Simultaneous Quantification of Residual Lignin and Hexenuronic Acid from Chemical Pulps with UV Resonance Raman Spectroscopy and Multivariate Calibration

Journal of Pulp and Paper Science

Volumn 29, Issue 11, 2003, Pages 363-370

  Saariaho, A M ^a   Hortling, B ^b   Jaaskelainen A S ^a   Tamminen, T ^b   Vuorinen, T ^a  

^a AALTO UNIVERSITY   (Finland)

^b KCL   (Finland)

Author keywords

Calibration; Chemical Pulps; Concentration; Lignins; Measurement; Raman Spectroscopy; Uronic Acids

Indexed keywords

BLEACHED PULP; CALIBRATION; CHEMICAL PULP; ORGANIC ACIDS; REGRESSION ANALYSIS; SOFTWOODS; SPECTROSCOPIC ANALYSIS; ULTRAVIOLET DEVICES;

PARTIAL LEAST SQUARES (PLS); ULTRAVIOLET RESONANCE RAMAN (UVRR) SPECTROSCOPY;

LIGNIN;

BLEACHED PULPS; CALIBRATION; CHEMICAL PULPS; HEXENURONIC ACID; LIGNINS; RAMAN SPECTROSCOPY; REGRESSION ANALYSIS; SOFTWOOD PULPS;

EID: 1242265033     PISSN: 08266220     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (32)

