nature

Volumn 433, Issue 7022, 2005, Pages 139-142

  Kurin Csörgel, Krisztina ^a   Epstein, Irving R ^b   Orbán, Miklós ^a  

^a EÖTVÖS LORÁND UNIVERSITY   (Hungary)

^b BRANDEIS UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CALCIUM; CHEMICAL REACTORS; COMPLEXATION; HALOGEN COMPOUNDS; OXIDATION; POSITIVE IONS; PRECIPITATION (CHEMICAL);

CHEMICAL OSCILLATORS; CHEMICAL SPECIES; LIVING SYSTEMS; OXYHALOGEN CHEMISTRY;

LIVING SYSTEMS STUDIES;

TRANSITION ELEMENT;

CHEMICAL REACTION;

ALGORITHM; ARTICLE; CHEMICAL ANALYSIS; CHEMICAL REACTION; COMPLEX FORMATION; FLOW RATE; OSCILLATION; OXIDATION; PRECIPITATION; PRIORITY JOURNAL; PROTON TRANSPORT; REACTION ANALYSIS; REACTOR;

EID: 12744255180     PISSN: 00280836     EISSN: None     Source Type: Journal    
DOI: 10.1038/nature03214     Document Type: Article

References (13)

1. Bray, W. C. A periodic reaction in homogeneous solution and its relation to catalysis. J. Am. Chem. Soc. 43, 1262-1267 (1921).
2. Belousov, B. P. A periodic reaction and its mechanism. In Sbornik Referatov po Radiatsionni Meditsine 145 (Medgiz, Moscow, 1958).
3. Zhabotinsky, A. M. Periodic kinetics of oxidation of malonic acid in solution. Biofizika 9, 306-311 (1964).
4. Epstein, I. R., Kustin, K., De Kepper, P. & Orbán, M. Oscillating chemical reactions. Sci. Am. 248, 112-123(1983).
5. De Kepper, P., Kustin, K. & Epstein, I. R. A systematically designed homogeneous oscillating reaction: the arsenite-iodate-chlorite system. J. Am. Chem. Soc. 103, 2133-2134 (1981).
6. Sagués, F. & Epstein, I. R. Nonlinear chemical dynamics. Dalton Trans., 1201-1217 (2003).
7. Orbán, M., De Kepper, P. & Epstein, I. R. Minimal bromate oscillator: Bromate-bromide-catalyst. J. Am. Chem. Soc. 104, 2657-2658 (1982).
8. Richter, P. H. & Ross, J. Concentration oscillations and efficiency: Glycolysis. Science 211, 715-717 (1981).
9. Harris, D. C. Quantitative Chemical Analysis 5th edn 312-313 (Freeman, New York, 1999).
10. Edblom, E. C., Luo, Y., Orbán, M., Kustin, K. & Epstein, I. R. Kinetics and mechanism of the oscillatory bromate-sulfite-ferrocyanide reaction. J. Phys. Chem. 93, 2722-2727 (1989).
11. Rábai, G., Orbán, M. & Epstein, I. R. Design of pH-regulated oscillators. Acc. Chem. Res. 23, 258-263 (1990).
12. Berridge, M. J. Calcium oscillators. J. Biol. Chem. 265, 9583-9586 (1990).
13. Szucs, A. et al. Interacting biological and electronic neurons generate realistic oscillatory rhythms. Neuroreport 11, 563-569 (2000).