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note
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2 = 0.0763 for all data. CCDC 245087 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB2 1EZ, UK; fax: (+44)1223-336-033; or deposit@ ccdc.cam.ac.uk).
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C. Belle, C. Béguin, I. Gautier-Luneau, S. Hamman, C. Philouze, J.-L. Pierre, F. Thomas, S. Torelli, E. Saint-Aman, M. Bonin, Inorg. Chem. 2002, 41, 479.
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10
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12444343409
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note
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3 did not afford the expected mononuclear copper(II) complex of HL. Instead, 2 was isolated in 40% yield.
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-
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11
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12444302151
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note
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+.
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-
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12
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12444320664
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note
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+: 531 (330), 880 (210).
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1842731048
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14
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0030894332
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+ Hammet constant is observed for related compounds (Figure S8 in the Supporting Information). Moreover, the UV/Vis feature of the oxidized species matches well that reported for methoxyphenoxyl-copper(II) complexes (D. Zurita, I. Gautier-Luneau, S. Ménage, J.-L. Pierre, J. Biol. Inorg. Chem. 1997, 2, 46; Y. Shimazaki, S. Huth, S. Hirota, O. Yamauchi, Inorg. Chim. Acta 2002, 331, 168). This further confirms that the one-electron electrochemical process is ligand-based rather than metal-based.
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0037187580
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+ Hammet constant is observed for related compounds (Figure S8 in the Supporting Information). Moreover, the UV/Vis feature of the oxidized species matches well that reported for methoxyphenoxyl-copper(II) complexes (D. Zurita, I. Gautier-Luneau, S. Ménage, J.-L. Pierre, J. Biol. Inorg. Chem. 1997, 2, 46; Y. Shimazaki, S. Huth, S. Hirota, O. Yamauchi, Inorg. Chim. Acta 2002, 331, 168). This further confirms that the one-electron electrochemical process is ligand-based rather than metal-based.
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Shimazaki, Y.1
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16
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4644240894
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This is evident in the CV curve from an irreversible anodic signal (corresponding to the oxidation of the bridging phenolato moiety) associated, in the reverse scan, with a cathodic peak which is observed ca. 0.3 V lower, that is, at a potential value similar to that of the nonbridging phenoxyl/phenolato couple: See F. Michel, F. Thomas, S. Hamman, E. Saint-Aman, C. Bucher, J.-L. Pierre, Chem. Eur. J. 2004, 10, 4115.
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0035578243
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J. G. Radziszewski, M. Gil, A. Gorski, J. Spanget-Larsen, J. Waluk, B. J. Mroz, J. Chem. Phys. 2001, 115, 9733.
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12444310977
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note
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.+ due to its low stability.
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19
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12444287141
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note
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.+ measured at 215 K lacks most of the transitions associated with the quartet. It still exhibits a signal at g = 2.06 that could be attributed to an excited (S = 1/2) state, indicating that the exchange constant J is weak.
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20
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0038702236
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