1. BRUNOW, G., LUNDQUIST, K. and GELLERSTEDT, G., "4.4. Quantitative Analysis" in Analytical Methods in Wood Chemistry, Pulping and Papermaking, E. Sjöström and R. Alén, Eds., 90, Springer-Verlag, Berlin, Germany (1999).
2. VUORINEN, T., BUCHERT, J., TELEMAN, A., TENKANEN, M. and FAGERSTRÖM, P., "Selective Hydrolysis of Hexenuronic Acid Groups and its Application in ECF and TCP Bleaching of Kraft Pulps", Proc. 1996 TAPPI Intl. Pulp Bleaching Conf., 43-51.
3. TENKANEN, M., GELLERSTEDT, G., VUORINEN, T., TELEMAN, A., PERTTULA, M., LI, J. and BUCHERT, J., "Determination of Hexenuronic Acid in Softwood Kraft Pulps by Three Different Methods", J. Pulp Paper Sci. 25(9): J306-311 (1999).
4. GELLERSTEDT, O. and LI, J., "An HPLC Method for the Quantitative Determination of Hexeneuronic Acid Groups in Chemical Pulps", Carbohydr. Res. 294:41-51 (1996).
5. HALTTUNEN, M., VYÖRYKKÄ, J., HORTLING, B., TAMMINEN, T., BATCHELDER, D., ZIMMERMANN, A. and VUORINEN, T., "Study of Residual Lignin in Pulp by UV Resonance Raman Spectroscopy", Holzforschung 55:631-638 (2001).
6. PERANDER, A-M., HALTTUNEN, M., JÄÄSKELÄINEN, A.-S., VYÖRYKKÄ. J. and VUORINEN, T., "Determination of Residual Lignin from Pulp Samples with UV Resonance Raman Spectroscopy", oral presentation, Proc. 11th Intl. Symp. Wood Pulping Chem., ATIP, Vol. I, 331-334 (2001).
7. WILLARD, H.H., MERRITT, L.L., DEAN, J.A. and SETTLE, F.A., "Instrumental Methods of Analysis", 7th ed., Wadsworth Inc., New York, NY, USA, Ch.12, 321-339 (1988).
8. AGARWAL, U.P. and ATALLA, R.H., "Raman Spectroscopy" in Surface Analysis of Paper, T.E. Conners and S. Banerjee, Eds., CRC Press Inc., Boca Raton, FL, USA, 152-181 (1995).
9. MARTENS, H. and NAES, T., Multivariate Calibration, John Wiley & Sons Ltd., Chichester, UK, 86 (1989).
10. SUN, Z., IBRAHIM, A. and OLDHAM, P.B., "Rapid Lignin Measurement in Hardwood Pulp Samples by Near-Infrared Fourier Transform Raman Spectroscopy", J. Agric. Food Chem. 45:3088-3091 (1997).
11. IBRAHIM, A., OLDHAM, P.B., CONNERS, T.E. and SCHULTZ, T.P., "Rapid Characterization of Wood Pulp Lignin by Fourier Transform Raman Spectroscopy", Microchem. J. 56:393-402 (1997).
12. MEDER, R., GALLAGHER, S., MACKIE, K.L., BÖHLER, H. and MEGLEN, R.R., "Rapid Determination of the Chemical Composition and Density of Pinus Radiata by PLS Modelling of Transmission and Diffuse Reflectance FTIR Spectra", Holzforschung 53:261-266 (1999).
13. HAUKSSON, J.B., BERGQVIST, G., BERGSTEN, U., SJÖSTRÖM, M. and EDLUND, U., "Prediction of Basic Wood Properties for Norway Spruce. Interpretation of Near Infrared Spectroscopy Data Using Partial Least Squares Regression", Wood Sci. Tech. 35:475-485 (2001).
14. SCHIMLECK, L.R., EVANS, R. and MATHESON, A.C., "Estimation of Pinus radiate D. don Clear Wood Properties by Near-Infrared Spectroscopy", J. Wood Sci. 48:132-137 (2002).
15. ONA, T., SONODA, T., ITO, K., SHIBATA, M., KATO, T. and OOTAKE, Y., "Non-Destructive Determination of Wood Constituents by Fourier Transform Raman Spectroscopy", J. Wood Chem. Technol. 17(4):399-417 (1997).
16. ONA, T., SONODA, T., ITO, K., SHIBATA, M., KATO, T. and OOTAKE, Y., "Non-Destructive Determination of Hemicellulosic Neutral Sugar Composition in Native Wood by Fourier Transform Raman Spectroscopy", J. Wood Chem. Technol. 18(1):27-41 (1998).
17. ONA, T., SONODA, T., ITO, K., SHIBATA, M., KATAYAMA, T., KATO, T. and OOTAKE, Y., "Non-Destructive Determination of Lignin Syringyl/Guaiacyl Monomeric Composition in Native Wood by Fourier Transform Raman Spectroscopy", J. Wood Chem. Technol. 18(1):43-51 (1998).
18. ONA, T., SONODA, T., ITO, K., SHIBATA, M., KATO, T., OOTAKE, Y., TAMAI, T. and KOJIMA, Y., "Rapid Prediction of Native Wood Pulp Properties by Fourier Transform Raman Spectroscopy", J. Pulp Paper Sci. 26(2):J43-47 (2000).
19. ONA, T., SONODA, T., ITO, K., SHIBATA, M., OOTAKE, Y., OHSHIMA, J., YOKOTA, S. and YOSHIZAWA, N., "Rapid Determination of Cell Morphology in Eucalyptus Wood by Fourier Transform Raman Spectroscopy", Appl. Spectrosc. 53(9): 1078-1082 (1999).
20. ONA, T., SONODA, T., ITO, K. and SHIBATA, M., "Determination of Wood Basic Density by Fourier Transform Raman Spectroscopy", J. Wood Chem. Technol. 18(3):367-379 (1998).
21. ONA, T., SONODA, T., ITO, K., SHIBATA, M., OOTAKE, Y., OHSHIMA, J., YOKOTA, S. and YOSHIZAWA, N., "In Situ Determination of Proportion of Cell Types in Wood by Fourier Transform Raman Spectroscopy", Anal. Biochem. 268:43-48 (1999).
22. ONA, T., SONODA, T., ITO, K., SHIBATA, M., OOTAKE, Y., OHSHIMA, J., YOKOTA, S. and YOSHIZAWA, N., "Quantitative FT-Raman Spectroscopy to Measure Wood Cell Dimensions", Analyst 124:1477-1480 (1999).
23. WOLD, S., ANTTI, H., LINDGREN, F. and ÖHMAN, J., "Orthogonal Signal Correction of Near-Infrared Spectra", Chemom. Intell. Lab. Syst. 44:175-185 (1998).
24. HORTUNG, B., TAMMINEN, T., RANUA, M., POPPIUS-LEVLIN, K., KETTUNEN, H. and NISKANEN, K., "Influence of Alkaline Cooking on the Bleachability and Reinforcement Power of Softwood Pulps", Preprints 2000 Intl. Pulp Bleaching Conf., Oral Presentations, PAPTAC, 29-35.
25. TELEMAN, A., HAUSALO, T., TENKANEN, M. and VUORINEN, T., "Identification of the Acidic Degradation Products of Hexenuronic Acid by NMR Spectroscopy", Carbohydr. Res. 280:197-208 (1996).
26. GELADI, P. and KOWALSKI, B.R., "Partial Least-Squares Regression: A Tutorial", Anal. Chim. Acta 185:1-17 (1986).
27. "Permanganate Number of Pulp", TAPPI Test Method T 214m-50 (1950).
28. LI, J. and GELLERSTEDT, G., "The Contribution to Kappa Number from Hexenuronic Acid Groups in Pulp Xylan", Carboh. Res. 302:213-218 (1997).
29. AGARWAL, U.P., "An Overview of Raman Spectroscopy as Applied to Lignocellulosic Materials" in Advances in Lignocellulosics Characterization, TAPPI PRESS, Ch. 9, 201 (1999).
30. TAMMINEN, T.L. and HORTUNG, B.R., "Lignin Reactions During Oxygen Delignification of Various Alkaline Pulps" in Oxidative Delignification Chemistry, Fundamentals and Catalysis, D.S. Argyropoulos, Ed., Am. Chem. Soc. Symp. series 785, Washington, DC, USA, 73-91 (2001).
31. LIN-VIEN, D., COLTHUP, N.B., FATELEY, W.G. and GRASSELLI, J.G., The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules, Academic Press, San Diego, CA, USA (1991).
32. NUOPPONEN, M., SAARIAHO, A.-M. and VUORINEN, T., "A Study on Resin Acid Model Compounds and Resin in Pine Wood with UV Resonance Raman (UVRR) Spectroscopy", Proc. 7th Europ. Workshop Lignocellulosics Pulp, Åbo Akademi, Åbo, Finland, 221-224 (2002).