Synthesis, spectroscopic and magnetostructural evidence for the formation of Cu(II) complexes of pyridyl-2-carboxylate (2-pca) and quinolyl-2-carboxylate (2-qca) as a result of a novel oxidative P-dealkylation reaction of diethyl 2-pyridylmethylphosphonate (2-pmpe) and diethyl 2-quinolylmethylphosphonate (2-qmpe) ligands

Inorganica Chimica Acta

Volumn 357, Issue 3, 2004, Pages 755-763

  Zurowska, Bogumiła ^a   Ochocki, Justyn ^b   Mroziński, Jerzy ^a   Ciunik, Zbigniew ^a   Reedijk, Jan ^c  

^a UNIVERSITY OF WROC AW   (Poland)

^b MEDICAL UNIVERSITY OF LODZ   (Poland)

^c LEIDEN UNIVERSITY   (Netherlands)

Author keywords

Copper(II) complexes; Crystal structures; Magnetic properties; N,O ligands; Oxidation

Indexed keywords

CARBOXYLATION; CHELATION; CHROMOPHORES; CRYSTAL STRUCTURE; ELECTRON SPIN RESONANCE SPECTROSCOPY; GEOMETRY; ISOMERS; LIGANDS; MAGNETIC PROPERTIES; MAGNETIC SUSCEPTIBILITY; MAGNETISM; NITROGEN COMPOUNDS; OXIDATION; SALTS; SINGLE CRYSTALS; SYNTHESIS (CHEMICAL);

ANTIFERROMAGNETIC COUPLING; COPPER COMPLEXES; FERROMAGNETIC EXCHANGE; INTER-ATOMIC DISTANCES; MAGNETIC SUSCEPTIBILITY MEASUREMENTS; N ,O LIGANDS; SQUARE PLANAR GEOMETRY; VARIABLE TEMPERATURE;

COPPER COMPOUNDS;

CARBOXYLIC ACID DERIVATIVE; COPPER COMPLEX; DIETHYL 2 PYRIDYLMETHYLPHOSPHONATE; DIETHYL 2 QUINOLYLMETHYLPHOSPHONATE; METHYLPHOSPHONIC ACID; PYRIDYL 2 CARBOXYLATE; QUINOLYL 2 CARBOXYLATE; UNCLASSIFIED DRUG;

ARTICLE; ATOM; CHEMICAL MODIFICATION; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; CRYSTAL STRUCTURE; DEALKYLATION; ELECTRON SPIN RESONANCE; GEOMETRY; INFRARED SPECTROSCOPY; MAGNETISM; MEASUREMENT; MOLECULAR INTERACTION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STOICHIOMETRY; STRUCTURE ANALYSIS; TEMPERATURE; X RAY CRYSTALLOGRAPHY;

EID: 1242351317     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ica.2003.06.017     Document Type: Article

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