Biomimetic complexes: Thermal stability, kinetic study and decomposition mechanism of Co(II)-, Ni(II)- and Cu(II)-4(5)-hydroxymethyl-5(4)-methylimidazole complexes

Thermochimica Acta

Volumn 421, Issue 1-2, 2004, Pages 19-24

  Materazzi, S ^a   Aquili, S ^a   De Angelis Curtis, S ^a   Vecchio, S ^a   Kurdziel, K ^b   Sagone, F ^a  

^a SAPIENZA UNIVERSITY OF ROME   (Italy)

^b JAN KOCHANOWSKI UNIVERSITY   (Poland)

Author keywords

Coordination compounds; Coupled TG FT IR; Decomposition kinetics; EGA; Hydroxymethyl methylimidazole; Imidazole derivatives; TGA; Transition metal ions complexes

Indexed keywords

ACTIVATION ENERGY; AROMATIC COMPOUNDS; COBALT; COPPER; DECOMPOSITION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; NICKEL; REACTION KINETICS; THERMODYNAMIC STABILITY; THERMOGRAVIMETRIC ANALYSIS;

BIOMIMETIC COMPLEXES; DERIVATIVE THERMOGRAVIMETRY (DTG); EVOLVED GAS ANALYSIS (EGA); KISSINGER METHODS;

BIOMIMETIC MATERIALS;

COBALT COMPLEX; COPPER COMPLEX; HYDROXYL GROUP; IMIDAZOLE DERIVATIVE; METHYL GROUP; NICKEL COMPLEX;

ANALYTIC METHOD; ARTICLE; BIOMIMETICS; COMPLEX FORMATION; CROSS COUPLING REACTION; DECOMPOSITION; ENERGY BALANCE; FOURIER ANALYSIS; GAS ANALYSIS; INFRARED SPECTROMETRY; KINETICS; MATHEMATICAL COMPUTING; MOLECULAR INTERACTION; MOLECULAR MECHANICS; THERMODYNAMICS; THERMOGRAVIMETRY; THERMOSTABILITY;

EID: 12344299245     PISSN: 00406031     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tca.2004.02.020     Document Type: Article

References (17)

1. Lane T.J., Quinlan C.S.C., Quinlan K.P. J. Am. Chem. Soc. 82:1960;2994
2. Patel K.S., Bhatt I.M., Dani D.P. Indian Chem. Soc. LIV:1977;1007
3. Rzepka M., Surga W. Pol. J. Chem. 67:1993;2121
4. Kulig J., Kurdziel K., Barszcz B., Lenarcik B. Pol. J. Chem. 65:1991;2159
5. Kulig J., Barszcz B., Lenarcik B. Pol. J. Chem. 66:1992;79
6. B. Barszcz, J. Kulig, J. Chem. Soc., Dalton Trans. (1993) 1559.
7. Kurdziel K., Glowiak T., Jezierska J. Polyhedron. 21:2002;1857
8. Kurdziel K., Glowiak T., Jezierska J. Inorg. Chem. Commun. 6:2003;459
9. Ozawa T. Bull. Chem. Soc. Jpn. 38:1965;1881
10. Flynn J.H., Wall L.A. Polym. Lett. 4:1969;323
11. Kissinger H.E. Anal. Chem. 29:1957;1702
12. Kissinger H.E. J. Res. Natl. Bur. Standard A: Phys. Chem. 57:1956;217
13. Materazzi S., Vasca E. Thermochim. Acta. 373:2001;7
14. Materazzi S., Kurdziel K., Tentolini U., Bacaloni A., Aquili S. Thermochim. Acta. 395:2003;137
15. Materazzi S., D'Ascenzo G., Aquili S., Kadish K.M., Bear J.L. Thermochim. Acta. 397:2003;129
16. Materazzi S., Aquili S., Bianchetti C., D'Ascenzo G., Kadish K.M., Bear J.L. Thermochim. Acta. 409:2004;145
17. Sell T., Vyazovkin S., Wight C. Combust. Flame. 119:1999;174