Hydrogen atom vs electron transfer in catecholase-mimetic oxidations by superoxometal complexes. Deuterium kinetic isotope effects

Dalton Transactions

Volumn , Issue 2, 2005, Pages 365-368

  Simándi, Tatiana M ^a   May, Zoltán ^a   Szigyártó, Imola Cs ^a   Simándi, László I ^a  

^a CHEMICAL RESEARCH CENTER   (Hungary)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; CATALYSIS; DEHYDROGENATION; DEUTERIUM; ELECTRON TRANSITIONS; ENZYMES; HYDROGEN; OXIDATION; PLANTS (BOTANY); REACTION KINETICS; SPECTROPHOTOMETERS; TRANSITION METAL COMPOUNDS;

DEUTERIUM KINETIC ISOTOPE EFFECTS; ELECTRON TRANSFER; METALLOENZYMES; SOLVOLYTIC LOSS; SUPEROXOMETAL COMPLEXES;

ORGANOMETALLICS;

2 AMINOPHENOL; 2 AMINOPHENOL OXIDASE; 2-AMINOPHENOL; 2-AMINOPHENOL OXIDASE; AMINOPHENOL DERIVATIVE; CATECHOL DERIVATIVE; CATECHOL OXIDASE; DEUTERIUM; HYDROGEN; OXIDOREDUCTASE; OXYGEN; RADIOISOTOPE; SUPEROXIDE;

ARTICLE; BIOMIMETICS; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; ELECTRON TRANSPORT; HYDROGEN BOND; KINETICS; OXIDATION REDUCTION REACTION;

AMINOPHENOLS; BIOMIMETICS; CATALYSIS; CATECHOL OXIDASE; CATECHOLS; DEUTERIUM; ELECTRON TRANSPORT; HYDROGEN; HYDROGEN BONDING; KINETICS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; OXIDOREDUCTASES; OXYGEN; RADIOISOTOPES; SUPEROXIDES;

EID: 12444329801     PISSN: 14779226     EISSN: None     Source Type: Journal    
DOI: 10.1039/b412500b     Document Type: Article

References (27)

1. (a) E. I. Solomon, U. M. Sundaram and T. E. Machonkin, Chem. Rev:, 1996, 96, 2563;
2. (b) R. Than, A. A. Feldmann and R Krebs, Coord. Chem. Rev., 1999, 182, 211;
3. (c) C. Gerdemann, Ch. Eicken and B. Krebs, Acc. Chem. Res., 2002, 183;
4. (d) C. X. Zhang, H.-C. Liang, K. J. Humphreys, K. D. Karlin, in Advances in Catalytic Activation of Dioxygen by Metal Complexes, ed. L. I. Simándi, Kluwer Academic Publishers, Dordrecht-Boston-London, 2003, pp. 79-121.
5. (a) P. Gentschev, N. Möller and B. Krebs, Inorg. Chim. Acta, 2000, 300, 442;
6. (b) R. Wegner, M. Gottschaldt, H. Görls, E.-G. Jäger and D. Klemm. Chem. Eur. J., 2001, 7, 2143;
7. (c) C. Fernandes, A. Neves, A. J. Bortoluzzi, A. S. Mangrich, E. Rentschier, B. Spoganicz and E. Schwingel, Inorg. Chim. Acta, 2001, 320, 12;
8. (d) S. Torelli, C. Belle, S. Hamman, J. L. Pierre and E. Saint-Aman, Inorg. Chem., 2002, 41, 3983;
9. (e) J. Ackermann, F. Meyer, E. Kaifer and H. Pritzkow, Chem. Eur. J., 2002, 8, 247;
10. (f) L. M. Neves Rossi, A. J. Bortoluzzi, B. Spoganicz, C. Wiezbicki, E. Schwingel, W. Haase and S. Ostrovsky, Inorg. Chem., 2002, 41, 1788;
11. (g) E. Monzani, L. Quinti, A. Perotti, L. Casella, M. Gullotti, L. Randaccio, S. Geremia, G. Nardin, P. Faleschini and G. Tabbi, Inorg. Chem., 1998, 37, 553;
12. (h) J. Pap, J. Kaizer and G. Speier, J. Inorg. Biochem., 2001, 86, 371.
13. (a) L. I. Simándi and T. L. Simándi, J. Chem. Soc. Dalton Trans., 1999, 4529;
14. (b) Z. May, G. Besenyei, L. I. Simándi, D. Asari and T. Funabiki, J. Inorg. Biochem., 2001, 86, 332;
15. (c) L. I. Simándi, T. M. Simándi, Z. May and G. Besenyei, Coord. Chem. Rev., 2003, 245, 87;
16. (d) L. I. Simándi, T. M. Barna, Gy. Argay and T. L. Simándi, Inorg. Chem., 1995, 34, 6337;
17. (e) L. I. Simándi and T. L. Simándi, J. Chem. Soc., Dalton Trans., 1998, 3275;
18. (f) L. I. Simándi, in Advances in Catalytic Activation of Dioxygen by Metal Complexes, ed. L. I. Simándi, Kluwer Academic Publishers, Dordrecht, Boston, London, 2003, pp. 265-328.
19. (a) L. I. Simándi, T. M. Barna, L. Korecz and A. Rockenbauer, Tetrahedron Lett., 1993, 34, 717;
20. (b) L. I. Simándi, T. M. Barna and S. Németh, J. Chem. Soc., Dalton Trans., 1996, 473;
21. (c) T. M. Simándi, L. I. Simándi, M. Györ, A. Rockenbauer and Á. Gömöry, Dalton Trans., 2004, 1056.
22. P. Chaudhuri, M. Hess, U. Florke and K. Wieghardt, Angew. Chem., Int. Ed. Engl., 1998, 37, 2217.
23. (a) L. Melander, Isotope Effects on Reaction Rates, The Ronald Press Co., New York, 1960, ch. 2;
24. (A) F. Ruff, I. G. Csizmadia, Study of Organic Reaction Mechanisms, Application of Kinetic Methods (in Hungarian), Nemzeti Tankönyvkiadó, Budapest, ch. 8.
25. K. Nakamoto and P. J. McCarthy, Spectroscopy and Structure of Metal Chelate Compounds, Wiley, New York, London, Sydney, 1968, p. 253.
26. The Aldrich Library of FT-IR Spectra, ed. C. J. Pouchert, edn. 1, The Aldrich Chemical Company, Inc., Milwaukee, WI, USA, 1985, vols. 1 and 2.
27. R. A. More O'Ferrall, J. Chem. Soc. B, 1970, 785.