Molybdenum(VI) cis-dioxo complexes with chiral schiff base ligands: Synthesis, characterization, and catalytic applications

Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

Volumn 59, Issue 11-12, 2004, Pages 1223-1228

  Zhou, Xiangge ^a   Zhao, Jin ^a   Santos, Ana M ^a   Kühn, Fritz E ^a  

^a TECHNICAL UNIVERSITY OF MUNICH   (Germany)

Author keywords

Catalysis; Chirality; Epoxidation; Molybdenum; Salen

Indexed keywords

CATALYSIS; CATALYSTS; CHELATION; CHIRALITY; EPOXIDATION; LIGANDS; MOLYBDENUM; MOLYBDENUM OXIDE;

ASYMMETRIC EPOXIDATION; CATALYTIC APPLICATIONS; CHIRAL SCHIFF-BASE; ENANTIOMERIC EXCESS; OLEFIN EPOXIDATION; SALEN; SALEN DERIVATIVES; TERT-BUTYLHYDROPEROXIDE; AS-LIGANDS; OPTICALLY ACTIVE; SCHIFF-BASE LIGANDS; SYNTHESISED; ]+ CATALYST;

SYNTHESIS (CHEMICAL);

LIGAND; MOLYBDENUM COMPLEX; SCHIFF BASE;

ANALYTIC METHOD; ARTICLE; CATALYSIS; CATALYST; CHEMICAL PROCEDURES; CHEMICAL REACTION; CHIRALITY; COMPLEX FORMATION; ENANTIOMER; EPOXIDATION; INFRARED SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STRUCTURE ANALYSIS; SYNTHESIS; TEMPERATURE DEPENDENCE;

EID: 12444320299     PISSN: 09320776     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (35)

1. a) W. J. Mijs, C. R. H. I. De Jonge, Organic Synthesis by Oxidation with Metal Compounds, Plenum, New York, (1996);
2. b) C. C. Reddy, G. A. Hamilton, K. M. Madyashta, Biological Oxidation System, Academic Press, San Diego, CA, (1990).
3. a) E. N. Jacobsen, W. Zhang, M. L. Güler, J. Am. Chem. Soc. 113, 6703 (1991);
4. b) E. N. Jacobsen, W. Zhang, A. R. Muci, J. R. Ecker, L. Deng, J. Am. Chem. Soc. 113, 7063 (1991);
5. c) W. Zhang, E. N. Jacobsen, J. Org. Chem. 56, 2296 (1991);
6. d) M. Palucki, G. J. McCormick, E. N. Jacobsen, Tetrahedron Lett. 36, 5457 (1995);
7. e) T. Mukaiyama, T. Yamada, T. Nagata, K. Imagawa, Chem. Lett. 327 (1993);
8. f) W. Adam, J. Jeko, A. Levai, C. Nemes, T. Patonay, P. Sebok, Tetrahedron Lett. 36, 3666 (1995);
9. g) P. Pietikäinen, Tetrahedron Lett. 40, 1001 (1999).
10. a) R. A. Sheldon, J. Mol. Catal. 7, 107 (1980);
11. b) W. R. Thiel, T. Priermeier, Angew. Chem. Int. Ed. Engl. 34, 1737 (1995);
12. c) W. R. Thiel, J. Mol. Catal. 117, 449 (1997);
13. d) F. E. Kühn, A. D. Lopes, A. M. Santos, E. Herdtweck, J. J. Haider, C. C. Romão, A. G. Santos, J. Mol. Catal. A: Chem. 151, 147 (2000);
14. e) M. Abrantes, A. A. Valente, M. Pillinger, I. S. Gonçalves, J. Rocha, C. C. Romão, Inorg. Chem. Commun. 5, 1069 (2002);
15. f) M. Abrantes, A. A. Valente, M. Pillinger, I. S. Gonçalves, J. Rocha, C. C. Romão, J. Catal. 209, 237 (2002);
16. g) C. D. Nunes, A. A. Valente, M. Pillinger, A. C. Fernandes, C. C. Romão, J. Rocha, I. S. Gonçalves, J. Mater. Chem. 12, 1735 (2002);
17. h) M. J. Jia, W. R. Thiel, Chem. Commun. 2392 (2002).
18. a) W. A. Herrmann, J. J. Haider, J. Fridgen, G. M. Lobmaier, M. Spiegler, J. Organomet. Chem. 603, 69 (2000);
19. b) S. Bellemin-Caponnaz, K. S. Coleman, J. A. Osborn, Polyhedron 18, 273 (1999);
20. c) R. J. Cross, P. D. Newman, R. D. Peacock, D. Stirling, J. Mol. Catal. A: Chem. 144, 273 (1999).
21. a) F. E. Kühn, A. M. Santos, A. D. Lopes, I. S. Gonçalves, J. E. Rodriguez-Borges, M. Pillinger, C. C. Romão, J. Organomet. Chem. 621, 207 (2001);
22. b) A. A. Valente, I. S. Gonçalves, A. D. Lopes, J. E. Rodriguez-Borges, M. Pillinger, C. C. Romão, J. Rocha, X. García-Mera, New. J. Chem. 25, 959 (2001);
23. c) I. S. Gonçalves, A. M. Santos, C. C. Romão, A. D. Lopes, J. E. Rodriguez-Borges, M. Pillinger, P. Ferreira, J. Rocha, F. E. Kühn, J. Organomet. Chem. 626, 1 (2001).
24. J. Zhao, X-G. Zhou, A. M. Santos, E. Herdtweck, C. C. Romão, F. E. Kühn, Dalton Trans. 3736 (2003).
25. T. Katsuki, J. Mol. Catal. A: Chem. 113, 87 (1996).
26. a) E. N. Jacobsen, in I. Ojima (ed.): Catalytic Asymmetric Synthesis, pp. 159-202, VCH, Weinheim (1993);
27. b) T. Katsuki, Coord. Chem. Rev. 140, 189 (1995);
28. c) T. Katsuki, in I. Ojima (ed.): Catalytic Asymmetric Synthesis, 2nd ed., pp. 287-326, Wiley, New York (2000).
29. E. M. McGarrigle, D. M. Murphy, D. G. Gilheany, Tetrahedron: Asymmetry 15, 1343 (2004).
30. M. Gullotti, A. Pasini, G. M. Zanderighi, J. Chem. Soc. Dalton Trans. 4, 902 (1981).
31. H. Elias, F. Stock, C. Röhr, Acta Crystallogr. C53, 862 (1997).
32. M. Gullotti, A. Pasini, P. Fantucci, R. Ugo, R. D. Gillard, Gazz. Chim. Ital. 102, 855 (1972),
33. A. Böttcher, H. Elias, J. Glerup, M. Neuburger, C. E. Olsen, H. Paulus, J. Springborg, M. Zehnder, Acta Chem. Scand. Ser. A 48, 967 (1994).
34. M. J. Adam and L. P. Hall, Can. J. Chem. 60, 2229 (1982).
35. W. A. Herrmann, J. Fridgen, G. M. Lobmaier, M. Spiegler, New J. Chem. 23, 5 (1999).