Isomerization by ligand shuffling along a Cr24+ unit: Further reactions leading to cleavage of a quadruple bond

Dalton Transactions

Volumn , Issue 15, 2003, Pages 3022-3027

  Clérac, Rodolphe ^a,b   Cotton, F Albert ^a   Jeffery, Stephen P ^a   Murillo, Carlos A ^a   Wang, Xiaoping ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

^b CENTRE DE RECHERCHE PAUL PASCAL   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ANTIFERROMAGNETIC MATERIALS; CHEMICAL BONDS; ISOMERIZATION; MAGNETIC PROPERTIES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION; REACTION KINETICS;

CHROMIUM IONS; FORMAMIDINATE; INTERCONVERTING ISOMERS; LIGANDS;

CHROMIUM COMPOUNDS;

EID: 12344336603     PISSN: 14779226     EISSN: None     Source Type: Journal    
DOI: 10.1039/b305304k     Document Type: Article

References (30)

1. (a) F. A. Cotton, C. A. Murillo and I. Pascual, Inorg. Chem., 1999, 38, 2182;
2. (b) K. M. Carlson-Day, J. L. Eglin, L. T. Smith and R. J. Staples, Inorg. Chem., 1999, 38, 2216;
3. (c) K. M. Carlson-Day, J. L. Eglin, C. Lin, L. T. Smith, R. J. Staples and D. O. Wipf, Polyhedron, 1999, 18, 817;
4. (d) T. Ren, Coord. Chem. Rev., 1998, 175, 43;
5. (e) C. Lin, T. Ren, E. J. Valente and J. D. Zubkowski, J. Chem. Soc., Dalton Trans., 1998, 571;
6. (f) F. A. Cotton, L. M. Daniels, X. J. Feng, D. J. Maloney, J. H. Matonic and C. A. Murillo, Inorg. Chim. Acta, 1997, 256, 291;
7. (g) F. A. Cotton, J. H. Matonic and C. A. Murillo, Inorg. Chim. Acta, 1997, 264, 61;
8. (h) F. A. Cotton, L. M. Daniels, J. H. Matonic and C. A. Murillo, Inorg. Chim. Acta, 1997, 256, 277;
9. (i) A. Singhal and V. K. Jain, Can. J. Chem., 1996, 74, 2018;
10. (f) F. A. Cotton, L. M. Daniels and C. A. Murillo, Inorg. Chem., 1993, 32, 2881;
11. (k) F. A. Cotton and T. Ren, J. Am. Chem. Soc., 1992, 114, 2495;
12. (l) J. L. Bear, C. L. Yao, R. S. Lifsey, J. D. Korp and K. M. Kadish, Inorg. Chem., 1991, 30, 336;
13. (m) F. A. Cotton and R. A. Walton, Multiple Bonds Between Metal Atoms, Clarendon Press, Oxford, 2nd edn., 1993 and references therein.
14. See for example: C. Lin, J. D. Protasiewicz, E. T. Smith and T. Ren, Inorg. Chem., 1996, 35, 6422.
15. F. A. Cotton, P. Lei and C. A. Murillo, Inorg. Chim. Acta, 2003, 349, 173.
16. F. A. Cotton, L. M. Daniels, C. A. Murillo and X. Wang, Chem. Commun., 1998, 39.
17. F. A. Cotton, L. M. Daniels, C. A. Murillo and I. Pascual, J. Am. Chem. Soc., 1997, 119, 10223.
18. R. Clérac, F. A. Cotton, K. R. Dunbar, C. A. Murillo and X. Wang, Inorg. Chem., 2001, 40, 420.
19. M. H. Chisholm, D. L. Clark and M. J. Hampden-Smith, J. Am. Chem. Soc., 1989, 111, 574. The term "shuffle" was used in reference to the so-called "Bloomington shuffle.".
20. H. Remlinger, W. R. F. Lingier, J. J. M. Vandewalle and R. Merényi, Chem. Ber., 1971, 104, 3965.
21. Theory and Applications of Molecular Paramagnelism, ed. E. A. Boudreaux and L. N. Mulay, John Wiley and Sons, New York, 1976.
22. 2 can be isolated in low yield is red in color.
23. J. Pflugrath and A. Messerschmidt, MADNES, Munich Area Detector (New EEC) System, version EEC 11/1/89, with enhancements by Enraf-Nonius Corp., Delft, The Netherlands. A description of MADNES appears in: A, Messerschmidt and J. Pflugrath, J. Appl. Crystallogr., 1987, 20, 306.
24. (a) W. Kabsch, J. Appl. Crystallogr., 1988, 21, 67;
25. (b) W. Kabsch, J. Appl. Crystallogr., 1988, 21, 916.
26. F. A. Cotton, R. H. Niswander and J. C. Sekutowiski, Inorg. Chem., 1978, 17, 3541.
27. See F. A. Cotton, L. M. Daniels, C. A. Murillo, I. Pascual and H.-C. Zhou, J. Am. Chem. Soc., 1999, 121, 6856 for an in-depth discussion of how various factors affect the Cr-Cr bond length.
28. F. A. Cotton, L. M. Daniels, C. A. Murillo and I. Pascual, Inorg. Chem. Commun., 1998, 1, 1.
29. F. A. Cotton, L. M. Daniels, C. A. Murillo and H.-C. Zhou, Inorg. Chim. Acta, 2000, 305, 69 and references therein.
30. K. H. Theopold, Acc. Chem. Res., 1990, 23, 263.