Thermal runaway reaction hazards and mechanisms of hydroxylamine with acid/base contaminants

Thermochimica Acta

Volumn 421, Issue 1-2, 2004, Pages 1-9

  Wei, Chunyang ^a   Saraf, Sanjeev R ^a   Rogers, William J ^a   Sam Mannan, M ^a  

^a Texas AandM University   (United States)

Author keywords

Acid base contaminants; APTAC; Hydroxylamine; pH; Thermal decomposition

Indexed keywords

AMINES; CALORIMETERS; CONCENTRATION (PROCESS); CONDENSATION; HAZARDS; HYDROCHLORIC ACID; HYDROXYLATION; IMPURITIES; ORGANIC ACIDS; POTASSIUM COMPOUNDS; PRESSURE EFFECTS; PYROLYSIS; SOLUTIONS;

AUTOMATIC PRESSURE TRACKING ADIABATIC CALORIMETER (APTAC); HYDROXYLAMINE (HA); REACTIVE SYSTEM SCREENING TOOL (RSST); THERMOKINETIC DATA;

REACTION KINETICS;

HYDROCHLORIC ACID; HYDROXYLAMINE; POTASSIUM HYDROXIDE;

ACIDITY; ADIABATIC CALORIMETER; ARTICLE; CALORIMETER; CHEMICAL ENVIRONMENT; CHEMICAL INDUSTRY; CONCENTRATION RESPONSE; DECOMPOSITION; GAS ANALYSIS; HEATING; IONIZATION; KINETICS; MATHEMATICAL COMPUTING; MOLECULAR MECHANICS; POLLUTION; POLYMERIZATION; PRESSURE GRADIENT; PURIFICATION; QUANTUM MECHANICS; REACTION ANALYSIS; TEMPERATURE DEPENDENCE; THERMODYNAMICS; THERMOSTABILITY;

EID: 12344336741     PISSN: 00406031     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tca.2004.02.012     Document Type: Article

References (24)

1. Gustin J.L. Influence of trace impurities on chemical reaction hazards. J. Loss Prevent. Proc. Ind. 15:2002;37-48
2. Reisch M. Chem. Eng. News. 77:(9):1999;11
3. Business Concentrates, Chem. Eng. News 78 (25) (2000) 15.
4. Hydroxylamine and its Salts, Manufacturing Chemist and Aerosol News, 35 (8) (1964) 29-36.
5. Cisneros L.O., Rogers W.J., Mannan M.S. Adiabatic calorimetric decomposition studies of 50 wt.% hydroxylamine/water. J. Hazard. Mater. 82:(1):2001;13-24
6. Iwata Y., Koseki H., Hosoya F. Study on decomposition of hydroxylamine/water solution. J. Loss Prevent. Proc. Ind. 16:2003;41-53
7. Becke A.D. J. Chem. Phys. 98:1993;5648
8. Perdew J.P. Phys. Rev. B33:1986;8822
9. Dunning T.H. Jr. J. Chem. Phys. 90:1989;1007
10. M.J. Frisch, G.W. Trucks, H.B. Schlegel, G.E. Scuseria, M.A. Robb, J.R. Cheeseman, V.G. Zakrzewski, J.A. Montgomery Jr., R.E. Stratmann, J.C. Burant, S. Dapprich, J.M. Millam, A.D. Daniels, K.N. Kudin, M.C. Strain, O. Farkas, J. Tomasi, V. Barone, M. Cossi, R. Cammi, B. Mennucci, C. Pomelli, C. Adamo, S. Clifford, J. Ochterski, G.A. Petersson, P.Y. Ayala, Q. Cui, K. Morokuma, N. Rega, P. Salvador, J.J. Dannenberg, D.K. Malick, A.D. Rabuck, K. Raghavachari, J.B. Foresman, J. Cioslowski, J.V. Ortiz, A.G. Baboul, B.B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. Gomperts, R.L. Martin, D.J. Fox, T. Keith, M.A. Al-Laham, C.Y. Peng, A. Nanayakkara, M. Challacombe, P.M.W. Gill, B. Johnson, W. Chen, M.W. Wong, J.L. Andres, C. Gonzalez, M. Head-Gordon, E.S. Replogle, J.A. Pople, Gaussian'98, Revision A.11.3, Gaussian Inc., Pittsburgh, PA, 2002.
11. M.A. Grolmes, J.C. Leung, H.K. Fauske, Reactive systems vent sizing evaluations, in: Proceedings of the International Symposium on Runaway Reactions, CCPS, Cambridge, MA, March 1989, pp. 451-476.
12. Creed M.J., fauske H.K. An easy and inexpensive approach to the DIERS methodology. Chem. Eng. Prog. 86:(3):1990;45-49
13. S. Chippett, P. Ralbovsky, R. Granville, The APTAC: a high pressure, low thermal inertia, adiabatic calorimeter, in: Proceedings of the International Symposium on Runaway Reaction, Pressure Relief Design and Effluent Handling, 1998, pp. 81-108.
14. Townsend D.I., Tou J.C. Thermal hazard evaluation by an accelerating rate calorimeter. Thermochim. Acta. 37:(1):1980;1-30
15. http://response.restoration.noaa.gov/chemaids/react.html.
16. Lunak S., Veprek-Siska J. Catalytic effect of cations on the decomposition of alkaline solutions of hydroxylamine. Collect. Czech. Chem. Commun. 39:(2):1974;391-395
17. K.A. Hofmann, Friedrich Kroll, Thermal Decomposition of Hydroxylamine and Hydrazine Salts, Berichte, 57B, 1924, 937-944 (in German).
18. Cisneros L.O., Rogers W.J., Mannan M.S. Effect of air in the thermal decomposition of 50 mass% hydroxylamine/water. J. Hazard. Mater. 95:(1-2):2002;13-25
19. Hughes M.N., Nicklin H.G. Autoxidation of hydroxylamine in alkaline solutions. Part II. J. Chem. Soc. (A). 22:1971;3485-3487
20. Ebler E., Schott E. J. Prakt. Chem. 78:(2):1908;289
21. øiestad E.L., Uggerud E. The unimolecular chemistry of protonated hydroxylamine. Int. J. Mass Spectrom. 185-186-187:1999;231-240
22. Lin M.C., He Y., Melius C.F. Theoretical interpretation of the kinetics and mechanisms of the HNO + HNO and HNO + 2NO reactions with a unified model. Int. J. Chem. Kinet. 24:1992;489-516
23. Ruud K., Helgaker T., Uggerud E. J. Mol. Struct. (Theochem). 393:1997;59-71
24. Miller J.A., Bowman C.T. Prog. Energy Combust. Sci. 15:1989;287